Aldehydes and ketones Flashcards

(50 cards)

1
Q

common name?

A
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2
Q

common name?

A
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3
Q

common name?

A
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4
Q

common name?

A

formaldehyde

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5
Q
A
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6
Q
A
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7
Q

what is the IUPAC method for naming aldehydes?

A

lose “e”
add “al”

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8
Q
A
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9
Q

what would cyclopentanal look like?

A

does not exist because cyclic aldehydes cannot exist

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10
Q
A
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11
Q

what is the simplest ketone? its name?

A
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12
Q

what is the common naming method for ketones?

A

alkyl + alkyl + “ketone”

(similar to ethers)

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13
Q
A
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14
Q

what is the IUPAC naming method for ketones?

A

lose “e”
add “one”

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15
Q
A
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16
Q
A
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17
Q
A
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18
Q
A

when O is double bonded to a parent chain, it has -oxo- as substituent name

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19
Q
A
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20
Q
A
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21
Q

if a parent chain has 3-12 carbons, what state is it at room temperature typically?

22
Q

if a parent chain has more than 12 carbons, what state is it at room temperature typically?

23
Q

why is it that ketones are only ever H-bond acceptors and never donors?

A

they don’t have a hydrogen directly adjacent to the oxygen for it to donate

24
Q

why is it that all H-bond donors can also be acceptors?

A

If they have a hydrogen to give, it means they must have an adjacent oxygen to receive H-bonds.

25
which is acting as the H-bond donor and which is the H-bond acceptor?
26
which is acting as the H-bond donor and which is the H-bond acceptor?
27
28
what is the name of one common oxidizing agent?
potassium dichromate
29
30
31
what is the purpose of Tollen's test?
test for presence of any aldehydes
32
what does Tollen's test require?
tollen's reagent strong base
33
34
what does Fehling's test show positive for?
aliphatic aldehydes alpha hydroxy ketones
35
do aromatic aldehydes show positive on Fehling's test?
no, aliphatic aldehydes do
36
what are the agents within Fehling's test?
37
38
is this an aromatic aldehyde?
yes
39
is this an aromatic aldehyde?
no
40
is this an aromatic aldehyde?
no
41
42
43
44
hemiacetal
45
acetal
46
hydrate
47
find the acetal/hemiacetal/hydrate
48
include the entire reaction, starting at this point to get an acetal
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