ALKALIMETRY Flashcards

(50 cards)

1
Q

The strength of an acid
solution is determined by
titrating it against a standard
base solution or determining the
strength of an alkali solution by
titration with a standard acid
solution.

A

Principle of Acid – Base
Titration

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

is used to monitor
the reaction

A

pH indicator

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

reaction
usually occurs between acid and
base, hydroxide ions and hydrogen
protons, resulting in the formation
of water

A

neutralization

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

re chemical processes
whereby an amount of an acid has reacted with
an equivalent amount of a base with the
production of salt and water.

A

Neutralization reactions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

is the measurement of basic
substances by titration with
a standard acid

A

ACIDIMETRY

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

involves the determination
of acidic substances by
titration with a standard
base solution.

A

ALKALIMETRY

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

any substance which releases H ions in water solution

A

ARRHENIUS ACID

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

any substance which releases OH ions in water solution

A

ARRHENIUS BASE

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

any substance which donates a proton

A

BRONSTED LOWRY ACID

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

any substance which accepts a proton

A

BRONSTED LOWRY BASE

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

any substance which can accept an electron pair

A

LEWIS ACID

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

any substance which can donate an electron pair

A

LEWIS BASE

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

is any substance which in water ionizes to give hydrogen ions
(hydronium ions*)

A

ACID

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

is any substance which in water ionizes to give hydroxyl ions

A

BASE

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

is the combination of the proton and hydroxyl ion to
form the water molecule.

A

NEUTRALIZATION

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

by-product of neutralization

A

SALT

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

NEUTRALIZATION
Based on Media (Solvent) Used

A

Aqueous titrimetry
Non-aqueous titrimetry

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

use water as the solvent for
dissolving the analyte samples for the
titration.

A

Aqueous titrimetry

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

the concept of acids and bases has been
extended to include solvents other than
water, acids other than proton donors, and
bases other than hydroxyl ions donors.
These are considered, on nonaqueous
titrimetry

A

Non-aqueous titrimetry

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Non-aqueous titrimetry use ______ for dissolving the
sample.

A

organic solvents

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Strong Acid + Strong Base

A

Phenolphthalein, methyl red, methyl orange

22
Q

Weak Acid + Strong Base

A

Phenolphthalein

23
Q

Weak Acid + Weak Base

24
Q

Strong Acid + Weak Base

25
Weak Base + Salt
Crystal violet, Quinaldine red, malachite green
26
Relatively Strong Base
Methyl red, methyl orange
27
Weak acid
Azo-violet, o-nitro-aniline (very WA)
28
Strong Acid
Thymol blue
29
BASES' BURETTE
MOHR'S BURETTE
30
ACIDS BURETTE
GEISSLER'S BURETTE
31
The most common application of acid-base titrations is
determining an unknown analyte's acid or base concentration
32
_______ is carried out with ACID-BASE TITRIMETRY
Quantitative chemical analysis
33
Pharmaceutical applications of Acid-Base Titrimetry
A barbiturate, aspirin, and amino acid
34
An environmental analysis can be conducted with it.
Application of Acid-Base Titrimetry
35
percentage potency, strength or percentage purity of a drug or preparation. - amount per 100
% assay
36
Types of Titration Based On The Number of Volumetric Solution
DIRECT AND RESIDUAL/BACK TITRATION
37
Titrant is added into the analyte until chemical equivalent amounts of them reacts together
DIRECT
38
Described as the amount of volumetric solution in excess. The excess is back titrated with another volumetric solution
RESIDUAL OR BACK TITRATION
39
ONLY 1 VOLUMETRIC SOLN/STD. SOLUTION
DIRECT
40
USES 2 VOLUMETRIC SOLN. (VISS) 1 or more std. sol’n., involve addition of excess std. sol’n. & the excess is back titrated w/ another std. sol’n
RESIDUAL
41
WHY Residual Titration?
❖ Volatile ❖ Sample is insoluble in water ❖ Reaction with standard solution is slow ❖ Sample does not give a distinct endpoint with an indicator by direct titration (No sharp endpoint)
42
can be calculated by dividing the mass of the pure chemical by the total mass of the sample, and then multiplying this number by 100.
Percentage Purity
43
s carried in the same manner as the actual test BUT without the sample
Blank test
44
Blank test are Performed to correct errors due to
* the presence of impurities in the reagents * changes in volume at different temperature * absorption of carbon dioxide by the alkali * by the alkalinity imparted by the glass
45
ml in the blank titration is ml of acid =
total base
46
ml in actual is ml of acid =
base found in excess
47
l of acid that reacted with sample =
ml of the base that reacted with the sample
48
is the analysis of an acid , acid salt or other acidic substance
Alkalimetry
49
f using an accurately measured volume of a standard alkali solutions
DIRECT
50
if the process requires adding an excess of the standard alkali solution and determining the amount in excess by residual titration with standard acid solution
RESIDUAL