Alkenes Flashcards

(9 cards)

1
Q

Structure and bonding in Alkenes

A

Planar, 120

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2
Q

Why does E-Z isomerism exist?

A

Rigidity about the pi bond between the carbon-carbon

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3
Q

Stereoisomers

A

Molecules with the same molecular formula and the same arrangement of covalent bonds but with different spatial orientations of the groups.

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4
Q

E-Z stereoisomers

A

Stereoisomers with different spatial orientations around the carbon-carbon double bond.

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5
Q

Heterolytic fission

A

The breaking of a covalent bond which results in both electrons going to the same atom.

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6
Q

An electrophile is

A

a species which can accept a pair of electrons from a species with a high electron density

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7
Q

Alkene to Alcohol

A

Step 1: cold concentrated H2SO4

Step 2: warm and add H2O

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8
Q

Markownikoff’s rule

A

The more electronegative part of the electrophile will usually attach itself to the more highly substituted carbon atom

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9
Q

Production of pure ethanol

A

When alkenes are treated with steam at 300C, a pressure of 60 atmospheres and a phosphoric acid (H3PO4) catalyst, the H2O is added across the double bond and an alcohol is formed in a reaction known as hydration

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