Alkenes Flashcards
(9 cards)
Structure and bonding in Alkenes
Planar, 120
Why does E-Z isomerism exist?
Rigidity about the pi bond between the carbon-carbon
Stereoisomers
Molecules with the same molecular formula and the same arrangement of covalent bonds but with different spatial orientations of the groups.
E-Z stereoisomers
Stereoisomers with different spatial orientations around the carbon-carbon double bond.
Heterolytic fission
The breaking of a covalent bond which results in both electrons going to the same atom.
An electrophile is
a species which can accept a pair of electrons from a species with a high electron density
Alkene to Alcohol
Step 1: cold concentrated H2SO4
Step 2: warm and add H2O
Markownikoff’s rule
The more electronegative part of the electrophile will usually attach itself to the more highly substituted carbon atom
Production of pure ethanol
When alkenes are treated with steam at 300C, a pressure of 60 atmospheres and a phosphoric acid (H3PO4) catalyst, the H2O is added across the double bond and an alcohol is formed in a reaction known as hydration