amount of substances chp 3 Flashcards

1
Q

what is 1 mole equivalent to

A

one mole is the amount of a substance that contains 6.02 x 10^23

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2
Q

what is 6.02 x 10^23

A
  • Avagadros constant, its the number of particles in 1 mole of carbon-12
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3
Q

Definition of molar mass

A
  • Molar mass gives the mass in grams of a mole of substance.
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4
Q

whats the formula for finding out molar mass

A

mass / moles = Mr

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5
Q

Definition of relative molecular mass

A
  • mass of a molecule compared to 1/12th mass of atom of carbon-12
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6
Q

Definition of relative formula mass

A
  • the mass of a formula unit compared to mass of an atom of carbon-12
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7
Q

How is relative formula mass calculated

A
  • adding together the relative atomic masses of the elements in the empirical formula
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8
Q

what is the water that is part of the crystalline structure of a salt called

A

water of crystallisation

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9
Q

How accurate is finding the formula of a compound using experiments

A

assumption 1- all water has been lost (if there is a colour change you only see the surface of the crystals and water could be left inside). A solution is to heat to constant mass-the crystals are reheated repeatedly until the mass of the residue no longer changes, suggesting all water has been removed.
Assumption 2- no further decomposition (many salts decompose further when heated, this can be very difficult to judge if there is no colour change)

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10
Q

which volume measurements are most commonly used

A
  • cubic centimetre (cm^3) or millilitre (ml) : 1cm^3 = 1 ml
  • cubic decimetre (dm^3) or litre(l) : 1 dm^3 = 1000 cm^3= 1000ml = 1L
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11
Q

what’s the formula for calculating moles from volume and concentration

A

mol = conc x vol

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12
Q

what is a standard solution

A

a standard solution is a solution of known concentration

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13
Q

How are standard solutions prepared

A

prepared by dissolving an exact mass of the solute in a solvent and making up the solution to an exact volume

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14
Q

what is the relationship between a volume of any gas and the number of moles

A

-at same temp and pressure
- ^ 1 mol takes up same place

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15
Q

Definition of molar volume

A

The molar gas volume (Vm) is the volume per mole of gas molecules at a stated temp and pressure

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16
Q

what are the values for standard conditions

A

RTP is about 20 degrees and 101 kPa (1 atm) pressure

17
Q

what volume does 1 mole of gas take up in standard RTP

A

At RTP, 1 mole of gas molecules has a volume of approximately 24.0 dm^3=24000 cm^3

18
Q

whats the formula for calculating molar gas volume

A
19
Q

when would you use the ideal gas equation

A

when the experiment calls for a different temperature or pressure than standard or if you need to be more accurate In your calculations

20
Q

what assumptions are made about molecules when using the ideal gas equation

A
  • random motion
  • elastic collisions
  • negligible size
  • no intermolecular forces
21
Q

what is the ideal gas equation formula
what does each thing stand for

A

temperature is in kelvin (k)
pressure is in pascals (Pa)
volume is in (m^3)
amount of gas molecules is in moles (mol)
ideal gas constant is 8.314 j mol^-1K^-1

22
Q

how do you convert between the basic units used in chemistry

A

cm^3 to dm^3 = /1000
kPa to Pa = x 1000
K to °C = -273

23
Q

what is the real gas equation and how does it differ from the ideal gas equation

A

it takes into account intermolecular forces and the volume of gas molecules

24
Q

what is stoichiometry and what does it show

A
  • it is the ratio of moles of each substance in a reaction
  • used to find quantity of reactants needed to produce a certain amount of product
  • used to find quantities of products that should be formed from a certain quantity of reactants.

ONLY FOUND IN BALANCED EQUATIONS

25
Q

what is the formula for percentage yeild

A
26
Q

why is the theoretical yeild never really obtained

A

-the reaction may not have gone to completion
-other reactions (side reactions) may have taken place -alongside the main reaction
-purification of the product may result in loss of some product

27
Q

definition of limiting reagent

A

the reactant that is not in excess and hence will be completely used up first and stop the reaction

28
Q

how would you figure out the limiting reagenbt based on the chemical equation

A

find out by working out the amount in moles of each reactant and comparing, if there where equal amounts of both reactant which one would be used up first, that one would be the limiting reagent

29
Q

what is the atom economy of a reaction

A

the atom economy of a chemical reaction is a measure of how well atoms have been utilised

30
Q

what is the formula for atom economy

A
31
Q

what do we base off of the atom economy of a reaction

A
  • the sustainability of a reaction
  • efficency of reaction
  • ^high atom economy = efficent