Atomic Structure Flashcards

1
Q

Atom

A

Basic building block of matter, consist of protons, electrons, and neutrons

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2
Q

Protons

A

+1

1.0073 amu

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3
Q

Neutron

A

No charge, slightly heavier than a proton

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4
Q

Electron

A

-1

1/1837 mass of proton or neutron

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5
Q

Valence electrons

A

Electrons farthest away from nucleus that participate in bonding

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6
Q

Orbital

A

Region around nucleus where electron is likely to be found

Each has unique assignment for n, l, and m(l) quantum numbers

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7
Q

Atomic Number

A

Number of protons

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8
Q

Mass Number

A

Protons + Neutrons

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9
Q

Nucleus

A

Dense, positively charged atomic center that contains protons and neutrons

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10
Q

Atomic Mass Unit

A

1/12 of Carbon-12 atom mass

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11
Q

Atomic Weight

A

Average mass of all naturally occurring isotopes of a given element, measured in amu

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12
Q

Avogadro’s Number

A

6.022 X 10^23 atoms/ mol

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13
Q

Isotopes

A

Same atomic number, but different neutron number

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14
Q

Bohr Model

A

Atomic model where electrons located in discrete circular orbits around nucleus, with electrostatic force acting as centripetal force

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15
Q

What does emission give rise to and how is it useful?

A

Emission gives rise to fluorescence and the unique atomic emission spectra could be used to identify an element

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16
Q

Quantum Mechanics

A

Study of physics at atomic level with discrete levels of energy

17
Q

Atomic Emission Spectra

A

Discontinuous spectra of lit produced when electrons emit photons of certain frequencies as they return to their ground states

18
Q

Atomic Absorption Spectra

A

The spectrum of certain absorbed light wavelengths corresponding to the energy electrons require to jump to the next energy level

19
Q

What is the basis for color in compounds?

A

Absorption

20
Q

Balmer Series

A

Set of spectral lines that appear in visible light region when hydrogen atom undergoes transition from energy levels n > 2 to n = 2

21
Q

Lyman Series

A

Set of spectral lines that appear in UV region when hydrogen atom undergoes a transition from energy levels n > 1 to n = 1

22
Q

Heisenberg Uncertainty Principle

A

Impossible to determine with perfect accuracy the exact momentum and position of orbiting electron simultaneously

23
Q

Quantum Number

A

Set of four numbers used to describe electrons energy state

24
Q

Photon

A

Unit of energy in the form of light equal to hf

25
Pauli Exclusion Principe
No two electrons in the same atom can possess the same set of four quantum numbers
26
Principal Quantum Number
It is any positive integer value and it describes an electron's energy value Max number of electrons in energy level n is 2n^2, where the difference in energy between adjacent shells decreases as distance from nucleus increases
27
Azimuthal (Angular Momentum) Quantum Number
Refers to the subshells, ranges from 0 to n-1 l = 0, 1, 2, 3 ===> s, p, d, f Max number of electrons in a subshell = 4l + 2
28
Magnetic Quantum Number
Specific Region within a subshell where highly likely to find an electron, ranging from -l to l, including 0
29
Spin Quantum Number
-1/2 or + 1/2
30
What are the four quantum numbers?
Principal Quantum Number Azimuthal Quantum Number Magnetic Quantum Number Spin Quantum Number
31
Electron Configuration
Patterned order by which electrons fill subshells and energy levels in an atom
32
Aufbau Principle
Electrons fill an atom in order of increasing energy level
33
Hund's Rule
Electrons will first fill equal energy orbital of subshell unpaired with parallel spins before coupling with other electrons of opposite spins in same orbital to maximize number of half-filled orbitals, allowing for most stable electron distribution
34
Paschen Series
Set of spectral lines resulting when a hydrogen atom undergoes transition from energy levels n > 4 to n =3
35
Isoelectronic
Two different elements with same electron configuration
36
Paramagnetic
Atom or substance with unpaired electrons and attracted by a magnet
37
Diamagnetic
Atom or substance with no unpaired electrons and repelled by a magnet
38
Pfund Series
Set of spectral lines resulting when a hydrogen atom undergoes a transition from energy levels n > 5 to n = 5