BUTADIENE EXTRACTION PLANT Flashcards
(16 cards)
It is a C4 petrochemical used as raw material for synthetic ribbers such as styrene-butadiene rubber (SBR) primarily used for the production of automobile tires, for acrylonitrile-butadiene-styrene (ABS) used for appliances and automotive applications, and for styrene butadiene latex used for gloves, paper coatings and textiles.
Butadiene
It is composed of various C4 hydrocarbons such as isobutylenes and butanes.
Raffinate-1
It is mainly used for producing rubbers, as well as feedstock for the production of methyl-tert-butyl ether (MTBE) for gasoline blending.
Isobutylene
it can also be produced from raffinate, and used as comonomer for polymer production
butene-1
The _____ uses n-methyl-pyrrolidone (NMP) as solvent
NMP-based butadiene process
it is the least toxic solvent that is easily treated by conventional biological degradation
NMP
four basic process sections of a typical butadiene extraction plant
• extractive distillation
• conventional distillation
• solvent degassing
• solvent regeneration
_____ is used separate components with similar volatilities. A solvent (NMP) is added to alter the relative volatility of components in a mixture.
Extractive distillation
The _____ is sent to the extractive distillation section where it is vaporized and separated using two extractive distillation columns.
C4 feed
In the butadiene extraction plant, the overhead product from the _____ consists of a mixture of butenes and butanes and is designated as raffinate-1.
first column
The _____ is a dividing wall column consisting of a rectifier and an afterwasher.
second column
The overhead from the afterwasher is a ____ product that is sent to the conventional distillation system for further purification.
crude butadiene
In the butadiene extraction plant, it is removed from the bottom of the second column and sent to the solvent degassing system.
Rich solvent
_____ is fed to the propyne column, which is the first of two columns in the conventional distillation section.
Crude butadiene
C4 acetylenes are removed as a side stream and can be hydrogenated, used as fuel gas or as cracker feed, or burned in a _____
flare system
_____ is condensed and recycled to the extractive distillation section.
Vaporized NMP