C6 - Chemistry Out There Flashcards

(182 cards)

1
Q

C6 - Chemistry Out There

What is reduction?

A

Gain of electrons

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2
Q

C6 - Chemistry Out There

What does an oxidising agent do?

A

Accept electrons and gets reduced

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3
Q

C6 - Chemistry Out There

What does a reducing agent do?

A

Donate electrons and get oxidised

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4
Q

C6 - Chemistry Out There

What does displacement reactions involve?

A

One metal kicking another one out of a compound

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5
Q

C6 - Chemistry Out There

What is the rule for displacement reactions?

A

A more reactive metal will displace a less reactive metal from its compound

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6
Q

C6 - Chemistry Out There

Why do some iron and steels rust?

A

When they come into contact with air and water

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7
Q

C6 - Chemistry Out There

When does rusting of iron only occur?

A

When iron is in contact with both water and oxygen

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8
Q

C6 - Chemistry Out There

What is rust a form of?

A

Hydrated iron (III) oxide

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9
Q

C6 - Chemistry Out There

What is the equation for rusting?

A

Iron + oxygen + water -> hydrated iron (III) oxide

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10
Q

C6 - Chemistry Out There

What type of reaction is rusting of iron?

A

Redox

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11
Q

C6 - Chemistry Out There

What happens to iron when it reacts with oxygen?

A

Loses electrons - oxidised. Each Fe atom loses 3 electrons to become Fe3+.

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12
Q

C6 - Chemistry Out There

What happens to oxygen when it reacts with iron?

A

Reduced. Each O atom gains 2 electrons to become O2-.

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13
Q

C6 - Chemistry Out There

What are the 4 ways to prevent rusting?

A

Make alloys. Barrier. Tin coating/plating. More reactive metals (galvanising)

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14
Q

C6 - Chemistry Out There

What are steels alloys of?

A

Iron with carbon and small quantities of other metals

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15
Q

C6 - Chemistry Out There

What is stainless steel?

A

One of most common steels - rustproof alloy of iron, carbon and chromium.

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16
Q

C6 - Chemistry Out There

How does a barrier prevent rusting?

A

Keeps out water, oxygen or both.

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17
Q

C6 - Chemistry Out There

How is painting ideal to prevent rusting?

A

Ideal for large and small structures. Nice and colourful.

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18
Q

C6 - Chemistry Out There

How is oiling or greasing used to prevent rusting?

A

Has to be used when moving parts are involved e.g. Bike chains

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19
Q

C6 - Chemistry Out There

What is tin plating?

A

A coat of tin is applied to the object e.g. Food cans.

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20
Q

C6 - Chemistry Out There

How does tin plating prevent rusting?

A

Acts as a barrier, stopping water and oxygen from reaching iron surface.

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21
Q

C6 - Chemistry Out There

Tin plating only as long as…

A

Tin remains intact. If scratched, iron will lose electrons and rust even faster.

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22
Q

C6 - Chemistry Out There

Why is it not always a good idea to buy reduced bashed tins?

A

They could be starting to rust.

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23
Q

C6 - Chemistry Out There

How does the sacrificial method work?

A

Place a more reactive metal with the iron. Water and oxygen react with the sacrificial metal instead of iron.

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24
Q

C6 - Chemistry Out There

What is galvanising?

A

A coat of zinc put on object. Zinc is sacrificial protection - more reactive - loses electrons in preference to iron.

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25
# C6 - Chemistry Out There What sort of items are galvanised?
Steel buckets and corrugated iron roofing
26
# C6 - Chemistry Out There How can blocks of metal prevent rusting?
E.g. Magnesium can be bolted onto iron. Magnesium loses electrons in preference to iron.
27
# C6 - Chemistry Out There When are block of metal used on items?
Hulls of ships and underground iron pipes.
28
# C6 - Chemistry Out There What is oxidation?
Loss of electrons
29
# C6 - Chemistry Out There What does electrolysis mean?
Breaking down a substance with electricity
30
# C6 - Chemistry Out There How does electrolysis work?
Electric current passed through a molten or dissolved ionic compound, causing it to decompose. This creates a flow of charge through the electrolyte.
31
# C6 - Chemistry Out There What happens to the positive ions in electrolysis?
Move towards the cathode (-ve) and gain electrons.
32
# C6 - Chemistry Out There What happens to negative ions in electrolysis?
Move towards anode (+ve) and lose electrons
33
# C6 - Chemistry Out There What happens in electrolysis when ions lose or gain electrons?
They become atoms or molecules and are discharged from the solution at the electrodes.
34
# C6 - Chemistry Out There What is the ionic equation at the anode during electrolysis of copper (II) sulfate?
4OH- - 4e- → O2 + 2H2O
35
# C6 - Chemistry Out There What is the ionic equation at the cathode during electrolysis of copper (II) sulfate?
Cu2+ + 2e- → Cu
36
# C6 - Chemistry Out There What are ions are there in aqueous solutions?
Hydrogen ions (H+), hydroxide ions (OH-) and ions from the solute (ionic compounds)
37
# C6 - Chemistry Out There What is it sometimes easier to do in electrolysis?
Discharge ions from the water instead of from the solute
38
# C6 - Chemistry Out There What does discharging ions from the water instead of the solute do in electrolysis?
Produce hydrogen at the cathode and oxygen at the anode.
39
# C6 - Chemistry Out There What ions does a solution of aqueous sulfuric acid contain?
SO42- , H+ , OH-
40
# C6 - Chemistry Out There What is the equation at the cathode for electrolysis with sulfuric acid?
2H+ + 2e- → H2
41
# C6 - Chemistry Out There What is the equation at the anode for electrolysis with sulfuric acid?
4OH- - 4e- → O2 + 2H2O
42
# C6 - Chemistry Out There What reaction takes place at the anode?
Oxidation
43
# C6 - Chemistry Out There What reaction takes place at the cathode?
Reduction
44
# C6 - Chemistry Out There Where is hydrogen produced in electrolysis?
Cathode
45
# C6 - Chemistry Out There Where is oxygen produced in electrolysis?
Anode
46
# C6 - Chemistry Out There What is the reaction at the cathode for the electrolysis of copper(II) sulfate solution?
Cu2+ + 2e- → Cu
47
# C6 - Chemistry Out There What is the reaction at the anode for the electrolysis of copper(II) sulfate solution?
4OH- - 4e- -\> O2 + 2H2O
48
# C6 - Chemistry Out There What charge does the cathode have?
Negative
49
# C6 - Chemistry Out There What charge does the anode have?
Positive
50
# C6 - Chemistry Out There What happens when chlorine gas is passed through a solution of iron(II) salt?
Solution turns from green to yellow
51
# C6 - Chemistry Out There Why does the solution change colour when chlorine gas is passed through a solution of iron(II) salt?
Iron (II) ion is oxidised to iron (III). Fe2+ ion loses an electron to form Fe3+
52
# C6 - Chemistry Out There What causes the reaction to oxidise and turn a different colour when chlorine gas is passed through a solution of iron(II) salt?
Oxidising agent - chlorine gas
53
# C6 - Chemistry Out There What must be the reducing agent when chlorine gas is passed through a solution of iron(II) salt?
Iron (II) ion
54
# C6 - Chemistry Out There What happens to the chlorine when chlorine gas is passed through a solution of iron(II) salt?
Chlorine gains the electron Fe2+ lost. Chlorine reduced.
55
# C6 - Chemistry Out There When iron atoms are reacted with dilute acid how are iron (II) ions formed?
When iron atoms are oxidised.
56
# C6 - Chemistry Out There When iron atoms are reacted with dilute acid what happens to the iron atoms?
Lose electrons - oxidised by hydrogen ions
57
# C6 - Chemistry Out There When iron atoms are reacted with dilute acid what happens to the hydrogen atoms?
Gain electrons - reduced by iron atoms.
58
# C6 - Chemistry Out There What is the order of reactivity for zinc, iron, magnesium and tin/copper from most reactive to least reactive?
Magnesium, zinc, iron, tin/copper.
59
# C6 - Chemistry Out There What happens to metal ions in displacement reactions?
Gain electrons - are reduced
60
# C6 - Chemistry Out There What happens to the metal atoms in displacement reactions?
Loses electrons - are oxidised
61
# C6 - Chemistry Out There What happens between hard water and soap?
Doesn't lather. Makes scum
62
# C6 - Chemistry Out There What do you need to do to get a good lather with hard water?
Add more soap, use softer water.
63
# C6 - Chemistry Out There What does hard water form on pipes/kettles/boilers?
Limescale (calcium carbonate)
64
# C6 - Chemistry Out There What does limescale act as?
Thermal insulator
65
# C6 - Chemistry Out There How is a kettle with limescale different to a clean kettle?
Kettle with limescale in heating element will take longer to boil.
66
# C6 - Chemistry Out There What can limescale eventually do to pipes?
Block them
67
# C6 - Chemistry Out There What does hard water contain?
Calcium ions (Ca2+), magnesium ions (Mg2+), or both.
68
# C6 - Chemistry Out There What happens as water flows over rocks and through soil?
The soils/rocks contain Ca and Mg compounds - these ions dissolve in the water.
69
# C6 - Chemistry Out There What does magnesium sulfate dissolve in?
Water
70
# C6 - Chemistry Out There What does calcium carbonate commonly exist as?
Chalk, limestone and marble.
71
# C6 - Chemistry Out There Does calcium carbonate dissolve in water?
No but reacts with acids.
72
# C6 - Chemistry Out There How do we know rainwater is slightly acidic?
Carbon dioxide from air dissolves in rainwater forming carbonic acid.
73
# C6 - Chemistry Out There What is the word equation when rainwater reacts with carbon dioxide?
Carbon dioxide + water → carbonic acid
74
# C6 - Chemistry Out There What is the symbol equation when rainwater reacts with carbon dioxide?
CO2 + H2O -\> H2CO3
75
# C6 - Chemistry Out There What is the molecular formula of carbonic acid?
H2CO3
76
# C6 - Chemistry Out There What can rainwater react with to form calcium hydrogencarbonate?
Calcium carbonate
77
# C6 - Chemistry Out There What is the word equation for producing calcium hydrogencarbonate?
Carbon dioxide + water + calcium carbonate → calcium hydrogencarbonate
78
# C6 - Chemistry Out There What is the symbol equation for producing calcium hydrogencarbonate?
H2CO3 + CaCO3 → Ca(HCO3)2
79
# C6 - Chemistry Out There What are the two types of hardness?
Temporary and permanent
80
# C6 - Chemistry Out There What is temporary hardness caused by?
Hydrogencarbonate ion (HCO3-) in Ca(HCO3)2
81
# C6 - Chemistry Out There What is permanent hardness caused by?
Dissolved calcium sulfate (amongst other things)
82
# C6 - Chemistry Out There How is temporary hardness removed?
By boiling
83
# C6 - Chemistry Out There What does boiling do to temporary hardness?
Calcium hydrogencarbonate decomposes to form insoluble calcium carbonate.
84
# C6 - Chemistry Out There Why doesn't boiling remove permanent hardness?
Calcium carbonate precipitate (limescale) is insoluble
85
# C6 - Chemistry Out There What is the word equation for removing temporary hardness?
Calcium hydrogencarbonate → calcium carbonate + water + carbon dioxide
86
# C6 - Chemistry Out There What is the symbol equation for removing temporary hardness?
Ca(HCO3)2 (aq) → CaCO3 (s) + H2O (l) + CO2 (g)
87
# C6 - Chemistry Out There How can bot types of hardness be removed?
Using washing soda (sodium carbonate, NaCO3) or by 'ion exchange resin'.
88
# C6 - Chemistry Out There How does NaCO3 remove both types of hardness?
Carbonate ions join to calcium ions to make insoluble precipitate of calcium carbonate. Works whether hardness is due to calcium sulfate or calcium hydrogencarbonate.
89
# C6 - Chemistry Out There What is the ionic equation for removing hardness with sodium carbonate?
Ca2+ (aq) + CO32- (aq) → CaCO3 (s)
90
# C6 - Chemistry Out There How does 'ion exchange resin work'?
Lots of sodium ions (or hydrogen ions) and these are exchanged for calcium or magnesium ions.
91
# C6 - Chemistry Out There What is the method for comparing the hardness of water samples?
1. 100cm3 of water - conical flask 2. Add 1cm3 of soap solution. Bung in and shake. 3. Repeat until lasting lather formed (bubbles cover surface for at least 30 secs) 4. Record amount of soap needed.
92
# C6 - Chemistry Out There Gain of electrons
What is reduction?
93
# C6 - Chemistry Out There Accept electrons and gets reduced
What does an oxidising agent do?
94
# C6 - Chemistry Out There Donate electrons and get oxidised
What does a reducing agent do?
95
# C6 - Chemistry Out There One metal kicking another one out of a compound
What does displacement reactions involve?
96
# C6 - Chemistry Out There A more reactive metal will displace a less reactive metal from its compound
What is the rule for displacement reactions?
97
# C6 - Chemistry Out There When they come into contact with air and water
Why do some iron and steels rust?
98
# C6 - Chemistry Out There When iron is in contact with both water and oxygen
When does rusting of iron only occur?
99
# C6 - Chemistry Out There Hydrated iron (III) oxide
What is rust a form of?
100
# C6 - Chemistry Out There Iron + oxygen + water -\> hydrated iron (III) oxide
What is the equation for rusting?
101
# C6 - Chemistry Out There Redox
What type of reaction is rusting of iron?
102
# C6 - Chemistry Out There Loses electrons - oxidised. Each Fe atom loses 3 electrons to become Fe3+.
What happens to iron when it reacts with oxygen?
103
# C6 - Chemistry Out There Reduced. Each O atom gains 2 electrons to become O2-.
What happens to oxygen when it reacts with iron?
104
# C6 - Chemistry Out There Make alloys. Barrier. Tin coating/plating. More reactive metals (galvanising)
What are the 4 ways to prevent rusting?
105
# C6 - Chemistry Out There Iron with carbon and small quantities of other metals
What are steels alloys of?
106
# C6 - Chemistry Out There One of most common steels - rustproof alloy of iron, carbon and chromium.
What is stainless steel?
107
# C6 - Chemistry Out There Keeps out water, oxygen or both.
How does a barrier prevent rusting?
108
# C6 - Chemistry Out There Ideal for large and small structures. Nice and colourful.
How is painting ideal to prevent rusting?
109
# C6 - Chemistry Out There Has to be used when moving parts are involved e.g. Bike chains
How is oiling or greasing used to prevent rusting?
110
# C6 - Chemistry Out There A coat of tin is applied to the object e.g. Food cans.
What is tin plating?
111
# C6 - Chemistry Out There Acts as a barrier, stopping water and oxygen from reaching iron surface.
How does tin plating prevent rusting?
112
# C6 - Chemistry Out There Tin remains intact. If scratched, iron will lose electrons and rust even faster.
Tin plating only as long as...
113
# C6 - Chemistry Out There They could be starting to rust.
Why is it not always a good idea to buy reduced bashed tins?
114
# C6 - Chemistry Out There Place a more reactive metal with the iron. Water and oxygen react with the sacrificial metal instead of iron.
How does the sacrificial method work?
115
# C6 - Chemistry Out There A coat of zinc put on object. Zinc is sacrificial protection - more reactive - loses electrons in preference to iron.
What is galvanising?
116
# C6 - Chemistry Out There Steel buckets and corrugated iron roofing
What sort of items are galvanised?
117
# C6 - Chemistry Out There E.g. Magnesium can be bolted onto iron. Magnesium loses electrons in preference to iron.
How can blocks of metal prevent rusting?
118
# C6 - Chemistry Out There Hulls of ships and underground iron pipes.
When are block of metal used on items?
119
# C6 - Chemistry Out There Loss of electrons
What is oxidation?
120
# C6 - Chemistry Out There Breaking down a substance with electricity
What does electrolysis mean?
121
# C6 - Chemistry Out There Electric current passed through a molten or dissolved ionic compound, causing it to decompose. This creates a flow of charge through the electrolyte.
How does electrolysis work?
122
# C6 - Chemistry Out There Move towards the cathode (-ve) and gain electrons.
What happens to the positive ions in electrolysis?
123
# C6 - Chemistry Out There Move towards anode (+ve) and lose electrons
What happens to negative ions in electrolysis?
124
# C6 - Chemistry Out There They become atoms or molecules and are discharged from the solution at the electrodes.
What happens in electrolysis when ions lose or gain electrons?
125
# C6 - Chemistry Out There 4OH- - 4e- → O2 + 2H2O
What is the ionic equation at the anode during electrolysis of copper (II) sulfate?
126
# C6 - Chemistry Out There Cu2+ + 2e- → Cu
What is the ionic equation at the cathode during electrolysis of copper (II) sulfate?
127
# C6 - Chemistry Out There Hydrogen ions (H+), hydroxide ions (OH-) and ions from the solute (ionic compounds)
What are ions are there in aqueous solutions?
128
# C6 - Chemistry Out There Discharge ions from the water instead of from the solute
What is it sometimes easier to do in electrolysis?
129
# C6 - Chemistry Out There Produce hydrogen at the cathode and oxygen at the anode.
What does discharging ions from the water instead of the solute do in electrolysis?
130
# C6 - Chemistry Out There SO42- , H+ , OH-
What ions does a solution of aqueous sulfuric acid contain?
131
# C6 - Chemistry Out There 2H+ + 2e- → H2
What is the equation at the cathode for electrolysis with sulfuric acid?
132
# C6 - Chemistry Out There 4OH- - 4e- → O2 + 2H2O
What is the equation at the anode for electrolysis with sulfuric acid?
133
# C6 - Chemistry Out There Oxidation
What reaction takes place at the anode?
134
# C6 - Chemistry Out There Reduction
What reaction takes place at the cathode?
135
# C6 - Chemistry Out There Cathode
Where is hydrogen produced in electrolysis?
136
# C6 - Chemistry Out There Anode
Where is oxygen produced in electrolysis?
137
# C6 - Chemistry Out There Cu2+ + 2e- → Cu
What is the reaction at the cathode for the electrolysis of copper(II) sulfate solution?
138
# C6 - Chemistry Out There 4OH- - 4e- -\> O2 + 2H2O
What is the reaction at the anode for the electrolysis of copper(II) sulfate solution?
139
# C6 - Chemistry Out There Negative
What charge does the cathode have?
140
# C6 - Chemistry Out There Positive
What charge does the anode have?
141
# C6 - Chemistry Out There Solution turns from green to yellow
What happens when chlorine gas is passed through a solution of iron(II) salt?
142
# C6 - Chemistry Out There Iron (II) ion is oxidised to iron (III). Fe2+ ion loses an electron to form Fe3+
Why does the solution change colour when chlorine gas is passed through a solution of iron(II) salt?
143
# C6 - Chemistry Out There Oxidising agent - chlorine gas
What causes the reaction to oxidise and turn a different colour when chlorine gas is passed through a solution of iron(II) salt?
144
# C6 - Chemistry Out There Iron (II) ion
What must be the reducing agent when chlorine gas is passed through a solution of iron(II) salt?
145
# C6 - Chemistry Out There Chlorine gains the electron Fe2+ lost. Chlorine reduced.
What happens to the chlorine when chlorine gas is passed through a solution of iron(II) salt?
146
# C6 - Chemistry Out There When iron atoms are oxidised.
When iron atoms are reacted with dilute acid how are iron (II) ions formed?
147
# C6 - Chemistry Out There Lose electrons - oxidised by hydrogen ions
When iron atoms are reacted with dilute acid what happens to the iron atoms?
148
# C6 - Chemistry Out There Gain electrons - reduced by iron atoms.
When iron atoms are reacted with dilute acid what happens to the hydrogen atoms?
149
# C6 - Chemistry Out There Magnesium, zinc, iron, tin/copper.
What is the order of reactivity for zinc, iron, magnesium and tin/copper from most reactive to least reactive?
150
# C6 - Chemistry Out There Gain electrons - are reduced
What happens to metal ions in displacement reactions?
151
# C6 - Chemistry Out There Loses electrons - are oxidised
What happens to the metal atoms in displacement reactions?
152
# C6 - Chemistry Out There Doesn't lather. Makes scum
What happens between hard water and soap?
153
# C6 - Chemistry Out There Add more soap, use softer water.
What do you need to do to get a good lather with hard water?
154
# C6 - Chemistry Out There Limescale (calcium carbonate)
What does hard water form on pipes/kettles/boilers?
155
# C6 - Chemistry Out There Thermal insulator
What does limescale act as?
156
# C6 - Chemistry Out There Kettle with limescale in heating element will take longer to boil.
How is a kettle with limescale different to a clean kettle?
157
# C6 - Chemistry Out There Block them
What can limescale eventually do to pipes?
158
# C6 - Chemistry Out There Calcium ions (Ca2+), magnesium ions (Mg2+), or both.
What does hard water contain?
159
# C6 - Chemistry Out There The soils/rocks contain Ca and Mg compounds - these ions dissolve in the water.
What happens as water flows over rocks and through soil?
160
# C6 - Chemistry Out There Water
What does magnesium sulfate dissolve in?
161
# C6 - Chemistry Out There Chalk, limestone and marble.
What does calcium carbonate commonly exist as?
162
# C6 - Chemistry Out There No but reacts with acids.
Does calcium carbonate dissolve in water?
163
# C6 - Chemistry Out There Carbon dioxide from air dissolves in rainwater forming carbonic acid.
How do we know rainwater is slightly acidic?
164
# C6 - Chemistry Out There Carbon dioxide + water → carbonic acid
What is the word equation when rainwater reacts with carbon dioxide?
165
# C6 - Chemistry Out There CO2 + H2O -\> H2CO3
What is the symbol equation when rainwater reacts with carbon dioxide?
166
# C6 - Chemistry Out There H2CO3
What is the molecular formula of carbonic acid?
167
# C6 - Chemistry Out There Calcium carbonate
What can rainwater react with to form calcium hydrogencarbonate?
168
# C6 - Chemistry Out There Carbon dioxide + water + calcium carbonate → calcium hydrogencarbonate
What is the word equation for producing calcium hydrogencarbonate?
169
# C6 - Chemistry Out There H2CO3 + CaCO3 → Ca(HCO3)2
What is the symbol equation for producing calcium hydrogencarbonate?
170
# C6 - Chemistry Out There Temporary and permanent
What are the two types of hardness?
171
# C6 - Chemistry Out There Hydrogencarbonate ion (HCO3-) in Ca(HCO3)2
What is temporary hardness caused by?
172
# C6 - Chemistry Out There Dissolved calcium sulfate (amongst other things)
What is permanent hardness caused by?
173
# C6 - Chemistry Out There By boiling
How is temporary hardness removed?
174
# C6 - Chemistry Out There Calcium hydrogencarbonate decomposes to form insoluble calcium carbonate.
What does boiling do to temporary hardness?
175
# C6 - Chemistry Out There Calcium carbonate precipitate (limescale) is insoluble
Why doesn't boiling remove permanent hardness?
176
# C6 - Chemistry Out There Calcium hydrogencarbonate → calcium carbonate + water + carbon dioxide
What is the word equation for removing temporary hardness?
177
# C6 - Chemistry Out There Ca(HCO3)2 (aq) → CaCO3 (s) + H2O (l) + CO2 (g)
What is the symbol equation for removing temporary hardness?
178
# C6 - Chemistry Out There Using washing soda (sodium carbonate, NaCO3) or by 'ion exchange resin'.
How can bot types of hardness be removed?
179
# C6 - Chemistry Out There Carbonate ions join to calcium ions to make insoluble precipitate of calcium carbonate. Works whether hardness is due to calcium sulfate or calcium hydrogencarbonate.
How does NaCO3 remove both types of hardness?
180
# C6 - Chemistry Out There Ca2+ (aq) + CO32- (aq) → CaCO3 (s)
What is the ionic equation for removing hardness with sodium carbonate?
181
# C6 - Chemistry Out There Lots of sodium ions (or hydrogen ions) and these are exchanged for calcium or magnesium ions.
How does 'ion exchange resin work'?
182
# C6 - Chemistry Out There 1. 100cm3 of water - conical flask 2. Add 1cm3 of soap solution. Bung in and shake. 3. Repeat until lasting lather formed (bubbles cover surface for at least 30 secs) 4. Record amount of soap needed.
What is the method for comparing the hardness of water samples?