Carbohydrates Flashcards

1
Q

What is the primary function of carbohydrates

A

Provide the body with energy (ATP)

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2
Q

Most of the carbohydrates you eat are digested and broken down into …

A

Glucose

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3
Q

Excess glucose can be stored for later use as

A

Glycogen. (animals)

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4
Q

Why can indigestible carbohydrates be good for our health?

A

Create soft, bulky stool that easily moves through the large intestine. Helps delay the absorption of other carbs in your digestive tract, thereby preventing blood glucose spikes.

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5
Q

Carbohydrates are made up of smaller units called

A

Monosccharides.

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6
Q

Monosaccharides consist of

A

Carbon, hydrogen and oxygen.

In general, they have one carbonyl group C=O and the remaining carbons each bear 1 hydroxyl group -OH.

Carbonyl can vary in location (aldose connected to H, usually on the end and ketones connected to something other than H. Usually in the middle.)

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7
Q

How to name monosaccharides based on the number of carbons

A

3- triose
4- tetrose
5- pentose
6- hexose

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8
Q

Glyceraldehyde is a

A

Triose

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9
Q

Ribose is a

A

Pentose

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10
Q

Glucose is a

A

Hexose

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11
Q

Oligosaccharides

A

A carbohydrate whose molecules are composed of a relatively small number of monosaccharide units. (3-12 monosaccharides)

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12
Q

In order to form disaccharides, oligosaccharides and polysaccharides, monosaccharides under go ____ reactions

A

Condensation reactions. Specifically, dehydration reactions. The joining of two molecules with the loss of water.

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13
Q

Glycosidic bonds

A

Bond formed between a hydroxyl group of one molecule and the anomeric carbon of another.

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14
Q

Anomeric carbon

A

CHOH. This carbon derived from the carbonyl carbon (ketone or aldehyde)

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15
Q

Carbohydrates tend to form ring structures in which kind of solution

A

Aqueous due to acid and bases in the water. In water, the ring can open and form spontaneously. Alpha or beta products can be produced.

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16
Q

3 disaccharides

A
Maltose= glucose + glucose 
Sucrose= glucose + fructose 
Lactose= galactose + glucose
17
Q

Difference between glycoproteins and glycosaminoglycan

A

Glycoproteins are majorly composed of proteins.

Glycosaminoglycans are majorly composed of sugars.

18
Q

What type of bond is a glycosidic bond

A

Covalent

19
Q

Examples of oligosaccharides

A

Immunoglobin, mucin

20
Q

Where are oligosaccharides primarily located

A

On the surface of cells or in the extracellular matrix

21
Q

Oligosaccharides vs polysaccharides

A

Oligosaccharides consist of 3-12 monosaccharides and polysaccharides consist of 12 or more

22
Q

Characteristics of glycogen

A

Composed of alpha glucose monomers with extensive branching. Storage form of glucose in animals. Located mainly in liver and muscle.

23
Q

Starch

A

Composed of alpha glucose monomers with branching (amylopectin) or without branching/linear (amylose). This is the storage form of glucose in plants.

24
Q

Cellulose

A

Composed of beta-glucose monomers with no branching. Humans are unable to digest cellulose due to lack of enzymes that are able to break down beta-glucose linkages. Instead, this contributes to the formation of dietary fiber.

25
Q

Other names for glycosaminoglycans

A

GAGs, mucopolysaccharides

26
Q

What are glycosaminoglycans composed of

A

Repeating disaccharide units - amino sugar and ironic acid OR galactose without branching.

27
Q

5 GAGs

A
Chondroitin sulfate - most abundant GAG
Keratin sulfate
Dermatan sulfate
Heparan sulfate
Hyaluronate (only GAG that is not sulfated)
28
Q

Characteristics of GAGs

A

Highly negatively charged. Attracts water. Functions as a high lubricant or shock absorber due to its high viscosity and low compressibility.

29
Q

Role in the body

A

Primarily located on the surface of cells or in the ECM. Fills the space of the ECM in the form of hydrated gel.

30
Q

Most GAGs, with the exception of hyaluronate, are linked to a core protein, forming ___

A

A proteoglycan. GAGs extend perpendicular from the core protein in a bottle brush-like structure. Examples- aggrdcan, lumina, keratocan, mimican, decor

31
Q

What GAG cannot bind to protein to form a proteoglycan?

A

Hyaluronate

32
Q

Difference between alpha and beta linkage

A

Beta is up in the air (birds in the sky) and alpha is pointed down (fish in the sea.. bc alpha looks like a fish)