CHAPTER 23.2 Flashcards

(58 cards)

1
Q

________ are organic compounds with a hydroxyl group

A

Alcohol

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2
Q

Aliphatic alcohols can be classified as ______,_____ or ________

A

Primary, secondary or tertiary

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3
Q

Organic compounds who’s general formula can be written as R-O-R are called ________

A

Ethers

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4
Q

Ethers usually have ______ boiling points than alcohols of comparable formula mass

A

Lower

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5
Q

T or F? The addition of water to an alkene is called a hydration reaction

A

True

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6
Q

T or F? Hydrogenation of a double bond is an oxidation reaction

A

False

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7
Q

T or F?The benzene ring usually undergoes addition rather than substitution

A

False

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8
Q

Hydration reaction

A

The addition of water to an alkene

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9
Q

Fermentation

A

The production of ethanol from sugars by the action of yeast or bacteria

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10
Q

Alcohols

A

A class of organic compounds whose structures contain an -OH group

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11
Q

Addition

A

The reaction of HBr with propene for form 1-bromopropane

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12
Q

Hydrogenation

A

The reaction of hydrogen with butene to form butane

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13
Q

What is a hydroxyl group?

A

The -OH functional group in alcohols

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14
Q

Aliphatic alcohols can be classified into structural categories according to _______________

A

The number of R groups attached yo the carbon with the hydroxyl group

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15
Q

When using the IUPAC system to name continuous chain substituted alcohols, drop the _______ ending of a parent alkane name and the ending _________

A

-e
-ol

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16
Q

The parent alkane is the longest continuous chain of C that __________ the C attached of the hydroxyl group

A

Includes

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17
Q

The parent alkane is the longest continuous chain of C that __________ the C attached of the hydroxyl group

A

Includes

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18
Q

In numbering the longest continuous chain, the position of the _____________ is given the lowest possible number

A

Hydroxyl group

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19
Q

Alcohols containing two, three, and four -OH substituents are named ______________ _ respectively

A

Diols, triols and tetrals

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20
Q

What are glycols

A

Compounds with more than one -OH substituents

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21
Q

Alcohols are capable of ____________. Therefore, they boil at ________ temperatures than alkanes and halocarbons containing comparable numbers of atoms

A

Intermolecular hydrogen bonding
Higher

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22
Q

Because alcohols are derivatives of water they are somewhat _________

A

Soluble

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23
Q

Alcohols of up to ________ carbons are soluble in water in all proportions

A

Four

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24
Q

The carbon chain is ________ and is not attached to water. The hydroxyl group is ______ and strongly interacts with water through hydrogen bonding

A

Nonpolar
Polar

25
For alcohols of up to four carbons, the polarity of the hydroxyl group is more significant than the nonpolarity of the carbon chain these alcohols are?
Soluble in water
26
As the number of carbon atoms increase above four, the nonpolarity of the chain becomes more significant and the ___________ decreases
Solubility
27
What is fermentation?
The production of ethanol from sugars by the action of yeast or bacteria
28
Ethanol is the ___________ in alcoholic beverages
Intoxication substance
29
In an ____________ a substance is added at the double or triple bond of an alkene or alkyne
Addition reaction
30
The additional of a water to an alkene is a _________
Hydration reaction
31
Hydrogen halides can also be added to a double bond. The product is called a ________________ because it only has one substituent
Monosubstituted halocarbon
32
The addition of a hydrogen to a carbon carbon double bond to produce an alkane is called a __________
Hydrogenation reaction
33
Hydrogenation reactions often require ________
A catalyst
34
The hydrogenation of a double bond is a
Reduction reaction
35
Under normal conditions, benzene resists __________ it also resists the addition of a _____ or a _______
Hydrogenation Halogen Hydrogen halide
36
What is an ether
A compound in which oxygen is bonded to two carbon groups
37
The general structure for an ether is
R - O - R
38
When both groups are the same the ether is symmetric. Symmetric ethers are named using
The prefix di-
39
Ethers usually have ________ boiling points than alcohols of comparable molar mass
Lower
40
Ethers have ________ boiling points than comparable hydrocarbons and halocarbons
Higher
41
Ethers form _______ hydrogen bonds than hydrocarbons and halocarbons but ________ than alcohols
More Fewer
42
______ are organic compounds with a hydroxyl group
Alcohol
43
Aliphatic alcohols can be classified as ______, _______ or _______ alcohols depending on the number of R groups attached to the carbon with the hydroxyl group.
Primary Secondary Tertiary
44
For example 2-propanol represents a ________ alcohol
Secondary
45
In general, alcohols are more soluble in water than alkanes containing comparable numbers of atoms because they are capable of intermolecular ________
Hydrogen bonding
46
Alcohols can be prepared from alkenes by a ______ reaction
Hydration
47
In a hydration reaction ______ is added at the carbon carbon double bond of the alkene
Water
48
Another form of addition reaction is ______
Hydrogenation
49
In hydrogenation which is catalyzed by platinum or palladium, hydrogenation is added to the carbon carbon double bonds in a molecule to produce an ______
Alkane
50
Organic compounds whose general formula can be written as R-O-R are called ______
Ethers
51
Ethers usually have ______ boiling points than alcohols of comparable formula mass
Lower
52
T or F the addition of water to an alkene is called a hydration reaction
True
53
T or F hydrogenation of a double bond is an oxidation reaction
False
54
T or F the benzene ring usually undergoes addition rather than substitution
False
55
Hydration reaction
The addition of water to an alkene
56
Fermentation
The production of ethanol from sugars by the action of yeast or bacteria
57
Alcohols
A class of organic compounds whose structures contain an -OH group
58
Hydrogenation
The reaction of hydrogen with butene to form butane