Chapter 3: Functional Groups Flashcards
(32 cards)
functional group
an atom or group of atoms with characteristic chemical and physical properties
functional groups are attached to
carbon backbones made of C-C and C-H
heteroatoms
atoms other than C or H
pi bonds
most commonly found in C-C and C-O double bonds
function groups determine
geometry
physical properties
reactivity
heteroatoms
have higher electronegative, creates electron deficient sites on carbon with their lone pairs
hydrocarbons
anything that is only made of hydrogen and carbons
types of hydrocarbons
alkanes
alkenes
alkynes
aromatic
ion ion intermolecular forces
oppositely charged particles
very strong
ionic bonds
van der waals forces
london forces,
very weak,
caused by momentary changes in electron density,
in all compounds
dipole dipole intermolecular forces
permanent between 2 polar molecules
alignment of oppositely partial charges
stronger than weak vanderwals
net dipole moment
hydrogen bonding
H bonded O, F, N
strongest
when the surface area is large the intermolecular forces are (stronger / weaker)
stronger
when the polarity is high the strength of intermolecular forces
increases
boiling point
temp required to get liq to gas
strong intermolecular forces have what effect on boiling points
makes them increase
bigger surface area (increases / decreases) boiling point
increases
melting point
the temperature at which solid turns to liquid
strong intermolecular forces do what to melting point
increase
the more symmetrcal a fucntional group is
the higher the melting point
solubility
the amount of energy needed to break interactions between molecules or ions of the solute
like dissolves
like
ionic compounds solubilty
most are soluble in water
most insoluble in org. compounds
ion-ion has to be replaced by ion-dipole
organic compound solubilty
soluble in water if it contians one polar functional group for every 5 carbons