Chapter 3: Functional Groups Flashcards

(32 cards)

1
Q

functional group

A

an atom or group of atoms with characteristic chemical and physical properties

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2
Q

functional groups are attached to

A

carbon backbones made of C-C and C-H

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3
Q

heteroatoms

A

atoms other than C or H

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4
Q

pi bonds

A

most commonly found in C-C and C-O double bonds

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5
Q

function groups determine

A

geometry
physical properties
reactivity

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6
Q

heteroatoms

A

have higher electronegative, creates electron deficient sites on carbon with their lone pairs

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7
Q

hydrocarbons

A

anything that is only made of hydrogen and carbons

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8
Q

types of hydrocarbons

A

alkanes
alkenes
alkynes
aromatic

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9
Q

ion ion intermolecular forces

A

oppositely charged particles
very strong
ionic bonds

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10
Q

van der waals forces

A

london forces,
very weak,
caused by momentary changes in electron density,
in all compounds

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11
Q

dipole dipole intermolecular forces

A

permanent between 2 polar molecules
alignment of oppositely partial charges
stronger than weak vanderwals
net dipole moment

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12
Q

hydrogen bonding

A

H bonded O, F, N
strongest

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13
Q

when the surface area is large the intermolecular forces are (stronger / weaker)

A

stronger

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14
Q

when the polarity is high the strength of intermolecular forces

A

increases

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15
Q

boiling point

A

temp required to get liq to gas

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16
Q

strong intermolecular forces have what effect on boiling points

A

makes them increase

17
Q

bigger surface area (increases / decreases) boiling point

18
Q

melting point

A

the temperature at which solid turns to liquid

19
Q

strong intermolecular forces do what to melting point

20
Q

the more symmetrcal a fucntional group is

A

the higher the melting point

21
Q

solubility

A

the amount of energy needed to break interactions between molecules or ions of the solute

22
Q

like dissolves

23
Q

ionic compounds solubilty

A

most are soluble in water
most insoluble in org. compounds
ion-ion has to be replaced by ion-dipole

24
Q

organic compound solubilty

A

soluble in water if it contians one polar functional group for every 5 carbons

25
hydrophobic
not attracted to water
26
hydrophyllic
attracted to water
27
cholesterol
is both hydrophyllic and hydrophobic
28
vitamins
organic compounds that are needed in small amount but cannot be synthesized by the body, must be obtained through diets
29
vitamin A (retional)
helps with vision, found in carrots, water insoluble
30
Vitamin C (asorbic acid)
helps with the formation of collagen, citrus fruits, water-soluble
31
soap
polar head and nonpolar fatty acid tail, the polar head will interact with the water and break off of the fatty acid tail, the tail will absorb all of the dirt
32
crown ethers
cyclic ethers with a lot of oxygen atoms that bind to specific cations depending on their cavity size