chapter 9 Flashcards

1
Q

If it has more energy, does it make it less or more stable?

A

less stable

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2
Q

thermochemistry definition

A

absorption or release of heat energy that accompanies chemical reactions

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3
Q

if it has less energy, is it more or less stable

A

it is more stable

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4
Q

define energy

A

capacity to do work or supply heat (kinetic or potential)

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5
Q

define joule

A

SI unit for energy

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6
Q

What is kinetic energy

A

energy of motion

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7
Q

What is potential energy

A

stored energy

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8
Q

conservation of energy law

A

energy can’t be created or destroyed, only be converted into another form

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9
Q

define temperature

A

thermal energy (kinetic) of molecular motion

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10
Q

define heat

A

amount of thermal energy transferred from one object to another as a result in a temp difference between the two.

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11
Q

what is the first law in thermodynamics

A

energy can’t be created or destroyed, only converted from one to another.

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12
Q

define system

A

starting reactants and final products of the experiment

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13
Q

define surroundings

A

everything but the system (EX: flask, solvent, room)

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14
Q

define internal energy

A

sum of all kinetic and potential energies for every molecule, in the system of an isolated system

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15
Q

is it possible to completely isolate a chemical reaction from its surroundings

A

no

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16
Q

How do you calculate internal energy

A

energy final minus energy initial

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17
Q

if energy flows from a system to its surroundings, is it positive or negative?

18
Q

internal energy depends on what?

A

identity, pressure, size, state, temperature

19
Q

if energy flows from its surroundings to a system, is it positive or negative?

20
Q

state function

A

property whose value depends only on present state, condition, not path to get there.

21
Q

energy content in food is measure in?

22
Q

define work

A

fore that produced movement times distance the object moved.

23
Q

thermal chemical equation

A

chemical equation with enthalpy change

24
Q

what is enthalpy change

A

amount heat released or absorbed when reactants convert to products

25
thermodynamic standard state
most stable form of a substance at 1 atm pressure and at a specified pressure, usually 25 degrees C, 1M concentration for all substances in a solution
26
standard enthalpy of reaction
enthalpy change under standard conditions
27
endothermic
reactions in which the system gains heat
28
exothermic
reactions that lose heat to their surroundings
29
enthalpy of fusion
amount of heat necessary to melt a substance without changing its temperature
30
enthalpy of vaporization
amount of heat required to vaporize a substance without changing its temperature
31
sublimation
the direct conversion of a solid to a vapor at atm pressure without first melting it to a liquid
32
calorimeter
device that can measure amount of heat transferred during a reaction
33
bomb calorimeter
measures heat released during combustion reaction or flammable substance
34
heat capacity
amount of heat required to raise temperature of a substance
35
extensive property
depends on size and amount
36
specific heat
amount of heat necessary to raise the temperature of a given object
37
molar heat capacity
amount of heat necessary to raise the temp of 1 mol by 1 degree Celsius
38
hess's law
the overall enthalpy for a reaction is equal to the sum to the enthalpy changes for the individual steps in the reaction
39
standards heats of formation
the enthalpy changes for the formation of 1 mol in its standards state from its constituent elements in their standard states
40
rules for standard heat of formation
often the reaction is hypothetical and must be in stable form
41
define bond dissociation energy
amount of energy supplied to break a chemical bond