Chapter 9 - Carboxylic Acid Derivatives Flashcards
(9 cards)
Amides
Condensation products of carboxylic acids and ammonia or amines
- Suffix -amide
Lactams
Cyclic amides
Esters
Condensation products of carboxylic acids with alcohols
- Suffix -oate
Lactones
Cyclic esters
Anhydrides
Condensation dimers of carboxylic acids
Steric hindrance
Describes when a reaction cannot proceed because of substituents crowding the reactive site
Induction
Refers to uneven distribution of charge across a sigma bond because of differences in electronegativity
Conjugation
Refers to the presence of alternating single and multiple bonds, which creates delocalized pi electron clouds above and below the plane of the molecule
Transesterification
Exchange of one esterifying group for another on an aster