chem in the environment Flashcards

1
Q

what are the chemical tests for water

A

anhydrous cobalt chloride
anhydrous copper sulfate

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2
Q

what is the positive result of this test

(cobalt chloride)

A

cobalt chloride paper turns blue to pink on addition of water

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3
Q

what is the chemical reaction for this test

(cobalt chloride)

A

cocl2 + 6h2o <—-> cocl2.6h2o

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4
Q

what is the positive result of the anhydrous copper sulfate test

A

anhydrous copper sulfate turns white to blue on the addition of water

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5
Q

what is the reaction for this test

(copper sulfate)

A

CuSo4 + 5h2o <—-> CuSo4.5h2o

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6
Q

how to test for the purity of water

A

pure substances melt and boil at specific temperatures
pure water boils at 100 deg cel
pure water melts at 0 deg cel
impurities tend to increase the boiling temp and decrease the melting temp
so impure water would boil at a temperature higher than 100 and melt at a temperature lower than 0

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7
Q

what is distilled water useful for

A

Distilled water is used in practical chemistry because of its high purity

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8
Q

why is tap water not used in practical chemistry

A

Tap water contains more impurities which could interfere with chemical reactions so is typically not used

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9
Q

how can water be obtained from natural sources

A

lakes, rivers and underground water sources (groundwater)

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10
Q

what is an aquifer

A

A rock that stores water

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11
Q

what can water obtained from natural sources contain

A

Dissolved oxygen
Metal compounds
Plastics
Sewage
Harmful microbes
Nitrates from fertilisers
Phosphates from fertilisers and detergents

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12
Q

which substance found in natural source water can be beneficial

A

Dissolved oxygen - essential for aquatic life
Metal compounds - some provide essential minerals which are necessary for life, such as calcium and magnesium

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13
Q

which subtance found in natural source water can be fatal

A

Metal compounds - some are toxic like aluminium and lead

Some plastics - may be harmful to aquatic life in many ways, e.g. getting trapped in plastic waste, dying of starvation as their stomach is filled with plastic

Sewage - contains harmful microbes which can cause disease

Nitrate & phosphates from fertilisers - these can promote the growth of aquatic plant life which leads to the deoxygenation of water. Ultimately, this can cause damage to aquatic life in a process called eutrophication

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14
Q

some metal compounds can be beneficial some can be fatal
which is which

A

calcium, magnesium, potassium and sodium are all metals which are essential for life

lead, arsenic and mercury can be fatal to humans and aquatic life

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15
Q

what are the steps to purify water

A

-Water is pumped into screens to remove solid insoluble impurities

-Aluminium sulfate or Iron (III) Sulfate (COAGULANTS) is added to make fine suspended particles clump together

  • air is blown in through water in flotation tanks so that coagulated particles can be SKIMMED off.

-The water is then filtered through layers of sand and gravel to remove larger, insoluble debris.

-filter water using carbon will remove bad tastes and odours

-Chlorine gas is bubbled into the water to kill bacteria; the acidic effect on the water is reversed by adding an alkali, sodium hydroxide

-Some countries add fluoride to help fight tooth decay

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16
Q

what are the steps of purification of water called

A

Sedimentation - letting particles falling to the bottom of the container.

Flocculation - addition of a COAGULANT (aluminium sulfate, iron (III) sulfate, etc) to make the smaller particles stick together

filtering through carbon will remove tastes and odours

Chlorination - usage of chlorine to kill bacteria

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17
Q

what elements do artificial fertilizers contain and each elements uses

A

nitrogen - chlorophyll and other proteins
Phosphorus - root growth and crop ripening
potassium - making proteins and to resist diseases

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18
Q

what is a fertilizer

A

any substance added to soil to make it more fertile

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19
Q

what are the reactions to make fertilizers

A

NH3 + HNO3 —-> NH4NO3
Ammonia + Nitric Acid –> Ammonium Nitrate

3NH3 + H3PO4 ——> (NH4)3PO4
Ammonia + Phospheric Acid —> Ammonium Phospate

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20
Q

what is the composition of air

A

78% nitrogen (N2)
21% oxygen (O2)
the remainder is a mixture of noble gasses and CO2

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21
Q

what is the main source of carbon monoxide and the negative impact of it on the environment

A

incomplete combustion of carbon-containing substances
binds with haemoglobin, constricting oxygen supply in cells; leads to fatigue/death. toxic

22
Q

what is the main source of sulfur dioxide and its negative impact on the environment

A

hydrocarbons burned with sulfur impurities/compounds
causes acid rain and bronchospasm in asthmatics

23
Q

what is the main source of nitrogen oxides and its negative impact on the environment

A

high temperatures (eg car engine) that trigger a reaction between N2 and O2

causes respiratory problems

photochemical smog when uv light from sun reacts with the oxides

contributes to acid rain

24
Q

what are the main source of lead and its negative impact on the environment

A

combustion of leaded fuels
Damages brain and nerve cells in young children

25
what is the main source of methane and its negative impact on the environment
-Sources of methane: oil and natural gas, decomposition of vegetation, and waste gases from digestion in animals greenhouse gas-- > contributes to global warming
26
what is the main source of carbon dioxide and its negative impact on the environment
complete combustion of carbon-containing compounds global warming/climate change
27
how do greenhouse gasses (carbon dioxide and methane) cause global warming?
Trap heat inside Earth’s atmosphere, increasing it’s average temperature. Leads to climate change Causes global warming, melting of polar-caps, rising sea levels, floods and droughts
28
what are other ways can carbon dioxide be formed
Respiration Reaction between an acid and a carbonate Complete combustion of a carbon containing substance Thermal decomposition of limestone
29
what are the steps of fractional distillation of air
-Air is filtered for dust -Cooled to -80℃ to remove CO2 and water vapour (because they would freeze and block the pipes) using absorbent filters. -Remaining air is cooled to liquify at -200℃. The Noble gases are still in the gaseous state and are removed. -The (liquid) air, consisting of NO2 and O2, is pumped into the fractional column where it is slowly warmed. -The remaining components rise and condense in different fractions due to different boiling points and are collected.
30
what is a catalytic converter and how does it work
Present in car exhausts; contains transition metal catalysts of platinum and rhodium Aids redox reactions to neutralize toxic pollutants formed as a result of incomplete fuel combustion. (a) Carbon monoxide (b) Nitrogen oxides (c) Unburned hydrocarbons Reaction equations: (a) 2CO+ O2→ CO2 (b) 2NO+ 2CO→ N2+ 2CO2 (c) 2C8H18 + 25O2→ 16CO2 + 18H2O
31
ways to counteract climate change
planting trees reduction in livestock farming decreasing use of fossil fuels increasing use of hydrogen and renewable energy
32
ways to counteract acid rain
use of catalytic converters in vehicles reducing emissions of sulfur dioxide by using low-sulfur fuels and flue gas desulfurisation with calcium oxide
33
Describe photosynthesis
reaction between carbon dioxide and water to produce glucose and oxygen in the presence of chlorophyll and using energy from light inorganic substances to organic compounds
34
Word eqn for photosynthesis chemical eqn
carbon dioxide + water → glucose + oxygen 6CO2 + 6H2O → C6H12O6 + 6O2
35
what are the necessary elements in a fertilizer
nitrogen phosphorus potassium
36
why is carbon monoxide considered a pollutant
it is toxic
37
is carbon monoxide basic, acidic or neutral
is a neutral oxide
38
how is flue gas desulfurization done
sprinkle calcium hydroxide in chimneys of factories
39
what is the reaction in flue gas desulfurisation
so2 + ca(oh)2 ---> caso3 + h2o
40
what is done to calcium sulfide so it can be converted to a more useful form
react with water and oxygen to form gypsum, used for castings and blasters 2caso3 + 4h2o + o2 ----> 2Caso4.2h2o
41
Products of oxidation of methane
Carbon dioxide Water
42
some industrial uses of water
Contact process - sulfuric acid Production of hydrogen - electrolysis Hydration of alkenes to form alcohols
43
How is rain water treated before entering water supply
(past paper q) filtration chlorination
44
Acid rain question - what does sulfuric dioxide form what does nitric dioxide form
sulfuric dioxide - sulfuric acid nitric dioxide - nitric acid
45
calcium oxide and calcium carbonate can both neutralise acid (desulfurisation) Why is calcium oxide a better way to desulphurize than calcium carbonate
calcium oxide is soluble in water calcium carbonate is insoluble calcium oxide can raise the pH of the water above 7 making it alkaline calcium carbonate cannot
46
where could seaweed obtain the following while growing: Carbon hydrogen chlorine
CO2 H2O Sea water - NaCl (salt)
47
2 compounds in unpolluted air
Carbon dioxide Water
48
harmful effects of acid rain name 3
damage buildings soil acidification acidify lakes kill fish damage trees crop loss
49
3 bases to increase ph of soil
calcium hydroxide calcium oxide calcium carbonate
50
Why is ammonium nitrate prefered over other fertilizers such as ammonium sulfate
More nitrogen in Ammonium Nitrate
51
State the essential plant nutrient not supplied by ammonium phosphate.
Potassium
52
Why could a fertilizer like urea (CO(NH2)2) not be effective in promoting crop growth
only has nitrogen no phosphorous or potassium