Chemical Changes Part 2 Flashcards

(30 cards)

1
Q

what is electrolysis

A

when an ionic compound splits into its elements using electricity

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2
Q

in which states can sodium chloride do electrolysis + why

A

molten and solution
ions are free to move

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3
Q

process of electrolysis in molten sodium chloride

A
  • sodium ion moves to the cathode because oposites attract
  • chloride ion moves to the positive electrode because opposites attract
  • sodium ion gains an electron to become a sodium atom. this is reduction.
    -chloride ion loses an electron to become a chlorine atom. this is oxidation.
    -sodium is made - silver solid
  • chlorine is made - pale green gas and bubbles
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4
Q

what is an electrolyte

A

an ionic compound you need to separate

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5
Q

what are the electrodes made from

A

an inert substance (graphite or platinum)

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6
Q

what are the uses of aluminium

A

foil
planes
cans

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7
Q

what are the properties of aluminium

A

low density
conducts electricity
resistant to corrosion
malleable
conducts heat

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8
Q

what happens in electrolysis of molten aluminium oxide

A
  • separates in to Al 3+ and O 2-
  • O2- will move to the positive electrode
  • Al 3+ will move to the negative electrode
  • aluminium is made at the negative electrode
  • the oxide ion moves to the positive electrode but oxygen is not given off as it reacts with the carbon electrode to make carbon dioxide which is given off.
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9
Q

what are the issues of using aluminium oxide

A

it needs a lot of energy and costs a lot of money (needs to be heated to 2500 degrees)

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10
Q

how is the use of aluminium oxide made cheaper

A

they mix aluminium oxide with cryolite which lowers the melting point to 800 degrees and so it needs less energy

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11
Q

how many ions are in the beaker in solutions

A

4 ions

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12
Q

what are the steps of electrolysis of a solution

A

1- four ions in the beaker
2- ions move to the electrodes
3- ions are discharged
4- write half equations for each electrode
5- what is left in the container

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13
Q

how do you work out which ion will be discharged at the electrodes

A

use the rules

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14
Q

what are the rules for ionic solutions at the anode

A

if -ions are halogens the halogen is made
if - ions are not halogens oxygen is produced

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15
Q

what are the rules for ionic solutions at the cathode

A

if +ions (metals) are more reactive than hydrogen then hydrogen is produced
if +ions (metals) are less reactive than hydrogen then the metal is produced

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16
Q

what is inside a cell

A

chemicals that react together to produce electricity
the reactants create a supply of chemical potential energy

17
Q

how can a simple cell be made

A

dipping two different pieces of metal into a solution of ions which act as an electrolyte
the reaction between the two metals generate a voltage which can be measured using a voltmeter

18
Q

what determines the size of the voltage

A

concentration of the electrolyte
temperature of the electrolyte
type of electrolyte
type of electrode (which metals are used)

19
Q

what does the bigger the difference in reactivity of the metals mean

A

the bigger the voltage

20
Q

what produces no voltage

A

electrodes of the same material

21
Q

when will the voltage be a negative number

A

if an electrode is less reactive than the other metal

22
Q

example of rechargeable batteries

A

mobile phones
laptops

23
Q

properties of rechargeable batteries

A

can not be recharged
this is because the reaction used in the cells is reversible
the reaction will reverse when an electric current is applied

24
Q

examples of non rechargeable batteries

A

scales
remote control

25
properties of non rechargeable batteries
cannot be recharged this is because the reaction used in the cells is irreversible this reaction will stop when one of the reactants have been used up
26
how do fuel cells work
because a fuel (eg hydrogen ) is constantly supplied with a supply of oxygen the hydrogen is oxidised to make water
27
what are fuel cells an alternative to
using rechargeable batteries and cells
28
what is the process of a fuel cell
hydrogen and oxygen are pumped into the fuel cell the hydrogen atoms lose electrons and flow through the barrier the electrons move round the circuit which generates a current at the anode the electrons join with oxygen and hydrogen ions to produce water
29
advantages of using hydrogen fuel cells over rechargeable cells
faster to refuel than recharging lasts longer hydrogen can be renewable produces a constant voltage no toxic chemicals released no carbon dioxide given off
30
disadvantages of using hydrogen fuel cells over rechargeable cells
hydrogen is made from fossil fuels hydrogen is made from non renewable resources hydrogen is difficult to store hydrogen is flammable / explosive costs more to refuel than recharge costs more to manufacture not many hydrogen filling stations