chp 2 general chem DAT Flashcards

(40 cards)

1
Q

atomic symbols -

A
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2
Q

left bottom number

A

protons

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3
Q

left top number

A

atomic mass

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4
Q

atomic mass =

A

protons + neutrons

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5
Q

neutrons =

A

atomic mass - protons

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6
Q

electrons =

A

protons = electrons
unless element has a charge then sub or add the charge

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7
Q

bohr model of the atom

A

1913 Niels Bohr created the first working model of hydrogen atom

  • as energy moves up the next shell , the shell gets smaller and further from the nucleus
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8
Q

what is quantization ?

A

the concept that a physical quantity, like energy, can only exist in discrete, specific values

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9
Q

what are electrons ?

A

they zoom through 3D atomic or molecular orbitals

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10
Q

4 types of orbital

A

S,P,D,F

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11
Q

s orbital

A

shaped like spheres. not 2D circle. low energy orbitals are buried inside the higher energy orbitals

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12
Q

p orbitals

A

shaped like dumbbells. each energy level has 3 p orbitals (horizontal, vertical and diagonal )

when we say 2p shell we refer to 3 separate p orbitals

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13
Q

d orbitals

A

looks like a 4 leaf clover. there are 5 diff d orbitals per shell.

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14
Q

transition metals

A

are bright colored because they have a funky d orbital shaped that allows electrons in the d orbitals to absorb colored light and promote higher energy orbitals within d shell

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15
Q

f orbitals

A

they have 7 diff shapes.

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16
Q

s block

A

2 columns wide. 1 s orbital per shell

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17
Q

f block

A

14 column wide, 7 f orbitals per shell

18
Q

d block

A

10 columns wide. 5 d orbitals per shell

19
Q

f block

A

6 columns wide . 3 f orbitals per shell

20
Q

principle - quantum number

A

1,2,3,4=n
this tells us in which shell the electron is in or how far its from the nucleus

21
Q

azimuthal - quantum number

A

L = 0,1,2,3
tell us in which orbital the electron is in
0,1,2,3->s,p,d,f

22
Q

magnetic -quantum number

A

m = neg to pos number
tells us in which p orbital , d orbital or f orbital electron Is in

ex if its in p orbital, they only have 3 diff orbitals so -1,0,1

23
Q

ms -quantum number

A

spin number
equal to -1/2 or 1/2

24
Q

what does electron conf mean ?

A

description of quantum numbers and orbitals

25
1s2
1= is the principal quant number or energy n=1 s = what kind of orbital these electrons are in s means L = 0 2 = shows how many electrons are in the orbital
26
oxygen ex electron conf
1s22s22p4 2p4 means there are 4 electron using the 3 p orbitals ( 3 p because there are 3 p orbital types )
27
hunds rule
electrons never pair up unless there is no more space
28
condense electron conf
you write the noble gas before the element and the rest of the electron conf
29
bromine condense conf
Ar-4s23d104p5
30
valance vs core electrons
valence e are the ones in the outermost shell and core e are inside the inner shells.
31
valence electrons
the ones with the largest Principle quantum number
32
exception for valence electrons
elements in the d block , d shell electrons are also valence.
33
atomic orbital energy diagram
the larger the electrons principle quantum number the further away from the nucleus it is and higher in energy
34
rules for e-
aufbau: electrons fill the lowest energy orbitals firs hunds ; electron don't pair up until they have to pauli ; no 2 electrons in the same atom can have the same quantum number
35
excited vs ground state
ground state is the normal regular state excited state is when an electron absorbs a photon of light which get promoted into a higher energy shell when a electron falls back to ground state it emits color
36
paramagnetic vs diamagnetic
paramagnetic = unpaired electrons - which makes them attracted to magnets (ODD number of e) diamagnetic = all electrons are paired - they slightly resell magnetic fields (ODD or EVEN number of e)
37
a photons energy
the particle of light (photon)can be calculated using Ephoton = hf=hc/wavelenght
38
photons energy
as energy increases , frequency increases = wavelength decreases
39
photoelectric effet to function ...
metal has to be hit with a photon with enough energy. ( photon must have high frequency and low wavelength )
40