Cyanogenic and Isothiocyanate glycosides Flashcards

(31 cards)

1
Q

Glycosides yielding hydrocyanic acid (HCN) as one of the products of hydrolysis

A

Cyanogenic glycoside

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2
Q

Both amygdalin and prunasin yield __ as __.

A

mandelonitrile, aglycones

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3
Q

Amygdalin is therefore a true glycoside rather than a maltoside True or False

A

True

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4
Q

Amygdalin (enzyme) (product)

A

amygdalin hydrolase, glucose + prunasin

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5
Q

Prunasin (enzyme) (product)

A

Prunasin hydrolase, glucose+ mandelonitrile

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6
Q

Mandelonitrile (enzyme) (product)

A

Mandelonitrile lyase, benzaldehyde + HCN

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7
Q

an enzyme obtained from almond kernels

A

Emulsin

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8
Q

Emulsin two enzymes

A

Amygdalase, prunase

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9
Q

Uses of emulsin

A
  1. Flavoring agent

2. Anti cancer (laetrile or Vit. B17) and possibility for control of sickle cell anemia

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10
Q

It is carefully dried stembark of Prunus serotina Ehrhart ( Fam. Rosaceae)

A

Wild cherry

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11
Q

Wild cherry is also known as

A

prunus virginia and wild black cherry tree

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12
Q

a compound formed by partial hydrolysis of

amygdalin

A

Prunasin

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13
Q

The yield of hydrocyanic acid varies from __ in the inner bark, __ in trunk bark, varies even in bark of the same thickness from the same tree

A

0.23%- 0. 32%, 0.03%

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14
Q

Wild cherry uses

A

Flavored vehicle especially in cough remedies

Sedative expectorant

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15
Q

Kernels of varieties of Prunus armeniaca Linne. ( Fam. Rosaceae)

A

Apricot pits

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16
Q

Does Prunus armeniaca Linne has a therapeutic effect?

17
Q

The seeds of several mustard family plants contain glycosides, the aglycones of which are isothiocyanates

A

Isothiocynate glycosides

18
Q

The glycosides are also termed

A

glucosinolates

19
Q

Mustard family (brassicaceae) which includes

A
  • Oilseeds (rapeseed)
  • Condiments (mustard and horseradish)
  • Vegetables (broccoli, cabbage, and turnips)
20
Q

–derived from indolylmethylglucosinolate

- shown to reduce risk of estradiol- linked mammary cancer

A

indole- 3-carbinol

21
Q
  • isolated from broccoli

- shown to induce anticarcinogenic protective enzymes

A

4- methylsulfinyl isothiocyanate

22
Q

from black mustard

23
Q

from white mustard

24
Q

from rapeseed

25
Black mustard also called
brown mustard, sinapis nigra
26
Mustard is a dried ripe seeds of variety of
brassica nigra (linne.) Koch or of brassica juncea
27
product in the hydrolysis of black mustard, it is volatile
Allyl isothiocyanate
28
Allyl isothiocyanate commonly called
Volatile mustard oil
29
Also called Sinapis Alba
White mustard
30
Black mustard fixed oil
30-35%
31
white mustard fixed oil
20- 25%