Extractive 2 Flashcards
(37 cards)
THREE CLASSIFICATIONS OF EXTRACTIVES:
- AROMATIC PHENOLIC COMPOUNDS
- ALIPHATIC COMPOUNDS
- OTHER COMPOUNDS
- found in the bark and heartwood
AROMATIC PHENOLIC COMPOUNDS
-serve the purpose of protecting lignocellulose from fungal
and microbial attack and can be washed out as “resin”
from live trees
AROMATIC PHENOLIC COMPOUNDS
- have direct effect on fungal physiology
AROMATIC PHENOLIC COMPOUNDS
AROMATIC PHENOLIC COMPOUNDS:
A. Flavonoids
B. Stilbenes
C. Tannins
D. Lignan
- secondary metabolites that occur naturally in all plant families
Flavonoids
- Widely distributed in all parts of plants, these compounds afford
protection against ultraviolet radiation, pathogens, and herbivores
Flavonoids
- have an important effect on the durability of wood
Flavonoids
flavanoids protects heartwood against fungal colonization by a dual function:
- fungicidal activity and
- free radical scavengers
(antioxidants)
flavanoids are _________ and have received attention due to their role in the neutralization or scavenging of free radicals
natural antioxidants
- produced naturally by several plants upon attack by pathogens
Stilbenes
- produced by woody plants as stress metabolites and also as constitutive defensive
agents - compounds possessing the 1,2-diphenylethene structure
Stilbenes
Stilbenes are large class of plant secondary metabolites, belonging to ________
polyphenols
widely distributed in food (grapes, peanuts, and other foods) and
medicinal plants,
stilbenes
stillbenes possess a variety of biological activities, including antitumor, anti- inflammatory, antioxidant, antibacterial, and antiviral activities
true
stillbenes have two isomeric forms of 1,2-diphenylethylene:
- trans-stilbene and
- cis-stilbene
Hydroxylated trans-stilbene has an
important role in heartwood ________, especially for a resistance to fungal decay
durability
The durability and resistance to
decay by Pinus sylvestris (Pinaceae)
is due to _______
pinosylvins
constitute a distinctive and unique group of higher plant metabolites
Tannins
thought by some to constitute one of the most important groups of
higher plant defensive secondary metabolites
Tannins
of tannin includes compounds of two distinct chemical groups:
- hydrolysable tannins and
- condensed tannins
molecules with a polyol (D-
glucose) as a central core, the hydroxyl groups of these
carbohydrates are partially or totally esterified with phenolic groups like gallic acid (gallotannins) or ellagic acid (ellagitannins)
hydrolysable tannins
hydrolysable tannins are usually
present in ________ in plants
low amounts
probably the most ubiquitous of all plant phenolics, and presented exceptional concentrations in the barks and heartwoods of a variety of tree species
Condensed tannins