Groups of Cations Flashcards

1
Q

Cation that does not react with HCl, forms a PRECIPITATE in H2S in dilute mineral acid medium, and forms a YELLOW precipitate with Ammonium Polysulfide.

A

Cd2+

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1
Q

Cation that does not react with HCl, H2S in dilute mineral acid medium and (NH4)2Sbut forms a **WHITE **precipitate with NH4Cl.

Fresh Sample + Saturated CaSO4 yields a **WHITE **precipitate immediately

A

Ba2+

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2
Q

Cation that does not react with HCl, forms a PRECIPITATE in H2S in dilute mineral acid medium, SOLUBLE in Ammonium Polysulfide and a fresh sample forms a YELLOW precipitate with Acidified H2​S which does not dissolve in excess (NH4)2CO3.

A

Sn4+

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2
Q

Cation that does not react with HCl and H2S in dilute mineral acid medium but forms a WHITE precipitate with (NH4)2S.

Fresh sample + NH3 forms a WHITE precipitate insoluble in excess reagent

A

Al3+

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3
Q

Cation that does not react with HCl, forms a PRECIPITATE in H2S in dilute mineral acid medium, SOLUBLE in Ammonium Polysulfide and a fresh sample forms a **BROWN **precipitate with Acidified H2S

A

Sn2+

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3
Q

Cation that does not react with HCl, forms a **PRECIPITATE **in H2S in dilute mineral acid medium, SOLUBLE in Ammonium Polysulfide and a fresh sample forms a YELLOW precipitate with Acidified H2​S which dissolves in excess (NH4)2CO3.

Fresh sample + 1:1 HCl + KI yields no coloration.

A

As3+

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5
Q

Cation that does not react with HCl, forms a PRECIPITATE in H2S in dilute mineral acid medium, INSOLUBLE in Ammonium Polysulfide and a fresh sample forms a **BLUE **precipitate with NaOH.

A

Cu2+

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6
Q

Cation which forms a precipitate with dilute HCl. Upon addition of NH3no change will be observed

A

Lead

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7
Q

Cation that does not react with HCl, H2S in dilute mineral acid medium and (NH4)2S but forms a WHITE precipitate with NH4Cl.

Fresh Sample + Saturated CaSO4 yields a **WHITE **precipitate slowly

A

Sr2+

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8
Q

Cation which forms a precipitate with dilute HCl and turns **BLACK **upon the addition of NH3

A

Hg22+

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8
Q

Cation that does not react with HCl and H2S in dilute mineral acid medium but forms a** BLACK** precipitate with (NH4)2S which is INSOLUBLE in 1:1 HCl

Fresh sample + NaOH yields a BLUE precipitate which turns PINK upon standing

A

Co2+

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9
Q

Cation that does not react with HCl and H2S in dilute mineral acid medium but forms a BLACK precipitate with (NH4)2S which is INSOLUBLE in 1:1 HCl

Fresh sample + NaOH yields a GREEN precipitate.

A

Ni2+

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10
Q

Cation that does not react with HCl and H2S in dilute mineral acid medium but forms a **GREEN **precipitate with (NH4)2S.

Fresh sample + NaOH forms a **GREEN **precipitate soluble in excess reagent

A

Cr3+

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11
Q

Cation that does not react with HCl and H2S in dilute mineral acid medium but forms a PINK precipitate with (NH4)2S.

Fresh sample + NaOH forms a WHITE precipitate that turns **DARK **upon standing.

A

Mn2+

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13
Q

Cation that does not react with HCl, forms a **PRECIPITATE **in H2S in dilute mineral acid medium, SOLUBLE in Ammonium Polysulfide and a fresh sample forms an ORANGE precipitate with Acidified H2​S. Fresh sample + 1:1 HCl + KI yields Brown Color

A

Sb5+

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14
Q

Cation that does not react with HCl, H2S in dilute mineral acid medium, (NH4)2S and NH4Cl.

Forms a **YELLOW **precipitate with COBALT URANYL ACETATE

15
Q

Cation which forms a precipitate with dilute HCl and dissolves upon the addition of NH3

17
Q

Cation that does not react with HCl, forms a PRECIPITATE in H2S in dilute mineral acid medium, **SOLUBLE **in Ammonium Polysulfide and a fresh sample forms a YELLOW precipitate with Acidified H2​S which **DISSOLVES **in excess (NH4)2CO3.

Fresh sample + 1:1 HCl + KI yields **BROWN **coloration.

19
Q

Cation that does not react with HCl, forms a PRECIPITATE in H2S in dilute mineral acid medium, SOLUBLE in Ammonium Polysulfide and a fresh sample forms an ORANGE precipitate with Acidified H2​S. Fresh sample + 1:1 HCl + KI yields no color.

20
Q

Cation that does not react with HCl and H2S in dilute mineral acid medium but forms a BLACK precipitate with (NH4)2S which is soluble in 1:1 HCl

Fresh sample + NaOH yields a **GREEN **precipitate which turns **DARK **upon standing

21
Q

Cation that does not react with HCl, forms a **PRECIPITATE **in H2S in dilute mineral acid medium, INSOLUBLE in Ammonium Polysulfide and a fresh sample forms a YELLOW precipitate with NaOH.

22
Q

Cation that does not react with HCl and H2S in dilute mineral acid medium but forms a **BLACK **precipitate with (NH4)2S which is soluble in 1:1 HCl

Fresh sample + NaOH yields a REDDISH BROWN

23
Q

Cation that does not react with HCl, H2S in dilute mineral acid medium, (NH4)2S and NH4Cl.

Forms a** WHITE **precipitate with SODIUM BITARTRATE

24
Q

Cation that does not react with HCl, H2S in dilute mineral acid medium and (NH4)2Sbut forms a WHITE precipitate with NH4Cl.

Fresh Sample + Saturated CaSO4 yields no precipitate

25
Cation that does not react with HCl, H2S in dilute mineral acid medium, (NH4)2S and NH4Cl. Vapors turn red litmus to blue when heated with NaOH
NH3
26
Cation that does not react with HCl and H2S in dilute mineral acid medium but forms a **WHITE **precipitate with (NH4)2S. Fresh sample + NH3 forms a **WHITE** precipitate soluble in excess reagent
Zn2+
27
Cation that does not react with HCl, forms a **PRECIPITATE** in H2S in dilute mineral acid medium, **INSOLUBLE** in Ammonium Polysulfide and a fresh sample forms a **WHITE** precipitate with NaOH.
Bi3+
28
Cation that does not react with HCl, H2S in dilute mineral acid medium, (NH4)2S and NH4Cl. Forms a WHITE precipitate with excess NaOH which turns RED upon the addition of TITAN YELLOW reagent.
Mg2+