H Flashcards by Morgan Moore

Q

1c aldehyde

A

Formaldehyde

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Q

2c aldehyde

A

Acetaldehyde

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Q

3c aldehyde

A

Propionaldehyde

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Q

4C aldehyde

A

Butyraldehyde

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Q

5c aldehyde

A

Valeraldehyde

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Q

6c aldehyde

A

Caproaldehyde

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Q

7C aldehyde

A

Heptanaldehyde

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Q

8c aldehyde

A

Octanaldehyde

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Q

9c aldehyde

A

Nonanaldehyde

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Q

10c aldehyde

A

Dodecanaldehyde

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Q

11c aldehyde

A

Undecanaldehyde

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Q

12c aldehyde

A

Lauraldehyde

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Q

14c aldehyde

A

Myristaldehyde

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Q

16c aldehyde

A

Palmitaldehyde

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Q

18c aldehyde

A

Stearaldehyde

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Q

C1-6 mnemonic

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A

FAPBVC
123456

Q

Fatty aldehyde mnemonic

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A

Let my pie sit
12 14 16 18

Q

2c telomeric aldehyde

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A

Oxalaldehyde

Q

3c telomeric aldehyde

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A

Malonaldehyde

Q

4C telomeric aldehyde

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A

Succinaldehyde

Q

5C telomeric aldehyde

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A

Glutaraldehyde

Q

6c telomeric aldehyde

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A

Adipaldehyde

Q

7c telomeric aldehyde

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A

Pimelaldehyde

Q

Telomeric aldehyde mnemonic

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A

OMSGAP
2 3 4567

IUPAC ketones

Allan-2-one

Common ketone

Alkyl alkyl ketone

1° OH oxidized becomes

Aldehyde

2° aldehyde oxidized becomes

Ketone

Witting reaction

Replace carbonyl O with CH group

Hydrate hydrolysis

Replace carbonyl group with 2 alcohols

Imine hydrolysis

O and 2Hs become water New DB between C and N

Ace(ke)tal hydrolysis

Recopy 2 alcohol groups next to carbonyl O from carbonyland 2Hs become water New bonds between C and Os from alcohols

Grit and reaction order

1 - base 2 - nucleophilic attack on R-X 3 - attack on carbonyl

1/2 degree alcohols use

PBr3

3rd degree alcohols use

HBr

Neat

No water just ice Excess of OH

Why are hydrates unstable

2 eneg atoms on same C

Hemiace(ke)tal

1/2 OH 1/2 ether