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Organic Chem > H > Flashcards

H Flashcards

1
Q

1c aldehyde

A

Formaldehyde

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2
Q

2c aldehyde

A

Acetaldehyde

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3
Q

3c aldehyde

A

Propionaldehyde

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4
Q

4C aldehyde

A

Butyraldehyde

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5
Q

5c aldehyde

A

Valeraldehyde

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6
Q

6c aldehyde

A

Caproaldehyde

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7
Q

7C aldehyde

A

Heptanaldehyde

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8
Q

8c aldehyde

A

Octanaldehyde

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9
Q

9c aldehyde

A

Nonanaldehyde

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10
Q

10c aldehyde

A

Dodecanaldehyde

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11
Q

11c aldehyde

A

Undecanaldehyde

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12
Q

12c aldehyde

A

Lauraldehyde

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13
Q

14c aldehyde

A

Myristaldehyde

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14
Q

16c aldehyde

A

Palmitaldehyde

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15
Q

18c aldehyde

A

Stearaldehyde

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16
Q

C1-6 mnemonic

A

FAPBVC
123456

17
Q

Fatty aldehyde mnemonic

A

Let my pie sit
12 14 16 18

18
Q

2c telomeric aldehyde

A

Oxalaldehyde

19
Q

3c telomeric aldehyde

A

Malonaldehyde

20
Q

4C telomeric aldehyde

A

Succinaldehyde

21
Q

5C telomeric aldehyde

A

Glutaraldehyde

22
Q

6c telomeric aldehyde

A

Adipaldehyde

23
Q

7c telomeric aldehyde

A

Pimelaldehyde

24
Q

Telomeric aldehyde mnemonic

A

OMSGAP
2 3 4567

25
Q

IUPAC ketones

A

Allan-2-one

26
Q

Common ketone

A

Alkyl alkyl ketone

27
Q

1° OH oxidized becomes

A

Aldehyde

28
Q

2° aldehyde oxidized becomes

A

Ketone

29
Q

Witting reaction

A

Replace carbonyl O with CH group

30
Q

Hydrate hydrolysis

A

Replace carbonyl group with 2 alcohols

31
Q

Imine hydrolysis

A

O and 2Hs become water
New DB between C and N

32
Q

Ace(ke)tal hydrolysis

A

Recopy 2 alcohol groups next to carbonyl
O from carbonyland 2Hs become water
New bonds between C and Os from alcohols

33
Q

Grit and reaction order

A

1 - base
2 - nucleophilic attack on R-X
3 - attack on carbonyl

34
Q

1/2 degree alcohols use

A

PBr3

35
Q

3rd degree alcohols use

A

HBr

36
Q

Neat

A

No water just ice
Excess of OH

37
Q

Why are hydrates unstable

A

2 eneg atoms on same C

38
Q

Hemiace(ke)tal

A

1/2 OH 1/2 ether

Organic Chem (6 decks)

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