L3_OchemII Flashcards
(54 cards)
Non-polar molecules with an R-replacing hydrogen (R-O-R). Simple ones are used as anesthetics.
Ethers
Simple to complex polar molecules with a Sulfur atom replacing Oxygen in the OH- group; (R-S-H) The Sulfide Group (important in protein structure and in cellular energy production
Thiols
Polar alcohol molecules with one benzene ring or more; aromatic with OH group, many of these are used as antiseptics
Phenols
A polar group with a carbon double bonded to an oxygen, and seen in carboxylic acids, aldehydes, keytones, esters, amides
Carbonyl Group
R-COH
Aldehyde
The first aldehyde in series: R group is H (CH2O)
Formaldehyde
A liver metabolite of ethyl alcohol (responsible for alcohol hangover)
acetaldehyde
Derivative of aldehyde by substituting R’ for H OCRR’; This group is the chemical cause of the genetic disease Phenylketonuria (PKU)
Keytones
R-COOH; a common organic acid group; R is any aliphatic or aromatic compound
Carboxylic Acid
Why is carboxylic acid (R-COOH) a weak acid?
-COOH is a weak acid because H+ dissociates for only a brief period of time. Less H+ in solution means less acid in solution
A common carboxylic acid identified as fats or lipids; acid fats
fatty acids
How are fatty acids classified?
Their saturation. Saturated or unsaturated
Are saturated or unsaturated fatty acids higher in calories?
Saturated. They have more H, thus more calories
This unsaturated fatty acid is a messenger molecule
Prostaglandin
Created from the -COOH group by replacing H with an -R. Many are fragrant RCOOR’
Esters
The suffix of -oate refers to:
Esters
This molecule ______ NH3 has a tetrahedral structure, and can lose any of its 3 hydrogens to R groups
Ammonia
Differentiate between a primary, secondary and tertiary amine
Primary: 1 R group (RNH2)
Secondary: 2 R groups (RNHR)
Tertiary: 3 R groups (RNRR)
These are the building blocks of proteins and are all amines:
Amino acids
Most amino acids are:
Primary amines (R-NH2)
A huge class of amines based on ring structures with one or more nitrogen atoms in the carbon ring
heterocyclic amines
A class of amines that are the building blocks of DNA, RNA, porphyrin rings, vitamin B6, nicotine, carcinogens, alkaloids, etc.
Heterocyclic amines
A class of heterocyclic amines that chelate a metal ion in the molecule’s center. Important in the function of many enzymes
Porphyrins
An amine group with a carbonyl group is called:
Amide (OCN)