monosaccharides and disaccharides Flashcards

(56 cards)

1
Q

two molecules that are made of the same atoms connected in the same sequence, but the atoms are positioned differently in space

A

stereoisomers

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2
Q

non-superimposable mirror images

A

enantiomers

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3
Q

D-Ribose and L-Ribose are

A

enantiomers

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4
Q

stereoisomers that are not enantiomers (not mirror images)

A

diastereomers

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5
Q

D-arabinose and D-ribose are

A

diastereomers

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6
Q

diastereomers that differ at a single chiral carbon

A

epimers

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7
Q

D-glucose and D-mannose are ____that differ at____

A

epimers

second carbon position

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8
Q

an aldehyde and an alcohol make a

A

hemiacetal

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9
Q

a ketone and an alcohol make a

A

hemiketal

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10
Q

the two possible diastereomers that are formed because of cyclization

A

anomers

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11
Q

alpha D glucose OH group is

A

not in the same plane as the oxygen

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12
Q

beta D glucose OH group is

A

in the same plane as the oxygen

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13
Q

monosaccharides may readily undergo several oxidation reactions in the presence of metal ions or certain enzymes

A

oxidation

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14
Q

D-gluconic acid is an example of

A

aldonic acid

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15
Q

D-glucuronic acid is an example of

A

uronic acid

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16
Q

D-glucaric acid is an example of

A

aldaric acid

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17
Q

can be produced if the carbonyl groups of aldonic and uronic acids react with an OH group in the same molecule

A

lactone

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18
Q

example of naturally produced lacone

A

L-ascorbic acid (vitamin C)

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19
Q

powerful reducing agent that protects cells from reactive oxygen and nitrogen species

A

Vitamin C

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20
Q

another name for sugar alcohols

A

alditols

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21
Q

sugar alcohols are produced by the _____of aldehyde and ketone groups of monosaccharides

A

reduction

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22
Q

free OH groups of carbohydrates can be converted to esters by reaction with acids

A

esterfication

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23
Q

the products of the dehydration of a carboxylic acid and an alcohol

24
Q

originally called dextrose, it is found in large quantities throughout the natural world, a primary fuel for living cells, preferred energy for brain cells and cells without mitochondria

25
often referred to as the fruit sugar, because of its high content in fruit, twice as sweet as sucrose, used as a sweetening agent
D- fructose
26
sperm use ____ as an energy source
fructose
27
necessary to synthesize a variety of important biomolecules
galactose
28
a genetic disorder resulting from a missing enzyme in galactose metabolism
galactosemia
29
D-glucuronic acid is used in the liver to improve water solubility to remove waste molecules
uronic acids
30
D-glucosamine and D-galactosamine are the most common and often attached to proteins or lipids
amino sugars
31
form of sugar found in DNA
deoxy sugars
32
two monosaccharides linked by a glycosidic bond
disaccharides
33
disaccharide found in milk
lactose
34
lactose is made of
galactose and glucose via beta 1,4 linkage
35
lactose is a
reducing sugar
36
an intermediate product of starch hydrolysis
maltose
37
maltose has what kind of bond
alpha 1,4 linkage between two glucose molecules
38
a degradation product of cellulose
cellobiose
39
cellobiose has what kind of bond
beta 1,4 glycosidic bond between two glucose molecules
40
common table sugar produced in the leaves and stems of plants
sucrose
41
sucrose has what kind of bond
alpha, beta 1,2 glycosidic bond between glucose and fructose
42
sucrose is a
nonreducing sugar
43
have one type of monosaccharide and are found in starch, glycogen, cellulose, and citin
homoglycans
44
the energy reservoir of plant cells and a significant source of carbohydrates in human diet
starch
45
two polysaccharides occur together in starch
amylose and amylopectin
46
is composed of long, unbranched chains of D-glucose with a 1,4 linkages between them
amylose
47
branched forms of starch
amylopectin
48
the branches in amylopectin occur where
alpha 1,6 linkage
49
a polymer of D-glucopyranosides linked by beta 1,4 glycosidic bond
cellulose
50
most abundant organic substance on earth
cellulose
51
result from carbohydrates being linked to proteins and lipids
glycoconjugates
52
distinguished from other glycoproteins by their high carbohydrate content, roles in organizing extracellular matrix, involved in signal transduction
proteoglycans
53
example of a genetic disorder involving the metabolism of proteoglycans
hurler's syndrome
54
polysaccharide in which parallel strands are joined by hydrogen bonds
cellulose | chitin
55
used for structural support in the cell walls of fungi and the external skeletons of insects and crustaceans contain a nitrogen group
chitin
56
used for structural support in bacterial cell walls and have a chain of four amino acids
peptidoglycans