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Chem > Organic Synthesis formation > Flashcards

Organic Synthesis formation Flashcards

(41 cards)

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1
Q

Phenol -> Phenolic salt
reaction type
reagents/conditions
other products

A

neutralisation
NaOH
H2O

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2
Q

Phenol -> Phenolic salt (effervescence)
reaction type
reagents/conditions
other products

A

redox
Na
H2

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3
Q

Acid anhydride -> Ester
reagents/conditions
other products

A

alcohol
carboxylic acid

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4
Q

Acid anhydride -> Amide
reagents/conditions
other products

A

amine
carboxylic acid

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5
Q

Carboxylic Acid -> Ester
reaction type
reagents/conditions
other products

A

esterification/condensation reaction
H2SO4/reflux + alcohol
water

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6
Q

Carboxylic Acid -> Amide
reaction type
reagents/conditions
other products

A

condensation reaction
H2SO4/reflux + amine
water

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7
Q

Carboxylic Acid -> Acyl Chloride
reagents/conditions
other products

A

SOCl2
HCl + SO2

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8
Q

Carboxylic Acid -> Carboxylate Salt (hydroxide)
reaction type
reagents/conditions
other products

A

neutralisation
NaOH
water

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9
Q

Carboxylic Acid -> Carboxylate Salt
(carbonate)
reaction type
reagents/conditions
other products

A

neutralisation
Na2CO3
water + CO2

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10
Q

Ester -> Alcohol + Carboxylic Acid
reaction type
reagents/conditions

A

hydrolysis
hot aqueous acid (HCl)

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11
Q

Ester -> Alcohol + Carboxylate Salt
reaction type
reagents/conditions

A

hydrolysis
Hot aqueous alkali (NaOH)

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12
Q

Amine -> Ammonium Salt
reaction type (acid)
reagents/conditions

A

neturalisation
HCl

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13
Q

Amine -> Amide
reagents/conditions (3)
other products

A

carboxylic acid, H2O
acyl chloride, HCl
acid anhydride, carboxylic acid

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14
Q

Amide -> Carboxylic acid + Carboxylate Salt
reaction type (acid)
reagents/conditions

A

hydrolysis
hot aqueous acid (HCl)

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15
Q

Amide -> Amine + Carboxylate Salt
reaction type (alkaline)
reagents/conditions

A

hydrolysis
hot aqueous alkali (NaOH)

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16
Q

Acyl Chloride -> Ester
reaction type
reagents/conditions
other products

A

esterification
alcohol
HCl

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17
Q

Acyl Chloride -> Amide
reagents/conditions
other products

18
Q

Aldehyde -> Carboxylic Acid
reaction type
reagents/conditions

Study These Flashcards
A

oxidation
acidified potassium dichromate

19
Q

Aldehyde -> 1’ Alcohol
reaction type
reagents/conditions

Study These Flashcards
A

nucleophilic addition/reduction
NaBH4 + reflux

20
Q

Aldehyde -> hydroxynitrile
CH3CHO -> CH3CHOHCN
reagents/conditions

21
Q

Benzene -> Chlorobenzene
reaction type
reagents/conditions
other products

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A

electrophilic substitution
Cl/AlCl3
HCl

22
Q

Benzene -> Phenylketone
reagents/conditions
other products

Study These Flashcards
A

acylchloride
HCl

23
Q

Benzene -> Nitrobenzene
reagents/conditions
other products

Study These Flashcards
A

H2SO4/HNO3
H2O

24
Q

Benzene amide -> Amine
reaction type
reagents/conditions
other products

Study These Flashcards
A

reduction
Sn/HCl
H2O

25
Ketone -> 2' Alcohol reaction type reagents/conditions
nucleophilic addition/reduction NaBH4 + reflux
26
Ketone -> Hydroxynitrile reaction type reagents/conditions
nucleophilic addition NaCN/H+
27
1' Alcohol -> Aldehyde reaction type reagents/conditions other products
oxidation acidified potassium dichromate / distil H2O
28
1' Alcohol -> Carboxylic Acid reaction type reagents/conditions other products
oxidation acidified potassium dichromate / reflux H2O
29
2' Alcohol -> Ketone reaction type reagents/conditions other products
oxidation acidified potassium dichromate / reflux H2O
30
Alcohol -> Alkene reaction type reagents/conditions other products
dehydration H2SO4 H2O
31
Alcohol -> Haloalkane reaction type reagents/conditions other products
halogenation HCl H2O
32
Alcohol -> Ester reaction type reagents/conditions other products
esterification carboxylic acid, H2SO4 + reflux H2O
33
Nitrile -> Amine reaction type reagents/conditions
hydrogenation/reduction H2 150'
34
Nitrile -> Carboxylic Acid reaction type reagents/conditions other products
redox/neutralisation H2O + HCl NH4Cl
35
Haloalkanes -> Alcohol reaction type reagents/conditions other products
nucleophilic substitution NaOH + reflux NaCl
36
Haloalkane -> Amine reaction type reagents/conditions other products
nucleophilic substitution NH3 + ethanol HCl
37
Haloalkane -> nitrile reaction type reagents/conditions other products
nucleophilic substitution KCN + ethanol KCl
38
Alkene -> Haloalkane reaction type reagents/conditions other products
Electrophilic addition Br2/HBr, RTP
39
Alkene -> Alcohol reaction type reagents/conditions
hydration High + pressure + H3PO4
40
Alkene -> Alkane reaction type reagents/conditions
hydrodgenation Ni/150' + H2
41
Alkene -> polyalkene reaction type reagents/conditions
polymerisation zeigler-natta catalyst / high temp + press

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