Rates Of Reaction Flashcards
(11 cards)
What is rate of reaction
- Increase in concentration of a product per unit time
- The decrease in concentration of a reactant per unit time
Rate = change in concentration/ change in time
Why does the average rate decrease as the reaction proceeds
As the reaction rate proceeds there are fewer collision between reactants and molecules
What is a zero order reaction
Rate is unaffected by changing the concentration of a given reactant
What is a first order reactant
Changing the concentration has the same affect on the rate of reaction , if concentration doubles rate doubles
What is a second order reactant
Changing the concentration has squared the effect on the rate of reaction
How can concentration time graphs be used to determine order
Zero order
- straight line
- detracting half life
First order
- constant half life
- units s^-1
Second order
Increasing half life
- units mol^-1dm^3s^-1
How can rate concentration graphs by used
Zero order
- horizontal line
First order
- rising straight line
Second order
- upwards curve
What is half life
Time taken for the concentration of the reactant to reduce by half
K= ln2/ half life
What affects the rate constant and how
- increase in temperature increases k
- addition of a catalyst increases k
Basic rate equation
Rate = k [x] ^a [y]^b
Explains what happens when a catalyst is added in terms of K
When a catalyst is added Ea becomes smaller so e^-eA/RT becomes larger and rate increases