Rates Of Reaction Flashcards

(11 cards)

1
Q

What is rate of reaction

A
  1. Increase in concentration of a product per unit time
  2. The decrease in concentration of a reactant per unit time

Rate = change in concentration/ change in time

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2
Q

Why does the average rate decrease as the reaction proceeds

A

As the reaction rate proceeds there are fewer collision between reactants and molecules

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3
Q

What is a zero order reaction

A

Rate is unaffected by changing the concentration of a given reactant

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4
Q

What is a first order reactant

A

Changing the concentration has the same affect on the rate of reaction , if concentration doubles rate doubles

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5
Q

What is a second order reactant

A

Changing the concentration has squared the effect on the rate of reaction

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6
Q

How can concentration time graphs be used to determine order

A

Zero order
- straight line
- detracting half life

First order
- constant half life
- units s^-1

Second order
Increasing half life
- units mol^-1dm^3s^-1

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7
Q

How can rate concentration graphs by used

A

Zero order
- horizontal line

First order
- rising straight line

Second order
- upwards curve

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8
Q

What is half life

A

Time taken for the concentration of the reactant to reduce by half

K= ln2/ half life

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9
Q

What affects the rate constant and how

A
  • increase in temperature increases k
  • addition of a catalyst increases k
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10
Q

Basic rate equation

A

Rate = k [x] ^a [y]^b

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11
Q

Explains what happens when a catalyst is added in terms of K

A

When a catalyst is added Ea becomes smaller so e^-eA/RT becomes larger and rate increases

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