Rates of Reaction and Reversible Reactions Flashcards

(54 cards)

1
Q

What is the rate of a chemical reaction?

A

Speed at which reactants turn into products.

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2
Q

Give examples of slow, moderate, and fast reactions.

A
  • Slow: Rusting of iron
  • Moderate: Magnesium + acid
  • Fast: Burning
  • Very fast: Explosions
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3
Q

How can reaction rate be measured?

A
  • Measure amount of product formed or reactant used over time
  • Steeper graph = faster rate
  • Flat line = reaction finished
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4
Q

What does collision theory say about reaction rates?

A
  • More frequent collisions = faster rate
  • Collisions must have enough energy (activation energy) to be successful
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5
Q

What is activation energy?

A

Minimum energy needed for particles to react.

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6
Q

What factors increase the rate of reaction?

A
  • Higher temperature
  • Higher concentration (or pressure)
  • Greater surface area
  • Use of a catalyst
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7
Q

How does temperature affect rate?

A
  • Increased temp
  • Particles move faster → more collisions
  • Increased energy of collisions -> particles re moving faster
  • Reactions only happen if the particles collide with enough energy
  • More successful collisions per unit time
  • Increased rate
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8
Q

How does concentration affect rate?

A
  • Solution more concentrated
  • More particles of reactant in the same volume
  • Collisions more likely
  • Increased rate
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9
Q

How does pressure affect rate?

A
  • Increasing pressure
  • Particles are more crowded
  • Frequency of collisions between particles will increase
  • Increased rate
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10
Q

How does surface area affect rate?

A
  • Smaller particles = larger surface area to volume ratio
  • Particles have more area to work on
  • Frequency of collisions increase
  • Increased rate
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11
Q

What is a catalyst?

A

A substance that increases the rate of a reaction without being chemically changed or used up.

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12
Q

Does a catalyst affect the products of a reaction?

A

No, it doesn’t change the products — the reaction equation stays the same.

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13
Q

Why is only a small amount of catalyst needed?

A

Because it isn’t used up, you only need a tiny bit to catalyse large amounts of reactants.

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14
Q

How do catalysts speed up reactions?

A

They decrease the activation energy needed for a reaction to occur.

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15
Q

What does a catalyst provide to lower activation energy?

A

An alternative reaction pathway that has a lower activation energy.

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16
Q

Why does a lower activation energy increase the rate of reaction?

A

More particles have at least the minimum amount of energy needed when they collide.

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17
Q

What does activation energy look like on a reaction profile?

A

It’s the difference between the energy of the reactants and the highest point on the curve.

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18
Q

How can you compare activation energy with and without a catalyst on a reaction profile?

A

The highest point on the curve is lower for the reaction with a catalyst.

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19
Q

In a reaction profile, what does the curve look like with a catalyst?

A

It has a lower peak than the curve without a catalyst.

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20
Q

How does a catalyst affect rate?

A
  • Particles must collide with enough energy.
  • Catalysts provide an alternative pathway.
  • This pathway has lower activation energy.
  • More collisions successful.
  • Reaction speeds up
    -Increased rate
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21
Q

What does the rate of reaction measure?

A

How quickly reactants are used up or products are formed.

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22
Q

What is the formula for the rate of reaction?

A

Rate = Amount of reactant used or product formed ÷ Time

23
Q

Why is it usually easier to measure the rate of reaction by observing products rather than reactants?

A

Because products are often easier to detect or measure than reactants disappearing.

24
Q

How does the precipitation method work? (investigate how temperature affects rate)

A
  • Mix two clear solutions that form a precipitate.
  • Time how long a mark takes to disappear through the cloudy mixture.
25
What is a limitation of the precipitation method?
It is subjective; different observers might disagree on when the mark disappears.
26
How is the change in mass method used to measure reaction rate?
Measure the mass loss over time using a balance as gas is released.
27
What safety consideration must you keep in mind when using the change in mass method?
If the gas released is harmful, perform the experiment in a fume cupboard.
28
How does the volume of gas method work?
Use a gas syringe to measure the volume of gas produced over time.
29
What precaution should be taken when using a gas syringe for fast reactions?
Use the correct syringe size to prevent the plunger from being pushed out by vigorous gas production.
30
How does increasing surface area affect reaction rate?
More surface area leads to more frequent collisions → faster reaction.
31
How can you test the effect of surface area on rate using marble chips?
- Use the same mass of marble chips in different sizes (chips, crushed, powder). - Measure gas volume produced over time with a gas syringe.
32
How does changing acid concentration affect reaction rate with marble chips?
Higher acid concentration increases rate → reaction finishes sooner.
33
How do you keep experiments fair when testing concentration effects?
Keep the mass and surface area of marble chips and volume of acid the same, only vary concentration.
34
How can you measure how temperature affects the rate of reaction between sodium thiosulfate and hydrochloric acid?
Time how long it takes for a black mark to disappear as a yellow sulfur precipitate forms at different temperatures.
35
Why is it better to use a water bath to heat solutions for this experiment? (temp)
It’s safer and more accurate than heating acid directly.
36
What trend do typical results show for the effect of temperature on reaction time?
Higher temperature → faster reaction → shorter time for mark to disappear.
37
How do catalysts affect the decomposition of hydrogen peroxide?
They speed up the production of oxygen gas without being consumed.
38
What catalysts are commonly used for hydrogen peroxide decomposition?
Manganese(IV) oxide (MnO₂), copper(II) oxide (CuO), zinc oxide (ZnO).
39
How do you measure reaction rate with catalysts in this experiment?
Measure volume of oxygen gas produced over time with a gas syringe.
40
How can you compare the effectiveness of different catalysts?
Use the same volume and concentration of H₂O₂ and the same amount of catalyst, then compare gas production rates.
41
What is a reversible reaction?
A reaction where products can react to reform reactants (reaction goes both ways).
42
Give an example of a reversible reaction.
Thermal decomposition of ammonium chloride ↔ ammonia + hydrogen chloride.
43
What is dynamic equilibrium in reversible reactions?
Forward and backward reactions occur at the same rate, so concentrations stay constant.
44
What conditions are necessary for dynamic equilibrium to be established?
A closed system where no reactants or products escape.
45
How does increasing temperature affect the position of equilibrium?
- Increasing temp: endothermic reaction increases to absorb the extra heat
46
How does increasing pressure affect equilibrium in gaseous reversible reactions?
- Raising pressure: encourage reaction which produces fewer moles of gas
47
How does decreasing pressure affect equilibrium in gaseous reversible reactions?
- Lowering pressure: encourage the reaction which produces more moles of gas
48
How does decreasing temperature affect the position of equilibrium?
- Decreasing temp: exothermic reaction increases to give out more heat
49
Does adding a catalyst change the position of equilibrium?
- No, because it speeds up the forward reaction & the backward reaction by the same amount
50
All reactions are exothermic in _________ and endothermic in _______
All reactions are exothermic in one direction and endothermic in the other
51
Most gaseous reactions have ______ moles of gas on one side than the other
Most gaseous reactions have more moles of gas on one side than the other
52
Define dynamic equilibrium
- the rate of the forward reaction equals the rate of the backward reaction - the concentrations of reactants and products remain constant
53
Describe a method investigate the effect of different size marble chips on the rate of reaction between calcium carbonate and hydrochloric acid
1. Add a fixed volume of hydrochloric acid into a conical flask 2. Use a delivery tube to connect this flask to an inverted measuring cylinder 3. Add marble chips into the conical flask & close the bung 4. Measure the volume of gas produced in a fixed time using the measuring cylinder 5. Repeat with different sizes of marble chips
54
Describe a method to investigate the effect of a catalyst on the rate of reaction
1. Add hydrogen peroxide into a conical flask 2. Use a delivery tube to connect this flask to a measuring cylinder upside down in water trough 3. Add the chosen catalyst into the conical flask & close the bung 4. Measure the volume of gas produced in a fixed time using the measuring cylinder 5. Repeat experiment with different catalysts and compare results 6. Catalysts to try could include: manganese(IV) oxide, lead(II) oxide, iron(III) oxide and copper(II) oxide