soluability Flashcards
(9 cards)
soluability
- Physical property referring to the ability of a given substance (solute) to dissolve in a solvent
- solute will dissolve in a solvent if the solute - solvent IMF are equal to or greater then solute - solute and solvent - solvent
like dissolve like
- polar solutes dissolve in polar solvents (H2O)
e.g. amides, carboxylic acids, alcohol, keystone, ester, aldehyde - non polar solutes dissolve in non polar solvents (hexane)
e.g. hydrocarbon, haloalkane, >4 carbons long gets less polar
polarity
Polarity of each molecule due to functional groups which will change its solubility
- more polar groups in a solute make it more soluble in a polar solvent but less in non polar
carbon chain length
As it increases, the non-polar region of the molecule increases and solubility in a polar solvent decreases
- polar molecule with 4 or less carbon is soluble in polar solvent
- after 4 the solubility decreases
BP
temp liquid changes into a gas. Volatility is a qualitative measure of how easily a substance turns into gas.
BP and MP
require suffiicient energy to seperate molecules by overcoming IMF holding them together
The stronger the IMF the higher the MP and BP
Molecular mass
increasing number of carbons increases MP and BP
- within a homologous series, adding carbons to the chain increases mass therefore dispersion
Surface area
increasing surfaces area increases the MP and BP
- increase in branching leads to less surface are and an increase in distance between molecules therefore decreased dispersion
Functional group present
stronger IMF increases the MP and BP