Topic 8 - Fuels and Earth Science Flashcards

(51 cards)

1
Q

Hydocarbons are

A

Compounds that only contain carbon and hydrogen

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2
Q

Crude oil is

A

A complex mixture of hydrocarbons.
The hydrocarbons have their carbons arranged in chains or rings
Important source of substances called a feedstock for petrochemical industry)
A finite resource

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3
Q

Crude oil is seperated by

A

Fractional distillation

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4
Q

Fractional distillation is

A

When the oil is heated to a gas then enter the fractionating column where there is a temp gradient.
It is hot at the bottom and cooler at the top.
The longer hydrocarbons have higher boiling points, so condensate at the bottom.
Creates 6 different fractions

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5
Q

The 6 fractions in fractional distillation(top to bottom)

A

Gases
Petrol
Kerosene
Diesel oil
Fuel oil
Bitumen

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6
Q

Use of gases fraction

A

Used in domestic heating and cooking

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7
Q

Petrol fraction use

A

Fuel for cars

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8
Q

Kerosene fraction use

A

Fuel in aircraft

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9
Q

Diesel oil fraction use

A

Fuel in some cars, larger vehicles and trains

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10
Q

Fuel oil fraction use

A

Fuel for large ships and soem power stations

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11
Q

Bitumen fraction use

A

Used to surface roads and roofs

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12
Q

The lower the fraction in fractional distillation,

A

The number of hydrogen and carbon atoms in molecules increase
Boiling point increases
Ease of ignition decreases
Viscocity increases

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13
Q

The hydrocarbons in crude oil are mainly

A

part of the alkane homologous series

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14
Q

A homologous series is

A

A family of molecules which have the same general formula and share similar chemical properties.
They differ from neighbouring compounds by a CH2
Gradual variation in physical properties

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15
Q

two homologous series’ of hydrocarbons

A

Alkanes and alkenes

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16
Q

Hydrocarbons are good fuels because

A

The combustion reactions give out lots of energy. Very exothermic.

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17
Q

When hydrocarbons are burned in plenty of oxygen

A

Complete combustion occurs, and the only products formed are carbon dioxide and water.
Release lots of energy

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18
Q

When hydrocarbons are burned in insufficient oxygen

A

Incomplete combustion occurs.
This produces carbon dioxide and water, but also carbon and carbon monoxide(CO)

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19
Q

Why is carbon monoxide bad

A

It is toxic as it combines with red blood cells and stops blood carryign oxygen.
This can lead to death

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20
Q

Why is carbon bad

A

Tiny particles of it are relased into the atomsphere, and when they fall they form balck dust called soot.
Reduces air quality and makes builidings look dirty

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21
Q

Incomplete combustion occurs in

A

Some appliances that use carbon compounds as fuels

22
Q

Sulfur dioxide can be produced by fossil fuels if

A

They contain sulfur impurities

23
Q

Sulfur dioxide is bad because

A

It mixes with the clouds and forms dilute sulfuric acid. This falls as aicd rain

24
Q

Acid rain is bad because

A

It causes lakes to become acidic, and many plants and animals die
Kills trees, damages limestone buildings and stone statues, and causes metal corrosion

25
Nitrogen oxides are produced by
Reactions between nitrogen and oxygen in the air caused by the energy released in combustion(eg by car engines)
26
Nitrogen oxides are bad because
They are harmful ppolutants that can contribute to acid rain, and can cause a photochemical smog, which leads to breathing difficulties
27
Advanatges of using hydrogen to fuel cars
Very clean fuel Only waste product is water Renewable resource as it is obtained by the electrolysis of water
28
Disadvantages of using hydrogen to fuel cars
Expensive engine Expensive to obtain pure hydrogen Hydrogen is hard to store
29
Non-renewable fossils fuels from crude oil
Petrol Kerosene Diesel oil
30
Non-renewable fossil fuel found in natural gas
Methane
31
Cracking is
The splitting up of long, saturated hydrocarbons(alkanes) into smaller hydrocarbons. Some of the smaller ones are unsaturated(alkenes)
32
Cracking is done by
Heating up a larger hydrocarbon, and breaking the strong covalent bonds.
33
Cracking process
Vaporised hydrocarbons are passed over powdered catalysts at about 400*C-700*C. Pressure of 70atm. Aluminium oxide is the catalyst used, and the large lakanes split apart in the conditions.
34
Cracking is necessary because
Because the demand for petrol and diesel is much higher than fuel oil and bitumen, so they are broken down to make more of the in-demand alkanes. It also can produce and alkene used to make polymers.
35
The eartghs early atomsphere was formed by
Volcanoes releasing gases(carbon dioxide, steam, methane and ammonia).
36
Early atmosphere contained
Little or no oxygen Large amount of CO2 Water vapour Small amounts of other gases(ammonia, methane)
37
Oceans formed by
Water vapour condensed into large masses of water
38
The amount of CO2 in the atomsphere first decreased by
CO2 dissolving into the oceans
39
How was nitrogen gas put in the atmosphere
Ammonia reacting with oxygen, released by denitrifying bacteria. N2 isnt reactive so increased in amount
40
How did oxygen get into the ealry atmosphere
Green plants evolved and photosynthesised. Slowly removed CO2 and produced o2
41
Oxygen in the ealry atmosphere allowed`
Complex organisms to evolve Created the ozone layer
42
Chemical test for oxygen
If the gas relights a glowing splint it is oxygen
43
The greenhouse effect process
EM radiation from sun gets filtered through the atmosphere and some gets in. Short wavelengths are absorbed which warms the planet The earth radiates some heat radiation that has been absorbed from longer wavelength IR radiation Some of this is absorbed by greenhosue gases The gases radiate some of it back to earth The absorbtion and re-emission of this IR is what keep the earth warm
44
Greenhouse gases are
The gases in the atmosphere that can absorb and reflect heat radiation. Carbon dioxide, steam, methane etc
45
Human activity is causing
CO2 concentration to increase
46
Temperature change is correlated to
the increase in CO2 and methane concentration in recent decades
47
There are uncertainties in historical data because
The measurements were less accurate and sometimes non-existent. Some of it is predicted using analysis of fossils and gas bubbles
48
Composition of todays atmosphere
Nitrogen mainly 20% oxygen Less than 0.1% of CO2 Tiny amounts of methane
49
CO2 concentration has increased due to
Burning of fossils fuels to meet higher energy demands. deforestation to house people and grow food.
50
Methane concentration increase due to
Higher amount of livestock farmed. They produce methane in digestive process.
51
CO2 and methane increase is bad because
It leads to global warming due to too much greenhouse effect