Unit 1 Structure and Bonding Flashcards
Pure covalent bond
Equal sharing of a pair of e between two nuclei (Same electronegativity)
Permanent dipole
In HF F has a higher electronegativity so the dipole is pulled towards it
F becomes slightly negative δ−
H becomes slightly positive δ+
Bonding continium
≤0.4: pure covalent >0.4:Polar >1.7:ionic
(Non polar)
When do dipoles cancel out
Linear and Sometimes Tetrahedral
How are LDF’s formed
Formed by electrostatic attraction between temporary and induced dipoles
How are the dipoles formed
Electron cloud wobbles causing a temporary dipole which can induce a dipole by distorting it electron cloud
PD-PDI
Only occurs between polar molecules
Opposite charged ends attracting
Hydrogen bonding
Strongest IMF
Hydrogen can bond to F, O & N
When is it fair to compare 2 molecules
Same or similar number of electrons/mass
Same IMF’s
Ionic bonding
Between metals and non-metals
Metals lose electrons to become positively charged ions, whilst non-metals gain to become negatively charged ions
Covalent bonding
Between non-metal atoms