unit 1 topic C transition metals n' dat Flashcards

not that bad of a topic i swear

1
Q

define transition metal

A

metals with an incomplete d-subshell in at least one of their ions

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2
Q

which transition metals are an exception to Aufbau’s principle

A

Chromium and copper

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3
Q

why are chromuium and copper an exception to Aufbau’s principle

A

because of the special stability associated with the d subshell being half filled or completely filled

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4
Q

what does an increase in oxidation number mean

A

it means that an oxidation reaction has occurred

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5
Q

what does a decrease in oxidation number mean

A

it means that a reduction reaction has occurred

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6
Q

what are ligands

A

they may be negative ions or molecules with non bonding pairs of electrons that they donate to the central metal atom or ion

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7
Q

define dative bond

A

a dative bond is a covalent bond in which both electrons come from the same atom

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8
Q

what can ligands be classified as

A

they can be classified as monodentate, bidentate all the way up to hexadentate

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9
Q

what is the only hexadentate ligand you will come across in advanced higher called

A

EDTA or if you wanna be extra ethylenediamminetetraacetate

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10
Q

what does a bidentate ligand have

A

it has 2 atoms with non bonding electron pairs available to bond to the central metal ion

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11
Q

define coordination number

A

the total number of bonds from the ligands to the central transition metal

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12
Q

what is the ligand name and charge for chloride

A

chlorido and 1-

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13
Q

what is the ligand name and charge for oxide

A

oxido and 2-

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14
Q

what is the ligand name and charge for cyanide

A

cyanido and 1-

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