unit 5 Flashcards

(26 cards)

1
Q

Can al3+ be oxidised to pure metal Al?

A

No

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2
Q

Can zone melting produce materials with a purity of up to 98% but no higher?

A

No

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3
Q

During zone melting when is the impurity ion most soluble

A

Liquid phase

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4
Q

What is the inert pair effect?

A

s orbitals penetrate the nucleus better than p orbitals and dont participate in bonding

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5
Q

Can aluminum powder react with air?

A

Yes

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6
Q

The lattice energy of Al203 is very high therefore…

A

Combustion creates a lot of heat

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7
Q

What structure can tin and germanium form?

A

Diamond structure

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8
Q

Which density of tin (diamond structure) or tin (FCC structure) has the higher density?

A

FCC

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9
Q

Is carbon the only group 13 that can form diamond structure?

A

No tin and germanium can too

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10
Q

How can you reduce the melting point of aluminia?

A

mixing it with other materials

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11
Q

Why is the melting point of Al203 higher than aluminium?

A

strong ionic bonds

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12
Q

Can silicon and oxygen form long chain molecules?

A

Yes

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13
Q

What can zeolites be described as?

A

Framework structures

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14
Q

What can zeolites be used for and why?

A

Catalysts as very small molecules can fit inside

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15
Q

Do zeolites have low melting points because they are ionic?

A

No

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16
Q

Why is diamond hard?

A

All the bonds are covalent

17
Q

Why is graphite soft?

A

Its van der waal forces

18
Q

What can diamond be made from?

A

Graphite under high pressure

19
Q

how thick is a layer of graphene?

20
Q

What is lead azide?

A

Solid, sensitive Explosive, it can detonate to form nitrogen

21
Q

How does mixing Cryolite and Al203 reduce melting point?

A

Ions can disturb the crystal structure of alumnia making it easier for the Al and O to move away from their lattice sites

22
Q

How do group 3 exist?

A

Metalloid then rest are metals

23
Q

What does amphoteric mean?

A

Reacts as both an acid and a base

24
Q

Why does B3+ not form ionic compounds?

A

Very small radius which is so polarising electron density would be shared (covalent)

25
Why would BCl3 and AlCl3 easily be hydrolysed?
Theyre electron deficient (don't satisfy octet)
26
What is an allotrope?
different physical form in which an element can exist (eg carbon - diamond graphene graphite)