week five Flashcards
(48 cards)
Define catalyst
substances that increase the rate of chemical reactions without themselves being consumed
Define the rate of a chemical reaction
amount of product formed (or reactant consumed) per unit of time
What are the functions of an enzyme?
-lower the activation energy for the reaction
-increase the rate of a specific reaction
Glyphosate is the active ingredient in the herbicide called ROUND-UP. What common biological molecule does glyphosate resemble?
an amino acid
Glyphosate affects plants because it…
binds to a biosynthetic enzyme and inhibits its activity
Do catalyst affect the equilibrium state of the reaction? Why?
catalysts do not change the equilibrium state of the reaction because they affect both the forward and reverse reactions to the same extent
Catalysts are usually proteins called _____
enzymes
exergonic reactions ______ free energy and endergonic reactions _____ free energy
exergonic reactions release free energy and endergonic reactions require free energy
For an exergonic reaction, the energy _____ is more than the initial input of energy, so there is a ______ of energy.
For an exergonic reaction, the energy released is more than the initial input of energy, so there is a net release of energy.
This intermediate between reactants and products is called the ________
This intermediate between reactants and products is called the transition state
Define the transition state, is it stable, does it require free energy?
intermediate between reactants and products is called the transition state, It is highly unstable and therefore has a large amount of free energy
In all chemical reactions, reactants adopt at least ______ before their conversion into products
In all chemical reactions, reactants adopt at least one transition state before their conversion into products
To reach the transition state what must happen to the reactant?
the reactant must absorb energy from its surroundings
What is activation energy?
all chemical reactions, even spontaneous ones that release energy, require an input of energy that we can think of as an “energy barrier.” The energy input necessary to reach the transition state is called the activation energy
There is an _____ correlation between the rate of a reaction and the height of the energy barrier: the ______ the energy barrier, the _____ the reaction and the ______ the barrier, the ______ the reaction
There is an inverse correlation between the rate of a reaction and the height of the energy barrier: the lower the energy barrier, the faster the reaction and the higher the barrier, the slower the reaction
Although an enzyme ______ the activation energy, the difference in free energy between reactants and products ______
Although an enzyme reduces the activation energy, the difference in free energy between reactants and products does not change
Are catalysts consumed in the chemical process?
no
In a chemical reaction catalyzed by an enzyme, the reactant is often referred to as the ______
substrate
What are the letters that represent substrate, enzyme, and product?
S
E
P
To form an enzyme–substrate complex, enzymes bind substrates at a region of the enzyme called ______
the active site
Many enzymes require additional nonprotein molecules, called ______
Many enzymes require additional nonprotein molecules, called cofactors
Are cofactors organic?
Cofactors can be inorganic or organic
The activity of enzymes is ______ to temperature
The activity of enzymes is also sensitive to temperature. Enzymes have an optimal temperature, which is the temperature at which the enzyme is most active
What happens when an enzyme gets too hot?
At very high temperatures, enzymes unfold, or denature