18- kinetics Flashcards

(18 cards)

1
Q

what is a rate of reaction

A

a measure of how fast a reaction occurs

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2
Q

what is the rate equation

A

a mathematical expression that relates the rate of a chemical reaction to the concentration of its reactants

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3
Q

what is a order of reaction

A

it describes how the rate of a chemical reaction depends on the concentration of its reactants

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4
Q

what is the zero order reaction

A

the rate of reaction is independant of the concentration of the reactant

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5
Q

what is a first order reaction

A

the rate of reaction is directly proportional to the concentration of the reactant

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6
Q

what is a second order reaction

A

the rate of reaction is proportional to the square of the concentration of the reactant

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7
Q

what is the overall order of reaction

A

the sum of orders with respect to each reactant in the rate equation

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8
Q

what is the initial rates method

A

a method to determine the order of a reaction with respect to each reactant and calculate the rate constant

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9
Q

what is the shape of the line on a rate concentration graph for zero order reactions

A

a horizontal straight line

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10
Q

what is the shape of the line on a rate concentration graph for first order reactions

A

straight line with a positive slope

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11
Q

what is the shape of the line on a rate concentration graph for second order reactions

A

curve that slopes upward more steeply as the concentration increases

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12
Q

what are the different ways to monitor the progress of a chemical reaction

A
  • measuring the volume of gas given off
  • monitoring changes in pH
  • observing colour changes
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13
Q

what are clock reactions

A

a type of chemical reaction where a visible change, such as colour shift, occurs after a specific time.

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14
Q

what is the Arrhenius equation

A

π‘˜ =𝐴𝑒 ^βˆ’πΈπ‘Ž/𝑅𝑇

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15
Q

what is the Arrhenius equation in natural log

A

lnK = lnA - Ea/RT

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16
Q

what form of arrhenius can relate to y=mx +c

A

lnk = (-Ea/RT) - lnA

17
Q

what is the rate determining step

A

this is the slowest step which controls how fast the rest of the reaction proceeds

18
Q

how do you identify the rate determining step

A

step 1- observe the rate law
step 2- examine the mechanism
step 3- confirm molecularity