58 Flashcards by Hannah Hausmann

Q

How do you name epoxides

A

epoxy______ane

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Q

LAH, H3O+ with cooch3

A

MeOH

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Q

NaBH4, H3O+ with cooch3

A

Doesn’t react

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Q

NaBH4, H3O+

A

Weak reducing agent

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Q

H2, raney nickel

A

Removes DB

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Q

Strong OX 1 alcohol

A

COOH

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Q

Strong ox 2 alcohol

A

C=O

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Q

Strong ox 3 alcohol

A

Doesn’t react

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Q

HIO4, H2O

A

Cleaves diols

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Q

What’s receptive to grignard

A

Alkyl halide, ketone

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Q

HBr with ether

A

Cuts off at O, leaving it with mark, subs with OH. Adds be to other half

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Q

H2O2

A

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Q

MeCO2H

A

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Q

SAE + DET

A

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Q

SAE DET
TMSCl, TEA
HBr
TBAF

A

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Q

MeOH, H+ with epoxides

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A

Opens them, OH at mark

Q

NaOMe, DMSO
H2O
With epoxide

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A

Opens them, OH at mark

Q

Gaining OH ox or red?

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A

neither

Q

Gaining Br ox or red?

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A

Neither

Q

Gaining O ox or red?

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A

Ox

Q

DA reaction

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A

DB on left, thing with one DB added to right side. All subs forced down

Q

Heat with ether

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A

Moves O to mark

Q

DB on DA rxn

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A

Leaves 2 bonds instead of 1

Q

Heat with molecule that could do DA

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A

Fuses to form structure

Unclosed cyclohexane with HV

Forms benzene with anti subs

Cold HBr

Adds at mark (12)

Hot HBr

Adds at anti mark (1,4)