Chapter 23 Flashcards
(21 cards)
1
Q
Swapping bromine with CN on an alkyl chain
A
NaCN
2
Q
CN to CNH2
A
- Xs LAH 2. H2O
3
Q
Swapping carboxylic acid to amine
A
- SOCl2 2. Xs NH3
4
Q
Amine to alkyl plus NH2
A
- XS LAH 2. H2O
5
Q
Adding NO2
A
HNO3, H2SO4
6
Q
NO2 to NH2
A
H2, PT OR 1. SNCl2, H3O+ 2. NaOH
7
Q
Adding methyl to amine
A
MeI
8
Q
Alkyl halide to N3
A
NaN3
9
Q
Gabriel synthesis
A
Molecule, KOH
10
Q
Ketone to amine
A
H+/Nh3, H2/Pt
11
Q
Amine to amide
A
Ketone with Cl
12
Q
Acylated NH
A
OP director, NH can be reduced by NAOH or H3O+
13
Q
Amine to alkene
A
XS MeI, Ag2O, H2O, heat
14
Q
Nitrous acid to NO
A
HCl
15
Q
Adding NO
A
NaNO2, HCl
16
Q
Amine to diazonium salt
A
NaNO2, HCl
17
Q
Changing amine (NH2) to aryl dizonium salt (N2Cl)
A
NaNO2, HCl
18
Q
HBf4
A
Subs F
19
Q
H2O, heat
A
Subs OH
20
Q
H3PO2
A
subs H
21
Q
Azo plus ring with AG
A
AG para to N
