59 Flashcards
(44 cards)
1
Q
NBS, heat
A
Adds br to carbon next to DB
2
Q
Tbu-OK
A
Removes subs
3
Q
BH3, THF H2O2, NaOH
A
Adds OH at anti mark
4
Q
SO3, H2SO4
A
Adds SO3H
5
Q
HNO3, H2SO4
A
Adds NO2
6
Q
DIL H2SO4
A
7
Q
NaOH, heat
A
Subs OH
8
Q
How to remove carbonyl
A
H2NNH2, H+
2. KOtBu
9
Q
Ketone to ether
A
RCO3H
10
Q
How to remove bromine
A
- NaOH, hot
- H3O+
11
Q
Na, MeOH, NH3
A
Removes DB
12
Q
NaNO2, HCl
A
13
Q
RCONH2 with SOCl2
A
R triple bonded to N
14
Q
LAH , H2O with RCN
A
RCNH2
15
Q
What happens when nitrile treated with grignard
A
N gets kicked off
16
Q
Pyridine
A
Makes LG leave, adds DB
17
Q
Gabriel with 1. KOH
2. RI
3. H2NNH2, HEAT
A
Removes cyclohexene
18
Q
- NaOET
- EtI
- NaOEt
- MeI
- H3O+. heat
A
Subs LG with ET and Me
19
Q
O3, H2O
A
Adds O or OOH
20
Q
COOH to aldehyde
A
- LiAl(OtBu)3H
- H2O
21
Q
Adding R to ketone
A
- RNH2
- H+, NaBH3CN
22
Q
- NaOH, heat
- R
A
Adds R to mark, gets rid of O
23
Q
Remove NH2
A
- XS MeI
- Ag2O, H2O, heat
24
Q
What happens to OCH3 in grignard
A
Gets kicked off
25
How do you retrosynthesize grignard
Cut CC bond necxt to COH
26
What happens to OH reacted with MGBR, then MEOH
Gets subbed swapped with H
27
How to remove OH to mark alkene
TsCl, py
TBUOK
28
Williamson ether
29
H2SO4, heat for OH
Removes, turns to alkene
30
How to add to alkene
RCO3H, Grignard
31
How to retrosynthesize ether
Cut bond between O and alkyl halide
32
Epoxide attached to cyclohexane with MrOH
OH at anti mark
33
H3O_
Adds OH at mark
34
Rearrangement
Subs can be moved to more or less sub places
35
Br2, H2O
Anti Br, OH- Br at anti mark
36
Alkene naming
Has to include db
37
DBs separated by one carbon
Are more stable
38
Delocalization and aromaticity makes something
Acidic
39
Catalytic H2SO4
Fuses intramolecular
40
NaBH3Cn
Gets rid of DB
41
Fe, H3O+
NaOH with NO2
NH2
42
NH2 with NaNO2, HCl
NN
43
NN with CUCN
CN
44
OX cn
NH2
