Chapter 14 Flashcards by Hannah Hausmann

Q

Alcohol plus 1. NaH 2. RBr

A

Ether

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Q

Disub alkene plus 1. Hg(OAc)2, ROH, 2. NaBH4

A

Ether

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Q

2ROH to ether

A

H2SO4 heat

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Q

Bulky alcohol to alkene

A

with H2SO4 heat

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Q

Ether to 2RX+ H2O

A

HX

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Q

Alkyl/aryl ether to ROH

A

HX

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Q

Ether to ROOR

A

O2

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Q

Thiol (RSH) to RSSR

A

Br2

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Q

RSSR to RSH

A

Zn, HCl

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Q

RSH to Sulfonic acid

A

KMnO4 or HNO3

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Q

RSH to RSNa

A

NaOH

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Q

RSNa to RSR

A

RBr

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Q

Alkene to epoxide

A

Peracid (like MCPBA)

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Q

+ DET

A

Wedge

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Q

DET

A

Dash

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Q

Can open epoxides by

Study These Flashcards

A

Acids (if using a nuceleophile) or bases (to take proton off where O is bonded to

Q

Open epoxides

Study These Flashcards

A

Nuc
H2O

Q

Asymmetrical epoxide, nuc attacks

Study These Flashcards

A

Less sub carbon