Chapter 22 Flashcards
(17 cards)
1
Q
Enol to enolate
A
Base (like LDA)
2
Q
LDA
A
Strong Ox
3
Q
Halogenation of enol/enolate
A
H3O+, Br. Will add to more sub if asymmetrical
4
Q
alpha haloketone to alpha beta unsaturated ketone
A
Base (like py)
5
Q
Adding Br to carboxylic acid
A
- Br, PBr3
- H2O
6
Q
Adding Br to other Carbon
A
Br2
7
Q
Adding Br to keton
A
NaOH, Br2
8
Q
Adding OH to carboxylic acid
A
- NaOH, Br2
- H3O+
9
Q
Cold NaOH
A
Leaves OH
10
Q
Hot NaOH
A
Gets rid of OH
11
Q
Aldol condensation
A
NaOH, heat
12
Q
Fusion with
A
LDA
13
Q
Intramolecular aldol
A
NaOH, heat
14
Q
Claisen condensation
A
- NaOEt
- H3O+
15
Q
Intramolecular claisen
A
- NaOEt
- H3O+
16
Q
Cold LDA
A
Adds on opposite end
17
Q
Warm LDA
A
Adds on same end
