BCM12 Flashcards

(42 cards)

1
Q

alpha d- glucopyranose (1->2) beta- d frutofuranose

A

sucrose

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2
Q

alpha - d glucopyranosyl (1->4) alpha- d- glucopyranose

A

maltose

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3
Q

beta- d galactopyranose (1->4) alpha/beta- d- glucopyranose

A

lactose

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4
Q

what is raffinose?

A

storage oligosaccaharide found in legumes

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5
Q

alpha (1->6) galactosyl sucrose

A

raffinose

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6
Q

raffinose

A

alpha (1->6) galactosyl sucrose

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7
Q

what is needed to digest alpha 1->6 glycosidic bonds?

A

alpha gal

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8
Q

what do legumes cause flatulance?

A

humans lack alpha Gal to digest rafinose bond so fermented by microorganisms creating methane and c02 - f

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9
Q

what are abo blood group antigens?

A

o linked oligosaccharides on rbc

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10
Q

how do A and B blood antigens differ

A

A has a alpha d acetylgalactosamine where b has a alpha d galactose

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11
Q

what are the main sugars in the blood group antigens?

A

alpha - l fructose
alpha/beta d - galactose
beta d acetyl glucosamine
alpha d acetyl galactosamine

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12
Q

what linkage do the blood antigens have?

A

alpha 1->3

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13
Q

how does H/O blood group antigen differ from A and B?

A

has one less sugar molecule of the variety that is fdifference between A and B (only 4 sugars)

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14
Q

what are glycosyl transferases?

A

enzymes that catalyse links between sugar monomoers

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15
Q

what are lecitns?

A

proteins that bind carbohydrates

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16
Q

what is ricin?

A

a very toxic lectin

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17
Q

what are lectins domains?

A

bind cell surface glycoproteins

18
Q

give examples of 3 sugar homopolymers?

A

starch
cellulose
glucans

19
Q

give an example of a sugar heteropolymer, describe

A

hyaluronan

d glucuronic acid adn n acetyl glucosamine

20
Q

where is hyaluronon found?

A

synovial fluid, joints
stops bone erosion
jelly in eyes

21
Q

beta (1->4) glucan (1->4 linkage) - ubranched

22
Q

describe celluose

A
beta (1->4) glucan, unbranched
highly ordered
rod shaped
cystalline
resistent to heat damage
found in gossyplum - cotton balls
23
Q

what gives cellulose such good tensile strength?

A

extensive h bonding

24
Q

what is chitin?

A

beta (1->4) hompolymer of n acetyal glucosamine

25
where is chitin found?
insect exoskeleton fungal cell wall very abundant polymer second only to cellulose
26
what is starch?
storage carbohydrate mix of glucans amylose and amylopectin
27
what is amylose?
(1->4) glucan, bent hollow left handed helix.
28
what is the basis of the starch iodine test?
helical arrangement of amylose I3- and I5- fit inside amylose coils light cant pass through due to electronorbitals
29
what are amylopectin and glycogen?
branched starches with alpha 1->4 glucam with alpha (1->6) branches
30
what is the animal equivalent of amylopectin?
glycogen
31
what do many modified polysaccharides act as?
hydrocolloid gels and gums
32
what is alignate
anionic polysaccahride heteropolymer beta 1-4 linked d mannuronate and alpha 1-4 linked l guluronate found in brown algae
33
what is agar
found in red algae mix of polysaccharide agarose 1-3 beta d galactopyranose 1-4 -3-6 anyhydro alpha l galactopyranose and agropectin microbiology plates
34
(1->3) beta d galactopyranose (1->4) -3-6 anyhdro alpha l galactopyranose and agropectin
agar
35
beta (1->4) linked d mannuronate and alpha (1->4) l glucoronate
alignate
36
what are pectins?
modified polysaccharides that glue plant cells together
37
what are the two components of pectic acid
homogalacturonan | and rhamnogalacturonan
38
what is homogalacturonan
alpha 1 -4 linked galacturonic acid residues can be methyl esterified or acetylated hydrophobic interactions
39
what is pectic acids role?
plats similar role to hyaluronan = very hydrophillic borate and calcium cross links thickener in jams
40
what are hydrocolloid gels used in
``` loads of things foods, pharmaceuticals paper thickener ice cream ```
41
what are beta 1-4 glycans used for
structural
42
what are alpha 1-4 glycans used for
storage