Chapter 14 - Forensic Arson & Explosives Flashcards
(28 cards)
Accelerant
Compound that facilitates the initiation and/or growth of a fire
Activation Energy
- The energy necessary to overcome the energetic barrier to a reaction
- Initial heat required to get the fire started
Backdraft
- A fire burns in an enclosed space and uses up most of its O2 supply
- This starves the fire of O2
- The O2 is rapidly reintroduced to the room with the accumulated unburned fuel
- Produces an explosion
Black Powder
- Low explosive material comprised of potassium nitrate, sulfur, and carbon (charcoal)
- Used as propellant in fireworks
In a 75:15:10 ratio
Chemical Explosive
Chemical that undergoes rapid reaction that releases kinetic and thermal energy
Combustion
Chemical process in which a substance reacts rapidly with O2 and gives off heat and light
Detonation
- An explosion in which the speed of burning is higher than the speed of sound in the surroundings
- Produce shock waves
Detonator
A device used to detonate an explosive
Dynamite
- Mixture of an adsorbent (diatomaceous earth, sawdust, clay, wood pulp)
- Has been soaked in nitroglycerin and wrapped in strong paper
Exothermic Reaction
Chemical reaction that gives off heat
Explosive
A solid, liquid, or combination which can produce gas at such a temp, pressure, and speed to cause damage to surroundings
Fire
- The atoms in a fuel react with O2
- Reaction produces different molecules (CO2, H2O)
- Energy is released in the form of light and heat
- O2, fuel, and heat are required to start a fire
Fire Tetrahedron
Four elements needed for fire to be sustained:
1. fuel
2. O2,
3. heat
4. chemical chain reaction
Flashover
Event in which every combustible surface exposed to thermal radiation in a an enclosed space rapidly & simultaneously ignites
Fuel
A substance that is used to begin/add to the process of combustion
High Explosive
- Compound that yields rapid chemical reactions regardless of container
- Charge reacts at a speed greater than 1,000m/sec
- Detonate at a rate greater than the speed of sound
- EX: used in mining and for military purposes
Kinetic Energy
The energy of motion
Low Explosive
- Burn only the surface layer of a compound
- Explode when combustion reaction is contained and builds pressure
- Charge reactes at rates less than 1,000 m/sec
- EX: igniters, fireworks (black powder)
Modus Operandi
The method a person uses to commit a crime
Oxidant (Oxidizer)
A substance that oxidizes (to combine with O2) another substance
PETN
- A nitro-containing high explosive
- Explosive used as the primary ingredient in detonating fuses
Pentaerythritol tetranitrate
Propellant
A substance used as a reagent in a reaction to provide acceleration
Secondary Explosive
- Explosive compound that is relatively stable to heat/ shock
- Requires more energy to be detonated
Primary Explosive
Detonate by ignition from some source such as flame, spark, impact, or other means that will produce enough heat