chem paper 2 Flashcards
(94 cards)
group 1 characteristics
shiny when freshly cut
good conductors
solid at room temp
soft
produce white/colourless ionic compounds
group 1 melting point trend
melting point decreases as you go down the group
more distance between nucleus and valence electron
decreased electrostatic forces
metallic bond weakens
easier to break
group 1 reactivity trend
reactivity increases down the group
outer electron becomes easier to lose because more distance weaker bond
how does lithium, sodium and potassium react in water
lithium - fizzes steadily and slowly disappears
sodium - melts to form a silvery ball, fizzes vigorously and quickly disappears
potassium - immediately ignites, burns with a lilac flame, very quickly disappears
group 7 characteristics
brittle in solid state
poor conductors
group 7 elements appearance
flourine - pale yellow gas
chlorine - green gas
bromine - orange-brown liquid
iodine - shiny grey-black crystalline solid and purple vapour
group 7/0 melting point trend
melting point increases as you go down
gain extra electron shells
so intermolecular forces are stronger
group 7 reactivity trend
reactivity decreases as you go down
increased electron shielding
reduces attractive forces of nucleus
so can’t get an electron to react
halide colours
chloride - white
bromide - cream
iodide - yellow
transition metals characteristics
shiny when freshly cut
good conductors
strong
malleable
produce coloured ionic compounds
good catalysts
metals that arent solid at room temp
mecury (liquid)
how to detect chlorine
dampen blue litmus paper
paper turns blue to red to white
how to detect hydrogen and oxygen
hydrogen: lit splint should make a squeaky pop
oxygen: glowing splint should relight
flame test colours
lithium - red
sodium - yellow
potassium - lilac
calcium - orange
copper - green
how to do a hydroxide precipitate test
add a few drops of sodium hydroxide solution to a solution containing metal ions
hydroxide precipitate colours
iron 2 - green
iron 3 - orange brown
copper 2 - blue
calcium - white
zinc - white
how to differentiate between calcium and zinc hydroxide
add excess sodium hydroxide
zinc becomes colourless and calcium stays white
how to detect sulfate ions
add a few drops of hydrochloric acid
then few drops of barium chloride solution
if sulfate present then you get a white precipitate
how to detect halide ions
add a few drops of dilute nitric acid
then a few drops of silver nitrate
how to interpret mass spectra
each peak is a fragment of the molecule
the peak on the far right represents the molecular ion
the mass:charge of the molecular in peak is the Mr of the molecule
what affects percentage yield
reactants may react unexpectedly
reaction may not complete
may lose product when you separate it
atom economy
sum of Mr of desired product/ sum of Mr of all products x 100
factors for reaction pathway
product yield
atom economy
usefulness of by-products
rate of reaction
equilibrium position
how to carry out a titration
measure out 25cm2 of alkali solution using a volumetric pipette and pour into your conical flask
add a few drops of phenolphthalein
ensure your burette is closed and pour your acid solution in until it hits zero
put an empty beaker underneath and run the burette tap through to get rid of any air bubbles and refill the burette
the burette should be clamped, at the bottom of the clamp stand you should have a white tile underneath your conical flask
run your acid solution through in intervals and swirl your flask
repeat until the mixture turns clear
then read off the titre at the bottom of the meniscus
repeat until you obtain at least 2 concordant results