chem red questions Flashcards

(25 cards)

1
Q

Isomerism for the specified compounds CH 3 – CH 2 – CH 2 – CH 2 – OH and
CH 3 - CH( OH) – CH 2 – CH 3
refers :
functional group position isomerism
spatial isomerism
carbon chain isomerism
multiple bond position isomerism

A

functional group position isomerism

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2
Q

Which two reagents can be used to determine the non-limiting hydrocarbon content?
bromine water
Potassium permanganate in a neutral medium
Phenols
Pyridine

A

bromine water
Potassium permanganate in a neutral

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3
Q

Pyruvic acid is involved in carbohydrate metabolism and is part of the Krebs cycle.
Specify what class of compounds it belongs to?
oxo acids catecholamines amino acids oxy acids(hydroxy acids)

A

oxo acids

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4
Q

Specify 2 six-membered heterocycle With two atoms nitrogen
pyrazine, pyrimidine pyridine, pyrimidine pyrrole, pyrimidine pyrimidine, furan

A

pyrazine, pyrimidine

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5
Q

What is the role of barbituric acid derivatives in medicine?
are hypnotics
are tonics
have a vasodilatory effect
lower blood pressure

A

are hypnotics

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6
Q

Specify the oxidation product of beta - methylpyridine
nicotinic acid pyridoxal n-methylpyridinium piperidine

A

nicotinic acid

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7
Q

Give 2 characteristics of pyridine
aromatic heterocyclic compound
electron-deficient system
pi-redundant system
has acidic properties

A

aromatic heterocyclic compound
electron-deficient system

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8
Q

What class of compounds do monosaccharides belong to?
Hetero-Polyfunctional compounds Polyfunctional compounds Aldehydes Alcohols

A

Hetero-Polyfunctional compounds

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9
Q

What compound can be used to obtain ethyl alcohol?
Glucose
Benzol
Cumene(Kumol)
Phenol

A

Glucose

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10
Q

Which monosaccharide belongs to ketohexoses?/What monosaccharide belongs to
ketohexoses?
Fructose
Mannose
Galactose
Glucose

A

Fructose

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11
Q

Cyclic forms of monosaccharides by chemical nature
Polyacetalss
Chelates
Ethers
Esters

A

Polyacetalss

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12
Q

What protein structure is characterized by globule formation?
Tertiary
Primary
Secondary
Quaternary

A

Tertiary

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13
Q

Which two conformations are characteristic of cyclohexane?
1. Boat
2. Eclipsed
3. Staggered
4. Chair

A
  1. Boat
  2. Chair
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14
Q

Specify 2 rules for determining whether stereoisomers belong to the D- or
L-series:
1. Determined by the configuration of the chiral center farthest from the carbonyl
group
2. Determined using the standard reference compound glyceraldehyde
3. Determined by the configuration of the carbonyl carbon atom
4. Determined using a polarograph

A
  1. Determined by the configuration of the chiral center farthest from the carbonyl
    group
  2. Determined using the standard reference compound glyceraldehyde
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15
Q

Specify two correct answers explaining the essence of heterolytic bond
rupture:
1. Observed in radical processes
2. As a result of the rupture, free radicals are formed
3. Observed in addition and substitution reactions
4. As a result of the rupture, an electrophile and a nucleophile are formed

A
  1. Observed in addition and substitution reactions
  2. As a result of the rupture, an electrophile and a nucleophile are formed
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16
Q

. Match the following particles with their properties:
1. Radical
2. Electrophile
3. Nucleophile
A. A particle that has a free orbital at the outer electron levelB. A particle containing
an unpaired electron in its outer electron shellC. A particle having a pair of electrons at
the outer electron level

A

Radical-b
3. Nucleophile-c
electrophile-a

17
Q

. Identify 3 compounds that are not heterocyclic:
1. Pyridine
2. Cumene
3. Nitrobenzene
4. Phenol

A
  1. Cumene
  2. Nitrobenzene
  3. Phenol
18
Q

Specify 2 simple lipids:
1. 1-palmitoyl distearoylglycerin
2. Phospholipids
3. Sphingolipids
4. Tristearoylglycerin

A
  1. 1-palmitoyl distearoylglycerin
  2. Tristearoylglycerin
19
Q

Choose 3 saturated fatty acids:
1. Palmitic acid
2. Stearic acid
3. Linoleic acid
4. Lauric acid

A
  1. Palmitic acid
  2. Stearic acid
  3. Lauric acid
20
Q

Specify a substance that is not related to carbonyl compounds
acetone
ethanol
ethanal
butanone

21
Q

Which amino acid contains an imidazole ring?
histidine proline tryptophan arginine

22
Q

Which compound is homopolysaccharide ?
dextrin
hyaluronic acid
chondroitin sulfate
heparin

23
Q

What class of compounds do monosaccharides belong to?
Polyfunctional compounds
Hetero-Polyfunctional compounds Aldehydes Alcohols

A

Hetero-Polyfunctional compounds

24
Q

Specify connection that refers to To heteropolysaccharides
heparin glycogen dextrin starch

25
When oxoacids are reduced,... are formed. Hydroxy acids Amino acids Amino alcohols Aldehydes
Hydroxy acids