chem sikli sorular Flashcards

(132 cards)

1
Q

What is configuration?
spatial arrangement of atoms in a molecule
arrangement of molecules on one plane
arrangement of atoms on one plane
definition of molecular structure

A

spatial arrangement of atoms in a molecule

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2
Q

Specify the energetically stable conformation for ethane
inhibited obscured skewed gauche

A

inhibited

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3
Q

A carbon atom that is bonded to four different atoms or groups is called
asymmetrical symmetrical mobile non-chiral

A

asymmetrical

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4
Q

Specify the achiral molecule
benzene
2-hydroxypropanoic acid 2-aminopropanoic acid 3-hydroxybutanoic acid

A

benzene

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5
Q

For which substance is optical isomerism observed?
Alanine Glycine Acrylic acid
methane

A

Alanine

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6
Q

What is the second name for optical isomerism?
Mirror isomerism Cis-trans isomerism There is no correct answer Geometric
isomerism

A

Mirror isomerism

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7
Q

Specify the isomers.
pentine-1 and pentine-2
3-methylpentane and 3-methylhexane
ethene and ethyne
butadiene and butene

A

pentine-1 and pentine-2

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8
Q

What is the name of the isomerism between pentane and isopentane?
Carbon skeleton Substituent positions Geometrical Conformational

A

Carbon skeleton

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9
Q

Which compounds exhibit geometric isomerism?
Butene-2
Butane
Isobutane
Butin

A

Butene-2

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10
Q

What is the second name for geometric isomerism?
Cis-trans isomerism
Metamerism Optical isomerism Enantiomerism

A

Cis-trans isomerism

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11
Q

Isomerism for the specified compounds CH 3 – CH 2 – CH 2 – CH 2 – OH and
CH 3 - CH( OH) – CH 2 – CH 3
refers :
functional group position isomerism
spatial isomerism
carbon chain isomerism
multiple bond position isomerism

A

functional group position isomerism

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12
Q

Specify homologue alkanes With whom it begins phenomenon isomerism
butane
pentane
heptane
propane

A

butane

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13
Q

Isomers are substances:
having the same qualitative and quantitative composition, but different structure
having the same qualitative composition, but different structure
having the same quantitative composition, but different structure
none of the answers is correct

A

having the same qualitative and quantitative composition, but different structure

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14
Q

Projection formulas are used to depict conformations.….
Newman Fisher Misher Rozanov

A

Newman

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15
Q

D- and L - lactic acids is called ….
racemic
optical
enantiomers
diastereomers

A

racemic

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16
Q

Which of these functional groups is considered the main one? -COOH -SO3H -NH2

A

COOH

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17
Q

Characteristic reactions for alkanes
SR АN АЕ SE

A

SR

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18
Q

Select a catalyst for benzene bromination
FeBr3
FeCl3
KCl
MgCl2

A

FeBr3

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19
Q

What is formed during the bromination of toluene?
2,4,6-tribromotoluene 2,4,6-tribromotoluene 1,2,3-tribromotoluene 2,3,5-
tribromotoluene

A

2,4,6-tribromotoluene

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20
Q

What is the mesomeric effect?
this is the transfer of the electronic influence of substituents along the conjugated system of
π-bonds
this is an increase in the electron density in the system
this is a decrease in the electron density in the system
this is a decrease in the energy of the molecule due to conjugation

A

this is the transfer of the electronic influence of substituents along the conjugated system of
π-bonds

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21
Q

What is the inductive effect?
is a redistribution of electron density along the sigma bond
is a decrease in the energy of the molecule due to conjugation
is a redistribution of electron density along the pi bond
is a redistribution of electron density along the sigma and pi bonds

A

is a redistribution of electron density along the sigma bond

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22
Q

By what mechanism does benzene sulfonation occur?
by electrophilic substitution
by electrophilic addition
by nucleophilic substitution
by nucleophilic addition

A

by electrophilic substitution

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23
Q

Electron acceptor Substitutes ( EA ):
Substituents that decrease the electron density in the system
Substituents that increase the electron density in the system
Substituents that do not affect the electron density in the system
Increases the stability of the molecule

A

Substituents that decrease the electron density in the system

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24
Q

How to influence electron donor deputies on mesomeric effect .
Positive
Negative
No effect
Stabilizes the molecule

A

Positive

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25
How influences electron-accepting deputies on mesomeric effect . Negative Positive No effect Destroys the molecule
Negative
26
Select subsequence stages reactions By mechanism SR initiation chain growth chain break
initiation → chain growth → chain break
27
Which hydrocarbons react according to Markovnikov's rule? hydrocarbons with an asymmetrical double bond aromatic hydrocarbons hydrocarbons containing a symmetrical double bond heterocyclic compounds
hydrocarbons with an asymmetrical double bond
28
Specify the color of the solution formed during the interaction of unsaturated hydrocarbons with bromine water colorless red blue brown
colorless
29
What acid is formed during the oxidation of toluene? benzoic acid aromatic aldehyde alcohol phenol
benzoic acid
30
In what diseases is there an accumulation of acetone in the body? for diabetes for inflammation for lung diseases for gastritis
for diabetes
31
What acid is formed during the hydrolysis of ethyl formate? methanoic acid ethanoic acid phthalic acid ethanol
methanoic acid
32
Specify a substance that is not related to carbonyl compounds ethanol ethanal acetone butanone
ethanol
33
Specify the substance that is oxidized by copper (II) hydroxide ethanal propanone alkene acetone
ethanal
34
What substance is oxidized by potassium permanganate in an acidic environment? styrene benzene acetone naphthalene
styrene
35
Which two reagents can be used to determine the non-limiting hydrocarbon content? bromine water Potassium permanganate in a neutral medium Phenols Pyridine
bromine water Potassium permanganate in a neutral medium
36
What compound is diphenhydramine a derivative of ? 2-aminoethanol (ethanolamine) choline betaine serine
2-aminoethanol (ethanolamine)
37
Which molecules contain both hydroxy and amino groups? Amino alcohols Amino acids Oxy acids Oxo acids
Amino alcohols
38
When oxoacids are reduced,... are formed. Hydroxy acids Amino acids Amino alcohols Aldehydes
hydroxy acids
39
What is formed when salicylic acid reacts with carboxylic acids? esters does not react methyl salicylate simple ethers
esters
40
What is formed when gamma -g hydroxybutyric acid is heated? γ-butyrolactone β-lactam β -lactone α-lactone
γ-butyrolactone
41
Pyruvic acid is involved in carbohydrate metabolism and is part of the Krebs cycle. Specify what class of compounds it belongs to? oxo acids catecholamines amino acids oxy acids(hydroxy acids)
oxo acids
42
Specify the qualitative reaction to glycerin glycerol + copper(II) hydroxide glycerol + nitric acid glycerol + sulfuric acid glycerol + calcium hydroxide
glycerol + copper(II) hydroxide
43
What properties do amino acids have? amphoteric neutral basic acidic
amphoteric
44
What compound is formed during the oxidation of cysteine? cystine citric acid lipoic acid methionine
cystine
45
Which compounds contain both a hydroxyl and a carboxyl group in a molecule? oxy acids oxo acids amino alcohols amino acids
oxy acids
46
Specify multifunctional connection glycerin acetoacetic acid glycolic acid glyoxylic acid
glycerin
47
Specify dicarbonic acid fumaric acid lactic acid crotonic acid pyruvic acid
fumaric acid
48
Which connections are formed at heating γ - hydroxy And γ - amino acids ? lactone and lactam lactide and lactim lactam and lactim lactam and diketopiperazine
lactone and lactam
49
Which compound has the maximum number of OH groups ? Glucose Ethylene glycol Glycerol Ethanol
Glucose (5) Ethylene glycol (2) Glycerol (3) Ethanol (1)
50
Name this compound: CH3 – CHNH2 – COOH in the following order: trivial (historical), rational and systematic IUPAC nomenclature
alpha-alanine → alpha-amino propionic acid → 2-amino propanoic acid
51
Select properties of hydroxy acids when heated forms lactide - lactic acid when heated, it forms an unsaturated acid - 3-hydroxybutanoic acid when heated, it forms butyrolactone - 4-oxybutanoic acid
when heated forms lactide - lactic acid when heated, it forms an unsaturated acid - 3-hydroxybutanoic acid when heated, it forms butyrolactone - 4-oxybutanoic acid
52
Specify the vitamin-like substance that is a structural element of complex lipids
choline
53
Nucleic acids contain nucleic bases: cytosine adenine guanine guanine cytosine pyrimidine purine adenine pyrimidine pyridine quinoline purine
cytosine adenine guanine
54
Pyrrole belongs to pi excess systems and is characterized by the reaction: electrophilic substitution electrophilic addition nucleophilic addition nucleophilic substitution
electrophilic substitution
55
Specify bicyclic connection xanthine furan pyrrole imidazole
xanthine
56
Identify a drug that is not a pyrazole derivative paracetamol analgin antipyrine amidopyrine
paracetamol
57
purine grounds nucleic acids refer to: adenine and guanine guanine and thymine adenine and uracil cytosine and uracil
adenine and guanine
58
Which amino acid contains an imidazole ring? histidine proline tryptophan arginine
histidine
59
Specify main forms vitamin RR nicotinic acid, nicotinamide ftivazid, furatsilin anabasine, konin antipyrine, amidopyrine
nicotinic acid, nicotinamide
60
Specify answer describing structure And properties uracil is a 2,4-dihydroxy derivative of pyrimidine is a protein component is an amino derivative of pyrimidine is a DNA component
is a 2,4-dihydroxy derivative of pyrimidine
61
Specify 2 six-membered heterocycle With two atoms nitrogen pyrazine, pyrimidine pyridine, pyrimidine pyrrole, pyrimidine pyrimidine, furan
pyrazine, pyrimidine
62
What is the role of barbituric acid derivatives in medicine? are hypnotics are tonics have a vasodilatory effect lower blood pressure
are hypnotics
63
What cycles does porphin consist of? pyrrole pyridine pyrimidine pyrazole
pyrrole
64
Specify the oxidation product of beta - methylpyridine lower blood pressure nicotinic acid pyridoxal n-methylpyridinium piperidine
nicotinic acid
65
What is furazolidone a derivative of? furan pyridine pyrrole thiophene
furan
66
Specify what properties does pyrrole have? slightly acidic basic strongly basic strongly acidic
slightly acidic
67
Give 2 characteristics of pyridine aromatic heterocyclic compound electron-deficient system pi-redundant system has acidic properties
aromatic heterocyclic compound electron-deficient system
68
According to the nature of the carbonyl group, monosaccharides are classified... Aldoses Simple ethers Complex ethers Heterocyclic compounds
Aldoses
69
General Name carbohydrates V this formula : C 6 H 12 O 6 Hexose Maltose Pentose Tetrose
Hexose
70
Which carbohydrate they call fruit sugar Fructose Glucose Galactose Maltose
Fructose
71
Which percent lactose V cow milk ? 4-5% 2-4% 5-6% 8-10%
4-5%
72
What class of compounds do monosaccharides belong to? Hetero-Polyfunctional compounds Polyfunctional compounds Aldehydes Alcohols
Hetero-Polyfunctional compounds
73
TO which one class carbohydrates relate ribose And deoxyribose ? Aldopentose Aldohexose Aldotetrose Ketopentose
Aldopentose
74
What compound can be used to obtain ethyl alcohol? Glucose Benzol Cumene(Kumol) Phenol
Glucose
75
Which carbohydrates are not hydrolyzed: Monosaccharide Polysaccharides Fructose Starch
Monosaccharide
76
How many stereoisomers are there in aldohexose: 16 2 4 12
16
77
How much carbon dioxide is released during the alcoholic fermentation of one mole of glucose? 44.8 L 22.4 L 11.2 L 67.3 L
44.8 L
78
What reaction can separate aldose from ketose? Oxidation Recovery Dehydration Fermentation
Oxidation
79
What acid is formed during the oxidation of the aldehyde group of aldohexose?/What acid is formed during the oxidation of the aldehyde group of aldohexose? Aldonic acid Gluconic acid Glyceric acid Glucuronic acid
Aldonic acid
80
Which monosaccharide belongs to ketohexoses?/What monosaccharide belongs to ketohexoses? Fructose Mannose Galactose Glucose
Fructose
81
Cyclic forms of monosaccharides by chemical nature Polyacetalss Chelates Ethers Esters
Polyacetalss
82
Monosaccharides that upon reduction form 6-atomic alcohols? fructose glucose xylose inositol
fructose glucose
83
What monosaccharide is part of ATP? ribose fructose glucose mannose
ribose
84
What monosaccharide residues does starch consist of? alfa-glyukopiranoza alpha-fructofuranose beta-glyukopiranoza alfa - glyukozamine
alfa-glyukopiranoza
85
Specify connection that refers to To heteropolysaccharides heparin glycogen dextrin starch
heparin
86
Specify carbohydrate animal organism glycogen cellulose starch raffinose
glycogen
87
Specify polysaccharide Not related To heteropolysaccharides glycogen muramine heparin hyaluronic acid
glycogen
88
Which compound is homopolysaccharide ? dextrin heparin hyaluronic acid chondroitin sulfate
dextrin
89
Xylitol is a sugar substitute for diabetes. Specify the method of obtaining xylitol xylose reduction xylose oxidation glucose oxidation glucose restoration
xylose reduction
90
Which disaccharide is synthesized in the mammary gland? lactose sucrose maltose cellobiose
lactose
91
Which disaccharide is formed at hydrolysis starch ? maltose sucrose glucose lactose
maltose
92
What kind of isomers are glucose And galactose? epimers diastereomers enantiomers trans isomers
epimers
93
Which disaccharide Not is formed at hydrolysis starch ? sucrose glucose maltose dextrin
sucrose
94
Specify polysaccharide Not related To heteropolysaccharides cellulose heparin muramin hyaluronic acid
cellulose
95
Specify heteropolysaccharides/ Geteropolisaxaridlarni belgilang hyaluronic acid, chondroitin sulfate glycogen, dextrin dextrin, chondroitin sulfate hyaluronic acid, dextrin
hyaluronic acid, chondroitin sulfate
96
Specify the properties describing heparin/ Geparinni tavsiflovchi xususiyatlarni ko'rsating heteropolysaccharide of connective tissue, found in the liver homopolysaccharide, exhibits protective action against bacteria monosaccharide, contains pyridine and pyrrole heterocycles constructed from two molecules of D-glucopyranose
heteropolysaccharide of connective tissue, found in the liver
97
Specify homopolysaccharides dextrans, cellulose glycogen, dextrin heparin, muramin hyaluronic acid, dextrin
dextrans, cellulose glycogen, dextrin
98
Select a property describing starch formed in plants during photosynthesis is a heteropolysaccharide a heteropolysaccharide of connective tissue, found in the liver a monosaccharide, contains pyridine and pyrrole heterocycles
formed in plants during photosynthesis
99
Indicate 3 substances that are formed during the hydrolysis of starch maltose dextrin glucose sucrose
maltose dextrin glucose
100
Select disaccharide fragments of cellulose and starch maltose cellobiose erythrose lactose
maltose cellobiose
101
Specify heteropolysaccharide which meets V tendons chondroitin sulfate hyaluronic acid heparin starch
chondroitin sulfate
102
A bipolar amino acid ion is formed: in internal neutralization when interacting with acids when interacting with alkalis when interacting with oxides
in internal neutralization
103
Amino acids are amphoteric compounds because: due to the presence of carboxyl and amino groups in its composition reacts with water forms ethers due to the presence of amino and hydroxyl groups in its composition.
due to the presence of carboxyl and amino groups in its composition
104
What is the name of the closest homologue of glycine: alanine cysteine threonine phenylalanine
alanine
105
What is the mass fraction of carbon in a glycine molecule: 32% 40% 65% 50%
32%
106
Glycine forms a peptide bond in a reaction with : alanine sulfuric acid aniline hydrogen chloride
alanine
107
Glycine and alanine are: homologues conformers hydrogen chloride same substance structural isomers
homologues
108
Alpha -amino acids include compounds in which: Both functional groups are attached to the same carbon atom. Both functional groups are attached to different carbon atoms. One functional group is attached to a carbon atom, and the other to a hydrogen atom.
Both functional groups are attached to the same carbon atom.
109
The removal of a proton from a carboxyl group and the addition of a proton to an amino group results in the formation of: bipolar ion monopolar ion tripolar ion nonpolar ion
bipolar ion
110
The amino acid that does not belong to the left-handed optical isomers is: Glycine Cysteine Phenylalanine
Glycine
111
Essential amino acids include: Tryptophan Serine Glycine Asparagine
Tryptophan
112
What amino acid is not synthesized by the body with phenylketonuria: Tyrosine Lysine Alanine Cysteine
Tyrosine
113
Glycine is used as: anti-stress agent antihypertensive agent antiparkinsonian agents pancreatic diseases
anti-stress agent
114
What reagent is used to protect the carboxyl group? C2H5OН C2H5NH2 C2H5OC2H5 NaOH
C2H5OН
115
Specify the protein that is a component of tendons, skin, blood vessels Collagen Globular Albumin Endorphins
Collagen
116
The primary structure of a protein is… amino acid sequence in a polypeptide chain disulfide bond spatial arrangement of a protein molecule
amino acid sequence in a polypeptide chain
117
What determines the tertiary structure of a protein: Polypeptide helix spiralization Polypeptide chain formation Oligomer formation Amino acid sequence
Polypeptide helix spiralization
118
How many dipeptides can be obtained from just three amino acids? / How many amino acids can be obtained from just three amino acids?: 6 2 4 3
6
119
What is the main bond in the formation of the primary structure of a protein? Peptide Hydrogen Vodorod Covalent
Peptide
120
The presence of what bonds determines the secondary structure of proteins./What are the secondary structure bonds of proteins? Hydrogen peptide covalent amide
Hydrogen
121
Which of the protein macromolecule structures has a helical shape?/ What are the helical shapes of macromolecules? Secondary Tertiary Primary Quaternary
Secondary
122
What protein structure is characterized by globule formation? Tertiary Primary Secondary Quaternary
Tertiary
123
For which protein was the amino acid sequence first deciphered?/ What amino acid sequences were determined for the first time? Insulin Hemoglobin. Collagen Myoglobin
Insulin
124
Fibrillar proteins include... Keratin Albumin Globulin No correct answer
Keratin
125
What compounds are monomers of protein molecules? Amino acids Glycerin Glucose Fatty
Amino acids
126
The primary structure of proteins is determined by ... amino acid sequence chemical properties of amino acids molecular weight number of amino acids
amino acid sequence
127
Specify the enzyme that breaks down peptide bonds peptidase lysozyme transaminase pepsin
peptidase
128
Between which amino acids is an ester bridge formed in the tertiary structure of a protein? / What amino acids are ester bridges formed between? serine and aspartic acid aspartic acid and lysine cysteine and cysteine leucine and leucine
129
What amino acids are involved in the formation of ionogenic interactions in the tertiary structure of proteins? aspartic acid and lysine serine and aspartic acid leucine and leucine cysteine and cysteine
aspartic acid and lysine
130
Find a substance that is not part of nucleic acids fructose deoxyribose ribose adenine
fructose
131
Specify saponifiable lipids glycerophospholipids terpenes adenine geraniol steroids
glycerophospholipids
132
The consistency of triglycerides is liquid if they contain… a lot of unsaturated fatty acids etheric connections a lot of saturated fatty acids phospholipids
a lot of unsaturated fatty acids