chem sikli sorular Flashcards
(132 cards)
What is configuration?
spatial arrangement of atoms in a molecule
arrangement of molecules on one plane
arrangement of atoms on one plane
definition of molecular structure
spatial arrangement of atoms in a molecule
Specify the energetically stable conformation for ethane
inhibited obscured skewed gauche
inhibited
A carbon atom that is bonded to four different atoms or groups is called
asymmetrical symmetrical mobile non-chiral
asymmetrical
Specify the achiral molecule
benzene
2-hydroxypropanoic acid 2-aminopropanoic acid 3-hydroxybutanoic acid
benzene
For which substance is optical isomerism observed?
Alanine Glycine Acrylic acid
methane
Alanine
What is the second name for optical isomerism?
Mirror isomerism Cis-trans isomerism There is no correct answer Geometric
isomerism
Mirror isomerism
Specify the isomers.
pentine-1 and pentine-2
3-methylpentane and 3-methylhexane
ethene and ethyne
butadiene and butene
pentine-1 and pentine-2
What is the name of the isomerism between pentane and isopentane?
Carbon skeleton Substituent positions Geometrical Conformational
Carbon skeleton
Which compounds exhibit geometric isomerism?
Butene-2
Butane
Isobutane
Butin
Butene-2
What is the second name for geometric isomerism?
Cis-trans isomerism
Metamerism Optical isomerism Enantiomerism
Cis-trans isomerism
Isomerism for the specified compounds CH 3 – CH 2 – CH 2 – CH 2 – OH and
CH 3 - CH( OH) – CH 2 – CH 3
refers :
functional group position isomerism
spatial isomerism
carbon chain isomerism
multiple bond position isomerism
functional group position isomerism
Specify homologue alkanes With whom it begins phenomenon isomerism
butane
pentane
heptane
propane
butane
Isomers are substances:
having the same qualitative and quantitative composition, but different structure
having the same qualitative composition, but different structure
having the same quantitative composition, but different structure
none of the answers is correct
having the same qualitative and quantitative composition, but different structure
Projection formulas are used to depict conformations.….
Newman Fisher Misher Rozanov
Newman
D- and L - lactic acids is called ….
racemic
optical
enantiomers
diastereomers
racemic
Which of these functional groups is considered the main one? -COOH -SO3H -NH2
COOH
Characteristic reactions for alkanes
SR АN АЕ SE
SR
Select a catalyst for benzene bromination
FeBr3
FeCl3
KCl
MgCl2
FeBr3
What is formed during the bromination of toluene?
2,4,6-tribromotoluene 2,4,6-tribromotoluene 1,2,3-tribromotoluene 2,3,5-
tribromotoluene
2,4,6-tribromotoluene
What is the mesomeric effect?
this is the transfer of the electronic influence of substituents along the conjugated system of
π-bonds
this is an increase in the electron density in the system
this is a decrease in the electron density in the system
this is a decrease in the energy of the molecule due to conjugation
this is the transfer of the electronic influence of substituents along the conjugated system of
π-bonds
What is the inductive effect?
is a redistribution of electron density along the sigma bond
is a decrease in the energy of the molecule due to conjugation
is a redistribution of electron density along the pi bond
is a redistribution of electron density along the sigma and pi bonds
is a redistribution of electron density along the sigma bond
By what mechanism does benzene sulfonation occur?
by electrophilic substitution
by electrophilic addition
by nucleophilic substitution
by nucleophilic addition
by electrophilic substitution
Electron acceptor Substitutes ( EA ):
Substituents that decrease the electron density in the system
Substituents that increase the electron density in the system
Substituents that do not affect the electron density in the system
Increases the stability of the molecule
Substituents that decrease the electron density in the system
How to influence electron donor deputies on mesomeric effect .
Positive
Negative
No effect
Stabilizes the molecule
Positive