Controlling The Position Of Equilibrium Flashcards

1
Q

What does a catalyst do to the equilibrium position

A

It doesn’t affect the equilibrium position, however it increases the rate at which equilibrium is established

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2
Q

Does changing the concentration, pressure or adding catalysts change the value of Kc/Kp

A

No it doesn’t

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3
Q

What is the only factor that affects the equilibrium constant(K)

A

Temperature

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4
Q

What effects does an increase in temperature have on the equilibrium constant in an endothermic reaction (the opposite applies to exothermic reactions )

A

The equilibrium constant increases as temperature rises and equilibrium moves to the right , giving a higher yield of products

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5
Q

the formula for Kc of a reaction with equation: aA+bB= cC+dD

A

kc= [C]^c[D]^d/[A]^a[B]^b
or basically products/reactants

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6
Q

if Kc=1, it means

A

the position of equilibrium is halfway between the reactants and the products and that the concentration of the reactants is equal to that of the products

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7
Q

if Kc is bigger than 1, it means

A

the equilibrium position is to the right and [products]>[reactants]

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8
Q

if Kc< 1, it means

A

the equilibrium position is to the left of the equation

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9
Q

the larger the value of Kc, the ………………. the equilibrium position lies

A

further to the right

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10
Q

homogeneous equilibrium

A

an equilibrium where all species are in the same physical state

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11
Q

heterogeneous equilibrium

A

it contains species in at least two different states

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12
Q

in Kc expressions for heterogeneous equilibriums, we only include species in which states?

A

aqueous and gaseous

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13
Q

the formula for the mole fraction of a species
(there are two alternatives )

A

number of moles of the species/ total number of moles

or

volume of the species/ total volume of gas mixture

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14
Q

the total mole fraction equals?

A

1

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15
Q

the formula for calculating the total pressure

A

sum of the partial pressures

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16
Q

how do we represent the partial pressure of a species called A

A

p(A)

17
Q

the formula for the partial pressure

A

mole fraction* total pressure

18
Q

do we use square brackets in expressions for partial pressures

A

no, because square brackets represent the concentration of species

19
Q

in a heterogeneous equilibrium only includes ………….. species in a Kp expression

A

gaseous

20
Q

according to le chatelier’s principle, what happens when you increase the concentration of a species

A

the equilibrium shifts to the direction that reduces concentration

21
Q

an equilibrium constant will only change if what changes

A

temperature

22
Q

is the equilibrium constant affected by changing the pressure, concentration, or adding a catalyst

A

no it is not

23
Q

what happens to equilibrium position as temperature rises in endothermic reactions

A

equilibrium constant increases, so the position of equilibrium moves to the right, to produce a higher yield of products

24
Q

is the equilibrium constant affected by changing the pressure, concentration, or adding a catalyst?

A

no it is not

25
Q

what happens to equilibrium position as temperature rises in exothermic reactions

A

the equilibrium constant constant decreases, so the equilibrium position moves to the left, giving a lower yield of products