Electrolysis Flashcards

(12 cards)

1
Q

What are electrolytes

A

ionic compounds in the molten state or dissolved in water

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2
Q

How do ions move in electrolysis

A

positive cations migrate to the negatively charged cathode
negative anions migrate to the positively charged anode

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3
Q

Describe electrolysis

A

a process in which electrical energy from a direct current supply, decomposes electrolytes

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4
Q

What is an electrolyte

A

liquids through which a current can flow

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5
Q

When a solution is electrolysed what occurs at the cathode

A

In a mixture of ions the H^+ and the other positive ions are present. It is the ion which is lower in the reactivity series that will be discharged and reduced

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6
Q

When a solution is electrolysed what occurs at the anode

A

If the solution contains a halide ions, they are discharged and released from the anode, otherwise if the solution contains other negative ions like sulphate and nitrate oxygen is released at the anode

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7
Q

What occurs at the cathode

A

reduction

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8
Q

What occurs at the anode

A

oxidation

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9
Q

What happens when copper sulphate is electrolysed with copper electrodes

A

The mass of the cathode increases as copper is deposited there and the mass of the copper anode decreases as copper is removed

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10
Q

How can copper be electrolysed to purify it

A

The cathode is a small piece of pure copper and the anode is a large piece of impure copper. The copper ions move to the cathode and as copper is likely the least reactive it is produced at the cathode
the impurities move towards the anode and are deposited there

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11
Q

How is aqueous sulphuric acid electrolysed

A

with a Hofmann Voltameter
oxygen and hydrogen are produced

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12
Q

What is formed when copper is electrolysed with inert electrodes

A

Copper at the cathode and oxygen at the anode

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