energy Flashcards

(44 cards)

1
Q

what is energy

A

the basic constituent of the universe and its the capacity to do work

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2
Q

work is powered by

A

ATP

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3
Q

what is thermodynamics

A

study of energy transformations that accompany physical and chemical changes

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4
Q

what are bioenergetics

A

branch that deals with living organisms

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5
Q

bioenergetics is imp for

A

understanding biochemical reactions

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6
Q

enthalpy

A

total heat (delta H)

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7
Q

entropy

A

state of disorder (delta s)

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8
Q

free energy

A

energy available to do chemical work (delta g)

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9
Q

energy exchange

A

heat or work

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10
Q

energy

A

equal to enthalapy H= q+w

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11
Q

H is -ve

A

gives off heat and is exothermic

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12
Q

H is +ve

A

takes in heat and is endothermic

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13
Q

H is zero

A

no heat exchanged: isothermic

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14
Q

free energy delta G

A

related to delta H

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15
Q

free energy

A

used to predict spontaneity

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16
Q

-ve delta g

A

spontaneous and exogernic

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17
Q

+ve delta g

A

nonspontaneous and endergonic

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17
Q

delta g is zero

18
Q

standard free energy

19
Q

biochemical reactions need to proceed

A

if delta g is +ve

20
Q

free energy are

21
Q

external energy is provided by

A

ATP hydrolysis

22
Q

spontaneous aggregation of non-polar

A

negative delta g

23
Q

aggregation decreases the surface area

A

of their contact with water

24
why is Spontaneous exclusion of water imp
for membrane formation and protein folding
25
2 reactions provide energy and drive metabolic processes
phosphorylation and redox
26
phosphorylation
inorganic group bonds w another molecule (ATP)= product is adenosine diphosphate
27
redox reaction
transferred from reduced to oxidized (NADH,NADPH,FADH2)
28
adenosine triphosphate
nucleotide plays and extraordinarily imp role in living cells
29
hydrolysis of ATP
ATP->ADP+Pi for free energy
30
drives reactions to several types
-biosynthesis of biomolecules -active transport across membrane -mechanical work such as muscle contraction
31
whats ATP
a nucleotide composed of adenine, ribose and triphosphate
32
structure of ATP
2 terminal phosphoryl groups linked by phosphoanhydride bonds, facilitate ATP hydrolysis
33
ATP undergoing hydrolysis
phosphoryl group tranfer potential
34
ATP acts as an energy
cuz it can carry phosphoryl groups from high energy to low energy
35
why ATP is exergonic
-has multiple -ve charges, resonance stabilization products of ATP hydrolysis more stable
36
resonance stabilization
when a molecule has 2 or more alternative that differs only in position of their electrons
37
why ATP is exergonic
hydrolysis is more solvated, increase in disorder w more molecules
38
NADH, NADPH and FADH2
all electron carriers w reducing power, donate high energy electrons in cellular redox reaction
39
NADH
for energy capturing in the complete oxidation of glucose and fatty acids and yield large amounts of ATP
40
NADPH
donates high energy electrons in biosynthesis of fatty acids and cholestrol, imp antioxidant
41
FADH2
from FAD, large variety of redox reactions
42
FAD2 most imp roles
citric acid cycle and a product of fatty acid degradation
43