lipids Flashcards

(38 cards)

1
Q

what are lipids

A

substances from living things that dissolve in nonpolar solvents

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2
Q

what are lipids used for

A

energy storage, mm structure, chemical signals, vitamins, pigments

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3
Q

Lipids can be subdivided into the following classes:

A
  1. Fatty acids
  2. Triacylglycerols
  3. Wax esters
  4. Phospholipids
  5. Sphingolipids
  6. Isoprenoids
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4
Q

what are fatty acids

A

Monocarboxylic acids that typically contain
hydrocarbon chains of variable lengths

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5
Q

how are fatty acids numbered

A

from carboxylate end and, a-carbon is adjacent to carboxylate group

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6
Q

what is denoted the omega (ω) carbon

A

Terminal methyl carbon

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7
Q

palmitic acid

A

CH3(CH2)12CH2COOH (16:0)

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8
Q

stearic acid

A

CH3(CH2)12CH2CH2CH2CH2COOH (18:0)

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9
Q

oleic acid

A

H H
| |
CH3(CH2)4C=C(CH2)7COOH (18:1)

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10
Q

linoleic acid

A

CH3(CH2)4CH=CH-CH2-CH=CH(CH2)7COOH (18:2)

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11
Q

a-linolenic acid

A

CH3CH2CH=CH-CH2-CH=CH-CH2-CH=CH(CH2)7COOH (18:3)

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12
Q

arachidonic acid

A

CH3(CH2)3-(CH-CH=CH)-(CH2)3COOH (20:4)

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13
Q

what do most naturally fatty acid have

A

even numbers of carbons in an unbranched chain

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14
Q

Fatty acids that contain only single carbon-carbon bonds are

A

saturated

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15
Q

Fatty acids that contain one or more double bonds are

A

unsaturated

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16
Q

cis

A

like group on same side

17
Q

trans

A

like groups are on opposite sides

18
Q

double bond in naturally occurring fatty acids are

A

cis cause a kink in fatty acid chain

19
Q

unsaturated fatty acids are

A

liquid at room temp

20
Q

saturated fatty acids are

21
Q

monounsaturated fatty acids have

A

1 double bond

22
Q

polyunsaturated fats have

23
Q

plants and bacteria can

A

synthesize all fatty acids they require from acetyl-CoA

24
Q

omega-6-fatty acids

A

linoleic acid and its derivatives

25
omega-3-fatty acids
a-linoleic acid and its derivatives (promote cardiovascularlar health)
26
diets w omega 6 and 3 fatty acids
lower blood levels of triacylglycerol and bp and platelet pressure
27
what are Essential fatty acids are used as
structural components, precursors from imp metabolites
28
what are fatty acid's imp chem properties
-react w alcohols to form esters -Unsaturated fatty acids with double bonds can undergo hydrogenation reactions to form saturated fatty acids -Certain fatty acids are covalently attached to proteins called acylated proteins
29
what configuration do fatty acid double bond have
cis
30
trans fatty acids are common in nature
false
31
what is hydrogenation treatment used for
converting polyunsaturated plain oils into margarine to trans double bond
32
what do acyl groups do
help facilitate the interactions between membrane proteins and their hydrophobic environment
33
what are Myristoylation and palmitoylation
most common form of protein acylation
34
what do Myristoylation and palmitoylation do
influence a variety of structural and functional properties of protein
35
where are hydrophobic fatty acid molecules transported from
fat cells to body cells for energy yielding redox reaction (acylation of water-soluble serum proteins)
36
what are eicosanoids
diverse group of powerful hormone-like molecule produced in most mammalian tissues
37
what r the 3 major typers of eicosanoids
-prostaglandins -thromboxanes -leukotrienes
38
eicosanoids goes through wide variety of physiological processes which are
smooth muscle contraction, inflammation, pain perception, and blood flow regulation