lipids Flashcards
(38 cards)
what are lipids
substances from living things that dissolve in nonpolar solvents
what are lipids used for
energy storage, mm structure, chemical signals, vitamins, pigments
Lipids can be subdivided into the following classes:
- Fatty acids
- Triacylglycerols
- Wax esters
- Phospholipids
- Sphingolipids
- Isoprenoids
what are fatty acids
Monocarboxylic acids that typically contain
hydrocarbon chains of variable lengths
how are fatty acids numbered
from carboxylate end and, a-carbon is adjacent to carboxylate group
what is denoted the omega (ω) carbon
Terminal methyl carbon
palmitic acid
CH3(CH2)12CH2COOH (16:0)
stearic acid
CH3(CH2)12CH2CH2CH2CH2COOH (18:0)
oleic acid
H H
| |
CH3(CH2)4C=C(CH2)7COOH (18:1)
linoleic acid
CH3(CH2)4CH=CH-CH2-CH=CH(CH2)7COOH (18:2)
a-linolenic acid
CH3CH2CH=CH-CH2-CH=CH-CH2-CH=CH(CH2)7COOH (18:3)
arachidonic acid
CH3(CH2)3-(CH-CH=CH)-(CH2)3COOH (20:4)
what do most naturally fatty acid have
even numbers of carbons in an unbranched chain
Fatty acids that contain only single carbon-carbon bonds are
saturated
Fatty acids that contain one or more double bonds are
unsaturated
cis
like group on same side
trans
like groups are on opposite sides
double bond in naturally occurring fatty acids are
cis cause a kink in fatty acid chain
unsaturated fatty acids are
liquid at room temp
saturated fatty acids are
solid
monounsaturated fatty acids have
1 double bond
polyunsaturated fats have
2 or more
plants and bacteria can
synthesize all fatty acids they require from acetyl-CoA
omega-6-fatty acids
linoleic acid and its derivatives