Etc Flashcards

(43 cards)

1
Q

NADH carries

A

2 e and 1 H+

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2
Q

NADH reversible?

A

Yes

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3
Q

FADH (FMNH) carries

A

1 e and 1 H+

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4
Q

FADH2 (FADH2) carries

A

2 e and 2 H+

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5
Q

FAD/FMN reversible?

A

tightly bound to proteins

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6
Q

FAD and FMN reduction potential

A

vary significantly with protein microenvironment

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7
Q

*QH carries

A

1 e and 1 H+

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8
Q

QH2 carries

A

2 e and 2 H+

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9
Q

coenzyme Q reversible?

A

yes

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10
Q

hemes carry

A

1 e-

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11
Q

heme reversible?

A

tightly bound or covalently bonded to proteins

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12
Q

cytochrome

A

protein with bound heme

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13
Q

Fe-S clusters carry

A

each Fe in an Fe-S cluster can carry 1 e

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14
Q

Fe-S clusters reversible?

A

covalently bonded to proteins by cysteine side chain sulfur ligands

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15
Q

Cu centers carry

A

1 e

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16
Q

Cu centers reversible?

A

covalently bonded to proteins by cysteine side chain sulfur ligands

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17
Q

intermembrane space charge

A

postitive

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18
Q

matrix charge

19
Q

what does the matrix contain

A

PDH, enzymes of the citric acid cycle, FA degradation pathways

20
Q

complex 1 input substrate

21
Q

complex 1 output e-carrier

22
Q

complex 1 number of H+ pumped to P side

23
Q

complex 1 number of H+ pumped to QH2

24
Q

complex 2 input substrate

25
complex 2 output substrate
coenzyme Q
26
complex 2 number of H+ pumped
0
27
complex 3 input substrate
coenzyme Q
28
complex 3 output substrate
Cytochrome C
29
complex 3 number of H+ pumped to P side
4
30
complex 4 input substrate
cytochrome c
31
complex 4 output e carrier
32
complex 4 number of H+ pumped to P side
2
33
order of ETC cofactors
1. NAD 2. FAD/FMN 3. Coenzyme Q 4. Hemes 5. Fe-S clusters 6. Cu clusters
34
ways that NADH can enter the ETC
Malate/Asp Lactate shuttle TCA
35
ways that FADH2 can enter the ETC
TCA Glycerol phosphate shuttle
36
which verision of coenzyme Q is fullly oxidized
ubiquinone
37
which verision of coenzyme Q is fully reduced
uniquinol
38
which verision of coenzyme Q is partly reduced
semiquinone
39
P/O ratio
ATP produced per O2 reduced
40
% effiency
eoutput/einput or delta g transport/delta g hydrolysis
41
delta G of moving a proton across the membrane
+ 18.9 kJ/mol
42
how many H+ pumped per NADH
10
43
per nadh+h what is made
nad fumerate .5o2 + 2H+ -> h2o