ps Flashcards

1
Q

light reactions make

A

ATP and NADPH

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2
Q

dark reactions use what to run what

A

ATP and NADPH to turn pentose phosphate and glycolysis in reverse

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3
Q

E = hc/gamma what are all the variables

A

h = planck’s constant
c = velocity of light
gamma = wavelength

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4
Q

electron transfer

A

chemical breakdown by ejection of the excited electron

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5
Q

resonance transfer

A

transfer of energy to adjacent molecule with same energy gap

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6
Q

why ultraviolet light bad

A

energy too high, will break covalent bonds

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7
Q

why infrared bad

A

energy too low, bond rotation and vibration

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8
Q

role of accessory pigment

A

can harvest more light in the EMS

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9
Q

chlorophylls

A

magnesium, looks similar to heme-like porphyrin ring

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10
Q

carotenoids

A

long chian with double bonds flanked by two rings
isoprenoid unit

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11
Q

phycobilins

A

open chain tetrapyrolls
similar to unwound chlorophylls

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12
Q

phytol side chain

A

chlorophyll, anchor in membrane

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13
Q

what starts e- flow

A

light absorption

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14
Q

what type of transfer is antenna molecule passing energy to neighboring chlorophyll molecules

A

resonance energy transfer

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15
Q

what type of transfer is privileged chlorophyll to electron acceptor

A

electron transfer

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16
Q

H+ pump

A

cytochrome b6f complex

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17
Q

1 e- carriers

A

ferredoxin
plastocyanin

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18
Q

the etc pumps protons from

A

stroma to lumen

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19
Q

how many photons per electron

A

one

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20
Q

what is reduced by e- transferred from chlorophyll

A

ferredoxin

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21
Q

what refills the reaction center “special pair” of chlorophyll molecules

A

plastocyanin

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22
Q

ps1 cylic flow

A

light -> p700 -> fd -> cytb6f -> plastocyanin and pumps protons

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23
Q

how many protons pumped per photon cytb6f

24
Q

ps1 wavelength at which chromophore absorbs max

25
input for cytochrome b6f
plastoquinone PQH2 (PSII) or 2 ferredoxin fd (ps1)
26
output for cytochrome b6f
2 molecules of plastocyanin (cu) 1 e- carrier
27
what is cytochrome b6f homologous to
complex 3 of mitochondiral repiratory chain
28
how are e- replaced in noncylic flow
ps2 uses h2o as e- source to replensih cyt b6f
29
ps2 wavelength at which chromophore absorbs max
p680
30
what helps catalyze splitting of water in ps2
mn4 clutster and tyrosine
31
ps2 equation
2h2o -> 4H+ + 4e- + o2
32
ps1 + ps2 equation
2 nadp + 3 adp + 3 hpo42- + H + 8 photons -> o2 + 3 atp + 2 NADPH + h2o
33
how many protons pumped per photon in ps2
1
34
p side in thylakoid
lumen
35
n side in thylakoid
stroma
36
rubscio type of enzyme
carboxylase/oxygenase
37
ruscio components
Mg2+ complexed to lysine 201 carbamate
38
rubisco mechanism
enediolate intermediate forms new c-c bond
39
rubisco octomer
cooperativity
40
hexose production equation
6 RuBP + 6 CO2 -> 12 (GAP or DHAP)
41
how many gap and dhap are siphoned off to regenerate rubp
4 gap and 2 dhap
42
what is needed in regenerating rubp
atp
43
is there redox in regenerating rubp
no, shuffling carbons
44
dark reactions equation
6 CO2 + 18 ATP + 12 NADPH + 12 H2O -> C6H12O6 + 18 ADP + 18 HPO42- +12 NADP + 6H
45
net reaction of photosynthesis
6 co2 + 6 h2o _ 48 photons -> c6h12o6 + 6 o2
46
photorespiration where
peroxisome via detour thorugh mitochondrion
47
photorespiration mechanism
reverse of carbon fixation (uses o2 and makes co2) wasterd rubp must be regenerated requires atp input
48
what have c4 plants done
evolved way to concentrate co2 to minimize side reactions
49
rubisco stimulated by
high pH co2 and mg2+ when reduced fd build up, reduces disulfies to activate DR enzymes
50
mg2+ moves from ____ to _____
lumen to stroma
51
H+ move from _____to ______
stroma to lumen
52
reverse of what is in rubisco mechanism
beta carboxylation
53
logic of calvin ycle
need to reduce C from CO2 to normal carb oxygen state
54
enzymes involved in regenerating rubp
transketolases and transaldolases
55
cyclic flow used
to pump protons
56
how manhy protons pumped in ps1
2H+ per photon
57
noncylic flow used
for biosynthesis