Halogenoalkanes Flashcards
(7 cards)
What allows halogenoalkanes to be good targets for nucleophiles
the polarity of the carbon halogen bond as they are more electronegative than the carbon
What is the name for the reaction where a halogenoalkane is substituted
Nucleophilic substitution
Draw a general nucleophilic sub mechanism where x is the nucleophile
What is the name for the reaction where halogenoalkanes produce alkenes
Elimination
What are the conditions for elimination
heated under reflux with an alkali like potassium hydroxide (KOH) dissolved in ethanol
What is the difference in conditions for nucleophilic sub and elimination
Substitution is favoured in aqueous solution. OH- acts as a nucleophile.
Elimination is favoured in ethanolic solution. OH- acts as a base.
Draw an elimination reaction between 2-iodopropane and KOH-