Lipid structures Flashcards

1
Q

Structure of fatty acid

A

Long hydrocarbon tail, methyl at one end, carboxyl at the other end

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2
Q

In humans there’s an ____ number of carbons in fatty acid

A

Even

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3
Q

How many carbons in fatty acids in humans

A

16 to 20

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4
Q

How many carbons in stearic acid

A

18

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5
Q

How many carbons in palmitic acid

A

16

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6
Q

What is arachidonic acid

A

One of C20 PUFA precursor of eicosanoid hormone

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7
Q

Which FA has 3 double bonds and 18 carbons

A

a-linolenic acid (essential FA)

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8
Q

Which FA has one double bond in the middle and 18 carbons

A

Oleic acid

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9
Q

Which FA has 4 double bonds and 20 carbons

A

Arachidonic acid

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10
Q

FA is attained by

A

ester linkages

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11
Q

More solid fast have more

A

Saturated fats

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12
Q

What causes the kinks in triglycerides

A

Cis double bonds

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13
Q

Which FA are tightly packed and have a high boiling point

A

Linear saturated

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14
Q

All natural unsaturated fats contain

A

Cis bonds

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15
Q

Trans fat is made during

A

Partial dehydrogenation of unsaturated fats

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16
Q

What is trans fat

A

partially dehydrogenated unsaturated fats

17
Q

What does partially dehydrogenated unsaturated fats do

A

Increases shelf life and allows for high temp. cooking

18
Q

What happens when the double bonds in unsaturated fats are fully oxidized

A

It becomes spoiled faster

19
Q

All unsaturated fats contain

A

Cis bonds

20
Q

What happens during partial hydrogenation of unsaturated fats

A

Isomerization

21
Q

Partial dehydrogenation of unsaturated fats raise

A

Melting point so that fat is solid

22
Q

Trans fat increases

A

Endogenous cholesterol

23
Q

What does an increase in trans fat lead to

A

Atherosclerosis

24
Q

Saturated fats ALSO…

A

Increase cholesterol, but to a lesser extent

25
Q

What is glycerolphospholipids made of

A

glycerol backbone attached to 2 FA chains and 1 phosphate group

26
Q

Glycerolphospholipids are important in

A

Cell membrane structure

27
Q

Lecithin

A

Phosphatidyl choline (emulsifying agent)

28
Q

Which phosphoacylgycerol is an emulsifying agent

A

Phosphatidylcholine

29
Q

What is the simplest glycerophospholipid

A

Phosphatidic acid

30
Q

How do you make a lysolipid structure

A

remove one of the FA chains from a phosphoacylglycerol

31
Q

WHat does a spingospine backbone consist of

A

one FA chain and one head group

32
Q

What is the head group in the sphingospine backbone

A

Glycolipid sugar head group, usually cerebrosides or gangliosides

33
Q

Ceramide linked to a phosphorylcholine via amide bond is

A

Sphingomyeling

34
Q

Ceramide linked to a galactose via amide bond is

A

Galactocerebroside

35
Q

Ceramide linked to a oligosaccharide via amide bon dis

A

Ganglioside

36
Q

Do unsaturated or saturated fatty acids have a higher melting point

A

Saturated

37
Q

Acylglyceride structure

A

One or more FA chains attached by ester linkages

38
Q
A