Lipid structures Flashcards

1
Q

Structure of fatty acid

A

Long hydrocarbon tail, methyl at one end, carboxyl at the other end

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2
Q

In humans there’s an ____ number of carbons in fatty acid

A

Even

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3
Q

How many carbons in fatty acids in humans

A

16 to 20

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4
Q

How many carbons in stearic acid

A

18

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5
Q

How many carbons in palmitic acid

A

16

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6
Q

What is arachidonic acid

A

One of C20 PUFA precursor of eicosanoid hormone

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7
Q

Which FA has 3 double bonds and 18 carbons

A

a-linolenic acid (essential FA)

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8
Q

Which FA has one double bond in the middle and 18 carbons

A

Oleic acid

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9
Q

Which FA has 4 double bonds and 20 carbons

A

Arachidonic acid

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10
Q

FA is attained by

A

ester linkages

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11
Q

More solid fast have more

A

Saturated fats

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12
Q

What causes the kinks in triglycerides

A

Cis double bonds

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13
Q

Which FA are tightly packed and have a high boiling point

A

Linear saturated

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14
Q

All natural unsaturated fats contain

A

Cis bonds

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15
Q

Trans fat is made during

A

Partial dehydrogenation of unsaturated fats

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16
Q

What is trans fat

A

partially dehydrogenated unsaturated fats

17
Q

What does partially dehydrogenated unsaturated fats do

A

Increases shelf life and allows for high temp. cooking

18
Q

What happens when the double bonds in unsaturated fats are fully oxidized

A

It becomes spoiled faster

19
Q

All unsaturated fats contain

20
Q

What happens during partial hydrogenation of unsaturated fats

A

Isomerization

21
Q

Partial dehydrogenation of unsaturated fats raise

A

Melting point so that fat is solid

22
Q

Trans fat increases

A

Endogenous cholesterol

23
Q

What does an increase in trans fat lead to

A

Atherosclerosis

24
Q

Saturated fats ALSO…

A

Increase cholesterol, but to a lesser extent

25
What is glycerolphospholipids made of
glycerol backbone attached to 2 FA chains and 1 phosphate group
26
Glycerolphospholipids are important in
Cell membrane structure
27
Lecithin
Phosphatidyl choline (emulsifying agent)
28
Which phosphoacylgycerol is an emulsifying agent
Phosphatidylcholine
29
What is the simplest glycerophospholipid
Phosphatidic acid
30
How do you make a lysolipid structure
remove one of the FA chains from a phosphoacylglycerol
31
WHat does a spingospine backbone consist of
one FA chain and one head group
32
What is the head group in the sphingospine backbone
Glycolipid sugar head group, usually cerebrosides or gangliosides
33
Ceramide linked to a phosphorylcholine via amide bond is
Sphingomyeling
34
Ceramide linked to a galactose via amide bond is
Galactocerebroside
35
Ceramide linked to a oligosaccharide via amide bon dis
Ganglioside
36
Do unsaturated or saturated fatty acids have a higher melting point
Saturated
37
Acylglyceride structure
One or more FA chains attached by ester linkages
38