module 8: lipids Flashcards

(56 cards)

1
Q

what is the defining feature of lipids?

A

insoluble in water

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2
Q

lipids form ( ) rather than polymers

A

aggregates

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3
Q

true or false: lipids have the lowest molecular weight compared to other biomolecules

A

true

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4
Q

how to fatty acids differ?

A

length & degree saturation

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5
Q

what are fatty acids?

A

hydrocarbon derivatives

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6
Q

how many double bonds so saturated & unsaturated fatty acids have?

A

saturated: 0
unsaturated: 1

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7
Q

what configuration are double bonds usually found in?

A

cis configuration

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8
Q

how are double bonds usually separated?

A

by a methylene group

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9
Q

do long chain fatty acids have stronger or weaker associates than short chains?

A

stronger

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10
Q

do saturated chains have stronger or weaker associates than unsaturated chains?

A

stronger

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11
Q

what does the melting temperature of a fatty acid reflect?

A

length & degree of saturation

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12
Q

fatty acids required for energy are stored as?

A

triacylglycerols

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13
Q

lipids occupy most of the ( ) space in ( )

A

intracellular, adipocytes

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14
Q

what are triacylglycerols?

A

3 fatty acids linked to glycerol through ester linkages

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15
Q

what does the ester linkage remove?

A

the polar caroboxyl group to make hydrophobic molecule

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16
Q

there is ( )x as much energy in lipids than carbohydrates?

A

6x

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17
Q

do triaclyglycerols have lower or higher oxygenation & hydration state than carbohydrates?

A

lower

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18
Q

what is saponification?

A

fat breaks ester linkages to release free fatty acids

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19
Q

what are micelles?

A

individual wedge-shaped units

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20
Q

what does olestra consist of?

A

8 fatty acids linked to a sugar group

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21
Q

what is wax made of?

A

non-polar esters of long chain fatty acids & long chain monohydroxylic alcohols

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22
Q

what is the melting point of wax?

A

60-100 C

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23
Q

what is the function of membranes?

A

define cells & regulate composition of intracellular environment

24
Q

how are membranes formed?

25
what is the most abundant lipid in membranes?
glyceolphospholipids
26
what is the backbone of glyceolphospholipids?
glycerol with a phosphate at C3 position
27
what is a phosphatidate made of?
glycerol 3-phosphate + 2 fatty acids
28
what is Phosphatidylinositol involved in?
intracellular signal transduction
29
what do plant cells often contain?
glacatolipids
30
what are glacatolipids made of?
1-2 galactose groups linked to a C3 of diacylglycerol
31
what are sphingolipids derived from?
sphingosine
32
what is a sphingosine?
long chain amino alcohol
33
what is a sphingolipid made of?
1 fatty acid is linked by amide bond to bond ceramide
34
what do glycosphingolipids determine?
blood type
35
what do different blood types reflect?
different sugar patterns
36
archaebacteria (extremeophiles) lives under ( ) conditons of temp, pH & ionic strength
high conditons
37
what are steroids made of?
3 six carbon rings and 1 five carbon D-ring
38
what is the main function of cholesterol?
mediating membrane fluidity
39
what does the activation of phospholipase C cause?
the cleavage of head group to produce inositol
40
what are ghost signals?
used as back up to ensure activation
41
what does the polar group of phosphatidylinositols do?
migrates to the ER to release Ca & activate kinases
42
what are eicosnoids?
paracine hormones
43
what are paracrine hormones?
act on cells near point of production
44
function of prostaglandins?
construction of blood vessels & control blood flow
45
what are thromboxnes involved in?
blood clot formation
46
function of leukotrienes
smooth-muscle contractions
47
what are steroids hormones made of?
hydrophobic, non-polar oxidized sterol derivatives
48
what do steroid hormones affect?
gene expression & metabolism
49
what are the 4 lipid vitamins?
A, D, E, K
50
what is the main function of vitamin D?
regulates calcium uptake & deposition
51
what can excessive amounts of vitamin D cause?
calcification of soft tissue
52
what 3 forms are vitamin A formed in?
retinol (alcohol) aldehyde (retinal) retinioc acid
53
what is the name for vitamin E
alpha-tocopherol
54
what does vitamin E do in response to light?
change cis & trans configurations
55
what is Rickets?
insufficient vitamin D associated with skeletal defects, can be reversed
56
function of vitamin K
synthesis of blood coagulation proteins